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Cyclohexanone,3-methyl-, (3R)-

1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING

Product Name

( R )-(+)-3-Methylcyclohexanone

2.HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Flammable liquids (Category 3)

According to European Directive 67/548/EEC as amended.

Flammable.

Label elements

Pictogram

Signal word

Hazard statement(s)

H226

Precautionary statement(s)

Hazard symbol(s)

R-phrase(s)

R10

S-phrase(s)

S16

S27

S36/37/39

Warning

Flammable liquid and vapour.

none

Flammable.

Keep away from sources of ignition - No smoking.

Take off immediately all contaminated clothing.

Wear suitable protective clothing, gloves and eye/face protection.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula

Molecular Weight

C7H12O

112,17 g/mol

CAS-No.

EC-No.

Index-No.

Classification

Concentration

(R)-(+)-3-Methylcyclohexanone

13368-65-5

236-438-6

Flam. Liq. 3; H226

R10

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.

Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires,

apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray;

solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

Use water spray to cool unopened containers.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Avoid breathing vapors, mist or gas. Remove all sources of ignition. Beware of vapours accumulating to form

explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous

earth, vermiculite) and place in container for disposal according to local / national regulations (see section

13). Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid inhalation of vapour or mist.

Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic

charge.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with

multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to

engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

Hand protection

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Handle with gloves.

Eye protection

Face shield and safety glasses

Skin and body protection

Choose body protection according to the amount and concentration of the dangerous substance at the

work place.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at

the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Density

Water solubility

liquid

colourless

no data available

168 - 169 °C - lit.

52 °C - closed cup

no data available

0,916 g/cm3 at 25 °C

no data available

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

Heat, flames and sparks.

Materials to avoid

Strong oxidizing agents, Strong reducing agents, Strong bases

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides

11. TOXICOLOGICAL INFORMATION

Acute toxicity

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. May cause respiratory tract irritation.

May be harmful if swallowed.

May be harmful if absorbed through skin. May cause skin irritation.

May cause eye irritation.

Signs and Symptoms of Exposure

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

investigated.

Additional Information

RTECS: Not available

12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

no data available

13. DISPOSAL CONSIDERATIONS

Product

This combustible material may be burned in a chemical incinerator equipped with an afterburner and

scrubber. Observe all federal, state, and local environmental regulations. Contact a licensed professional

waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

UN-Number: 2297 Class: 3

Packing group: III

Proper shipping name: METHYLCYCLO-HEXANONE

IMDG

UN-Number: 2297 Class: 3

Packing group: III

EMS-No: F-E, S-D

Proper shipping name: METHYLCYCLOHEXANONES

Marine pollutant: No

IATA

UN-Number: 2297 Class: 3

Packing group: III

Proper shipping name: Methylcyclohexanone

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Flam. Liq.

H226

R10

Flammable liquids

Flammable liquid and vapour.

Flammable.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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