Acetaldehyde,2,2,2-tribromo-

1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING Product Name Tribromoacetaldehyde 2.HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Acute toxicity, Dermal (Category 2) Acute toxicity, Oral (Category 3) Skin corrosion (Category 1B) According to European Directive 67/548/EEC as amended. Toxic if swallowed. Very toxic in contact with skin. Causes burns. Label elements Pictogram Signal word Hazard statement(s) H301 H310 H314 Precautionary statement(s) P280 P302 + P350 P305 + P351 + P338 P310 Hazard symbol(s) T+ R-phrase(s) R25 R27 R34 Danger Toxic if swallowed. Fatal in contact with skin. Causes severe skin burns and eye damage. Wear protective gloves/ protective clothing/ eye protection/ face protection. IF ON SKIN: Gently wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Very toxic Toxic if swallowed. Very toxic in contact with skin. Causes burns. S-phrase(s) S26 S28 S36/37/39 S45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Other hazards Lachrymator. 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Formula Molecular Weight : : : Bromal C2HBr3O 280,74 g/mol CAS-No. EC-No. Index-No. Classification Concentration Tribromacetaldehyd 115-17-3 204-067-9 - Acute Tox. 2; Acute Tox. 3; - Skin Corr. 1B; H301, H310, H314 T+, R25 - R27 - R34 For the full text of the H-Statements mentioned in this Section, see Section 16. 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8 °C Store under inert gas. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Eye protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour clear, liquid dark brown Safety data pH Melting point Boiling point Flash point Ignition temperature Lower explosion limit Upper explosion limit Density Water solubility no data available no data available 174 °C - lit. 65 °C - closed cup no data available no data available no data available 2,665 g/cm3 at 25 °C no data available 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid Heat, flames and sparks. Materials to avoid Strong oxidizing agentsStrong oxidizing agents, Strong bases Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen bromide gas 11. TOXICOLOGICAL INFORMATION Acute toxicity LD50 Oral - rat - 100 mg/kg Remarks: Behavioral:Convulsions or effect on seizure threshold. Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion Skin Eyes Toxic if swallowed. Causes burns. May be fatal if absorbed through skin. Causes skin burns. Causes eye burns. Signs and Symptoms of Exposure Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea Additional Information RTECS: AB3237500 12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available PBT and vPvB assessment no data available Other adverse effects no data available 13. DISPOSAL CONSIDERATIONS Product This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION ADR/RID UN-Number: 2927 Class: 6.1 (8) Packing group: I Proper shipping name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (Tribromacetaldehyd) IMDG UN-Number: 2927 Class: 6.1 (8) Packing group: I EMS-No: F-A, S-B Proper shipping name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (Tribromacetaldehyd) Marine pollutant: No IATA UN-Number: 2927 Class: 6.1 (8) Packing group: I Proper shipping name: Toxic liquid, corrosive, organic, n.o.s. (Tribromacetaldehyd) 15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Acute Tox. H301 H310 H314 Skin Corr. T+ R25 R27 R34 Acute toxicity Toxic if swallowed. Fatal in contact with skin. Causes severe skin burns and eye damage. Skin corrosion Very toxic Toxic if swallowed. Very toxic in contact with skin. Causes burns. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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