Propanal

1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING Product Name Propionaldehyde 2.HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Flammable liquids (Category 2) Eye irritation (Category 2) Specific target organ toxicity - single exposure (Category 3) Skin irritation (Category 2) According to European Directive 67/548/EEC as amended. Highly flammable. Irritating to eyes, respiratory system and skin. Label elements Pictogram Signal word Hazard statement(s) H225 H319 H315 H335 Precautionary statement(s) P210 P261 P305 + P351 + P338 Danger Highly flammable liquid and vapour. Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Hazard symbol(s) F Xi R-phrase(s) R11 R36/37/38 Highly flammable Irritant Highly flammable. Irritating to eyes, respiratory system and skin. S-phrase(s) S9 S16 S29 Keep container in a well-ventilated place. Keep away from sources of ignition - No smoking. Do not empty into drains. Other hazards Stench. 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Formula Molecular Weight : : : Propanal Aldehyde C-3 C3H6O 58,08 g/mol CAS-No. EC-No. Index-No. Classification Concentration Propanal 123-38-6 204-623-0 605-018-00-8 Flam. Liq. 2; Eye Irrit. 2; - STOT SE 3; Skin Irrit. 2; H225, H319, H315, H335 F, Xi, R11 - R36/37/38 For the full text of the H-Statements mentioned in this Section, see Section 16. 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8 °C Handle and open container with care. Handle and store under inert gas. Air and moisture sensitive. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Eye protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour Safety data pH clear, liquid colourless Stench. no data available Melting point Boiling point Flash point Ignition temperature Lower explosion limit Upper explosion limit Vapour pressure Density Water solubility Partition coefficient: n-octanol/water Relative vapour density -81 °C - lit. 46 - 50 °C - lit. -40 °C - closed cup 175 °C 2,6 %(V) 16,1 %(V) 343 hPa at 20 °C 0,805 g/cm3 at 25 °C completely soluble log Pow: 0,83 2,01 - (Air = 1.0) 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Materials to avoid Oxidizing agents, Strong bases, Strong reducing agents Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides 11. TOXICOLOGICAL INFORMATION Acute toxicity LD50 Oral - rat - 800 - 1.600 mg/kg LC50 Inhalation - rat - 0,5 h - 26000 ppm LD50 Dermal - rabbit - 2.460 mg/kg Remarks: Behavioral:Somnolence (general depressed activity). Behavioral:Convulsions or effect on seizure threshold. Lungs, Thorax, or Respiration:Dyspnea. Skin corrosion/irritation Serious eye damage/eye irritation Eyes - rabbit - Moderate eye irritation - 24 h Respiratory or skin sensitization no data available Germ cell mutagenicity Genotoxicity in vitro - rat - Liver Unscheduled DNA synthesis Genotoxicity in vitro - Mammal - lymphocyte DNA damage Genotoxicity in vitro - Hamster - Lungs Mutation in mammalian somatic cells. Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure May cause respiratory irritation. Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. Causes respiratory tract irritation. Harmful if swallowed. May be harmful if absorbed through skin. Causes skin irritation. Causes serious eye irritation. Signs and Symptoms of Exposure Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea Additional Information RTECS: UE0350000 12. ECOLOGICAL INFORMATION Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 14 mg/l - 96 h Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available PBT and vPvB assessment no data available Other adverse effects Harmful to aquatic life. no data available 13. DISPOSAL CONSIDERATIONS Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION ADR/RID UN-Number: 1275 Class: 3 Packing group: II Proper shipping name: PROPIONALDEHYDE IMDG UN-Number: 1275 Class: 3 Packing group: II EMS-No: F-E, S-D Proper shipping name: PROPIONALDEHYDE Marine pollutant: No IATA UN-Number: 1275 Class: 3 Packing group: II Proper shipping name: Propionaldehyde 15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Eye Irrit. Flam. Liq. H225 H315 H319 H335 Skin Irrit. STOT SE F Xi R11 R36/37/38 Eye irritation Flammable liquids Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Skin irritation Specific target organ toxicity - single exposure Highly flammable Irritant Highly flammable. Irritating to eyes, respiratory system and skin. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

Related Product

• 1233860-02-0
• 1233860-04-2
• 1233860-06-4
• 1233860-08-6
• 1233860-11-1
• 1233860-12-2
• 1233860-16-6
• 1233860-17-7
• 1233860-18-8
• 1233860-19-9
• 1233860-21-3
• 1233860-23-5

Recommended suppliers