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Benzenamine,N-[3-(trimethoxysilyl)propyl]-

1.1

IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifiers

Product name

Product Number

Brand

CAS-No.

N -[3-(Trimethoxysilyl)propyl]aniline

440809

3068-76-6

1.2

Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Laboratory chemicals, Manufacture of substances

2.1

2.2

HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]

Skin corrosion (Category 1B)

Skin sensitization (Category 1)

Germ cell mutagenicity (Category 2)

Carcinogenicity (Category 2)

Specific target organ toxicity - repeated exposure (Category 1)

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Causes burns. Harmful: danger of serious damage to health by prolonged exposure through inhalation, in

contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Possible risk of irreversible

effects. May cause sensitization by skin contact.

Label elements

Labelling according Regulation (EC) No 1272/2008 [CLP]

Pictogram

Signal word

Hazard statement(s)

H314

H317

H341

H351

H372

Danger

Causes severe skin burns and eye damage.

May cause an allergic skin reaction.

Suspected of causing genetic defects.

Suspected of causing cancer.

Causes damage to organs through prolonged or repeated exposure.

Precautionary statement(s)

P280

P281

P305 + P351 + P338

P310

P314

Supplemental Hazard

Wear protective gloves/ protective clothing/ eye protection/ face

protection.

Wear protective gloves.

Use personal protective equipment as required.

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER or doctor/ physician.

Get medical advice/ attention if you feel unwell.

none

Statements

According to European Directive 67/548/EEC as amended.

Hazard symbol(s)

R-phrase(s)

R34

R40

R43

R48/20/21/22

R68

S-phrase(s)

S26

S35

S36/37/39

S45

Causes burns.

Limited evidence of a carcinogenic effect.

May cause sensitization by skin contact.

Harmful: danger of serious damage to health by prolonged exposure

through inhalation, in contact with skin and if swallowed.

Possible risk of irreversible effects.

In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

This material and its container must be disposed of in a safe way.

Wear suitable protective clothing, gloves and eye/face protection.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

2.3

3.2

Other hazards - none

COMPOSITION/INFORMATION ON INGREDIENTS

Mixtures

Formula

Molecular Weight

C12H21NO3Si

255,39 g/mol

Component

N-[3-(Trimethoxysilyl)propyl]aniline

Classification

Concentration

CAS-No.

EC-No.

3068-76-6

221-328-2

Skin Corr. 1B; H314

C, R34

Aniline

CAS-No.

EC-No.

Index-No.

62-53-3

200-539-3

612-008-00-7

Carc. 2; Muta. 2; Acute Tox. 3; 1 - 3 %

STOT RE 1; Eye Dam. 1; Skin

Sens. 1; Aquatic Acute 1;

H301, H311, H317, H318,

H331, H341, H351, H372,

H400

T, N, Carc.Cat.3, Mut.Cat.3,

R23/24/25 - R40 - R41 - R43 -

R48/23/24/25 - R68 - R50

Methanol

CAS-No.

EC-No.

Index-No.

67-56-1

200-659-6

603-001-00-X

Flam. Liq. 2; Acute Tox. 3;

STOT SE 1; H225, H301 +

H311 + H331, H370

<1%

F, T, R11 - R23/24/25 -

R39/23/24/25

For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

4.1

4.2

4.3

5.1

5.2

5.3

5.4

6.1

6.2

6.3

6.4

7.1

FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a

physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with

water. Consult a physician.

Most important symptoms and effects, both acute and delayed

Inhalation of vapors may cause:, Cough, Headache, Nausea, Skin contact may provoke the following

symptoms:, allergic dermatitis

Indication of any immediate medical attention and special treatment needed

no data available

FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Carbon oxides, nitrogen oxides (NOx), silicon oxides

Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

no data available

ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.

Evacuate personnel to safe areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

environment must be avoided.

Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed

containers for disposal.

Reference to other sections

For disposal see section 13.

HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

Normal measures for preventive fire protection.

7.2

7.3

8.1

8.2

9.1

Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are

opened must be carefully resealed and kept upright to prevent leakage.

Light sensitive. Store under inert gas.

Specific end uses

no data available

EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components with workplace control parameters

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and

at the end of workday.

Personal protective equipment

Eye/face protection

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection

tested and approved under appropriate government standards such as NIOSH (US) or EN

166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and

the standard EN 374 derived from it.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must be selected

according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator

with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup

to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Odour

Odour Threshold

Melting point/freezing

point

Initial boiling point and

boiling range

Flash point

Evaporation rate

Form: clear, liquid

Colour: yellow

no data available

310 °C - lit.

110 °C - closed cup

no data available

Flammability (solid, gas) no data available

Upper/lower

flammability or

explosive limits

Vapour pressure

Vapour density

no data available

m) Relative density

1,07 g/mL at 25 °C

Water solubility

Partition coefficient: n-

octanol/water

Autoignition

temperature

Decomposition

temperature

Viscosity

Explosive properties

Oxidizing properties

no data available

9.2

10.

10.1

10.2

10.3

10.4

10.5

10.6

11.

11.1

Other safety information

no data available

STABILITY AND REACTIVITY

Reactivity

no data available

Chemical stability

no data available

Possibility of hazardous reactions

no data available

Conditions to avoid

Exposure to moisture. Exposure to sunlight.

Incompatible materials

Strong oxidizing agents, Water

Hazardous decomposition products

Other decomposition products - no data available

TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC:

No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. Material is extremely destructive to the tissue of

the mucous membranes and upper respiratory tract.

May be harmful if swallowed. Causes burns.

May be harmful if absorbed through skin. Causes skin burns.

Causes eye burns.

Signs and Symptoms of Exposure

Inhalation of vapors may cause:, Cough, Headache, Nausea, Skin contact may provoke the following

symptoms:, allergic dermatitis

Additional Information

RTECS: Not available

12.

12.1

12.2

12.3

12.4

12.5

12.6

13.

13.1

14.

14.1

ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

Results of PBT and vPvB assessment

no data available

Other adverse effects

Toxic to aquatic life.

no data available

DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed

professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

TRANSPORT INFORMATION

UN number

14.2

ADR/RID: 3267

UN proper shipping name

IMDG: 3267

IATA: 3267

ADR/RID:

IMDG:

IATA:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (N-[3-(Trimethoxysilyl)propyl]aniline)

Corrosive liquid, basic, organic, n.o.s. (N-[3-(Trimethoxysilyl)propyl]aniline)

14.3

Transport hazard class(es)

14.4

14.5

14.6

15.

ADR/RID: 8

Packaging group

ADR/RID: II

Environmental hazards

ADR/RID: no

Special precautions for user

no data available

REGULATORY INFORMATION

IMDG: 8

IMDG: II

IMDG Marine pollutant: no

IATA: 8

IATA: II

IATA: no

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.1

15.2

16.

Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

Chemical Safety Assessment

no data available

OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Aquatic Acute

Carc.

Eye Dam.

Flam. Liq.

H225

H301

H301 + H311 +

H331

H311

H314

H317

H318

H331

H341

H351

H370

H372

H400

Muta.

Skin Corr.

Skin Sens.

STOT RE

STOT SE

R11

R23/24/25

R34

R39/23/24/25

R40

R41

R43

R48/23/24/25

R50

R68

Acute toxicity

Acute aquatic toxicity

Carcinogenicity

Serious eye damage

Flammable liquids

Highly flammable liquid and vapour.

Toxic if swallowed.

Toxic if swallowed, in contact with skin or if inhaled

Toxic in contact with skin.

Causes severe skin burns and eye damage.

May cause an allergic skin reaction.

Causes serious eye damage.

Toxic if inhaled.

Suspected of causing genetic defects.

Suspected of causing cancer.

Causes damage to organs.

Causes damage to organs through prolonged or repeated exposure.

Very toxic to aquatic life.

Germ cell mutagenicity

Skin corrosion

Skin sensitization

Specific target organ toxicity - repeated exposure

Specific target organ toxicity - single exposure

Corrosive

Highly flammable.

Toxic by inhalation, in contact with skin and if swallowed.

Causes burns.

Highly flammable

Dangerous for the environment

Toxic: danger of very serious irreversible effects through inhalation, in contact with

skin and if swallowed.

Limited evidence of a carcinogenic effect.

Risk of serious damage to eyes.

May cause sensitization by skin contact.

Toxic: danger of serious damage to health by prolonged exposure through inhalation,

in contact with skin and if swallowed.

Very toxic to aquatic organisms.

Possible risk of irreversible effects.

Toxic

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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