Benzoyl chloride,3-methyl-

1.
1.1
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifiers
Product name
Product Number
Brand
CAS-No.
:
:
:
:
m -Toluoyl chloride
122254
Anonymous
1711-06-4
1.2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
:
Laboratory chemicals, Manufacture of substances
2.
2.1
2.2
HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Skin corrosion (Category 1B)
Specific target organ toxicity - single exposure (Category 3)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Causes burns. Irritating to eyes and respiratory system.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word
Hazard statement(s)
H314
H335
Precautionary statement(s)
P261
P280
P305 + P351 + P338
P310
Supplemental Hazard
Danger
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
Wear protective gloves/ protective clothing/ eye protection/ face
protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/ physician.
none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R34
R36/37
S-phrase(s)
S23
S26
S27
S36/37/39
S45
Causes burns.
Irritating to eyes and respiratory system.
Do not breathe vapour.
In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
Take off immediately all contaminated clothing.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
2.3
3.
3.1
Other hazards
Lachrymator.
COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula
Molecular Weight
Component
m-Toluoyl chloride
:
:
C8H7ClO
154,59 g/mol
Concentration
CAS-No.
EC-No.
1711-06-4
216-976-8
-
4.
4.1
4.2
4.3
FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a
physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
Most important symptoms and effects, both acute and delayed
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and
skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,
pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,
Headache, Nausea, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological
properties have not been thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available
5.
5.1
5.2
5.3
5.4
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
8.
8.1
8.2
FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large
fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or
spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of
water.
Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen chloride gas
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to
form explosive concentrations. Vapours can accumulate in low areas.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13). Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Exposure to moisture.
Specific end uses
no data available
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
9.
9.1
PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour Threshold
pH
Melting point/freezing
point
Initial boiling point and
boiling range
Flash point
Evaporation rate
Form: clear, liquid
Colour: colourless
no data available
no data available
no data available
no data available
86 °C at 7 hPa - lit.
77 °C - closed cup
no data available
i)
Flammability (solid, gas) no data available
j)
k)
l)
Upper/lower
flammability or
explosive limits
Vapour pressure
Vapour density
no data available
no data available
no data available
m) Relative density
1,173 g/mL at 25 °C
n)
o)
p)
q)
Water solubility
Partition coefficient: n-
octanol/water
Autoignition
temperature
Decomposition
temperature
no data available
no data available
no data available
no data available
r)
s)
t)
Viscosity
Explosive properties
Oxidizing properties
no data available
no data available
no data available
9.2
10.
10.1
10.2
10.3
10.4
10.5
10.6
11.
11.1
Other safety information
no data available
STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Strong bases
Hazardous decomposition products
Other decomposition products - no data available
TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 3.440 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
Ingestion
May be harmful if inhaled. Material is extremely destructive to the tissue of
the mucous membranes and upper respiratory tract. Causes respiratory
tract irritation.
May be harmful if swallowed. Causes burns.
Skin
Eyes
May be harmful if absorbed through skin. Causes skin burns.
Causes eye burns.
Signs and Symptoms of Exposure
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and
skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,
pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,
Headache, Nausea, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological
properties have not been thoroughly investigated.
Additional Information
RTECS: DM6644000
12.
12.1
12.2
12.3
12.4
12.5
12.6
13.
13.1
14.
14.1
ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available
DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
This combustible material may be burned in a chemical incinerator equipped with an afterburner and
scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION
UN number
14.2
ADR/RID: 3265
UN proper shipping name
IMDG: 3265
IATA: 3265
ADR/RID:
IMDG:
IATA:
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (m-Toluoyl chloride)
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (m-Toluoyl chloride)
Corrosive liquid, acidic, organic, n.o.s. (m-Toluoyl chloride)
14.3
Transport hazard class(es)
ADR/RID: 8
14.4
Packaging group
ADR/RID: II
14.5
Environmental hazards
ADR/RID: no
14.6
Special precautions for user
no data available
IMDG: 8
IMDG: II
IMDG Marine pollutant: no
IATA: 8
IATA: II
IATA: no
15.
15.1
15.2
16.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available
OTHER INFORMATION
Further information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

;

Recommended suppliers

Dayang Chem (Hangzhou) Co.,Ltd.

China (Mainland) Assessed Supplier

3-Methylbenzoyl chloride Manufacturer/High quality/Best price/In stock

  • Assay:Industrial Grade,
  • Appearance:detailed see specifications
  • Package:according to the clients requirement
  • Storage:Store in dry, dark and ventilated place.
  • Transportation:by sea or by air
  • Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.
Contact Supplier

Simagchem Corporation

China (Mainland) Assessed Supplier

High quality M-Methyl Benzoyl Chloride supplier in China

  • Assay:99%
  • Appearance:white-off powder or granule ( referto COA)
  • Package:25kg drum or 200kg per drum
  • Storage:Keep in a cool & dry place
  • Transportation:by sea or by air
  • Application:Pharma Intermediate
Contact Supplier

Hebei yanxi chemical co.,LTD.

China (Mainland) Assessed Supplier

3-Methylbenzoyl chloride CAS NO.1711-06-4

  • Assay:1,
  • Appearance:White powder
  • Package:25kg cardboard barrel
  • Storage:Dry and ventilated
  • Transportation:Sea &air
  • Application:Used as an intermediate for drugs such as penicillin and phenobarbital.It is also used to prepare phenylacetic acid, spices and pesticides to kill rat apis.
Contact Supplier

EAST CHEMSOURCES LIMITED

China (Mainland) Assessed Supplier

m-Methyl benzoyl chloride

  • Assay:99% ,
  • Appearance:Achromatic or yellow liquid
  • Package:According to customers' requirements
  • Storage:Store In Dry, Cool And Ventilated Place
  • Transportation:By Sea Or By Air
  • Application:As an intermediate of organic synthesis.
Contact Supplier

Ality Chemical Corporation

China (Mainland) Assessed Supplier

Factory Supply m-toluoyl chloride

  • Assay:99.9%
  • Appearance:Refer to COA
  • Package:drum
  • Storage:keep in cool and dry place
  • Transportation:by sea or by air
  • Application:Intermediates and materials
Contact Supplier

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View