information Related products Suppliers

Benzenamine, 2-ethyl-

1.1

IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifiers

Product name

Product Number

Brand

CAS-No.

2-Ethylaniline

E11803

578-54-1

1.2

Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Laboratory chemicals, Manufacture of substances

2.1

2.2

HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]

Acute toxicity, Inhalation (Category 3)

Acute toxicity, Dermal (Category 3)

Specific target organ toxicity - repeated exposure (Category 2)

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects.

Label elements

Labelling according Regulation (EC) No 1272/2008 [CLP]

Pictogram

Signal word

Hazard statement(s)

H311 + H331

H373

Precautionary statement(s)

P261

P280

P311

Supplemental Hazard

Statements

Danger

Toxic in contact with skin or if inhaled

May cause damage to organs through prolonged or repeated exposure.

Avoid breathing vapours.

Wear protective gloves/ protective clothing.

Call a POISON CENTER or doctor/ physician.

none

According to European Directive 67/548/EEC as amended.

Hazard symbol(s)

R-phrase(s)

R23/24/25

R33

S-phrase(s)

S36/37/39

S45

Toxic by inhalation, in contact with skin and if swallowed.

Danger of cumulative effects.

Wear suitable protective clothing, gloves and eye/face protection.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

2.3

3.1

Other hazards - none

COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Formula

Molecular Weight

Component

2-Ethylaniline

C8H11N

121,18 g/mol

Concentration

CAS-No.

EC-No.

578-54-1

209-424-2

4.1

4.2

4.3

5.1

FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with

water. Consult a physician.

Most important symptoms and effects, both acute and delayed

Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes

cyanosis. Onset may be delayed 2 to 4 hours or longer., To the best of our knowledge, the chemical,

physical, and toxicological properties have not been thoroughly investigated.

Indication of any immediate medical attention and special treatment needed

no data available

FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large

fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or

spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of

water.

5.2

5.3

5.4

6.1

6.2

6.3

6.4

7.1

7.2

7.3

8.1

8.2

Special hazards arising from the substance or mixture

Carbon oxides, nitrogen oxides (NOx)

Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

Use water spray to cool unopened containers.

ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove

all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form

explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up

Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and

place in container for disposal according to local regulations (see section 13). Keep in suitable, closed

containers for disposal.

Reference to other sections

For disposal see section 13.

HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic

charge.

Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are

opened must be carefully resealed and kept upright to prevent leakage.

Light sensitive.

Specific end uses

no data available

EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components with workplace control parameters

Exposure controls

Appropriate engineering controls

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling

the product.

Personal protective equipment

Eye/face protection

Face shield and safety glasses Use equipment for eye protection tested and approved under

appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and

the standard EN 374 derived from it.

Immersion protection

Material: butyl-rubber

Minimum layer thickness: 0,3 mm

Break through time: > 480 min

Material tested:Butoject? ( Z677647, Size M)

Splash protection

Material: Chloroprene

Minimum layer thickness: 0,6 mm

Break through time: > 30 min

Material tested:Camapren? ( Z677493, Size M)

data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 873000, e-mail sales@kcl.de,

test method: EN374

If used in solution, or mixed with other substances, and under conditions which differ from EN 374,

contact the supplier of the CE approved gloves. This recommendation is advisory only and must

be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our

customers. It should not be construed as offering an approval for any specific use scenario.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must be selected

according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator

with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup

to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

9.1

PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Odour

Odour Threshold

Melting point/freezing

point

Initial boiling point and

boiling range

Flash point

Evaporation rate

Form: clear, liquid

Colour: dark red

no data available

Melting point/range: 44 °C

210 °C

93 °C - closed cup

no data available

Flammability (solid, gas) no data available

Upper/lower

flammability or

explosive limits

Vapour pressure

Vapour density

no data available

4,85

m) Relative density

0,983 g/mL at 25 °C

Water solubility

Partition coefficient: n-

octanol/water

Autoignition

temperature

no data available

Decomposition

temperature

Viscosity

Explosive properties

Oxidizing properties

no data available

9.2

10.

10.1

10.2

10.3

10.4

10.5

10.6

11.

11.1

Other safety information

no data available

STABILITY AND REACTIVITY

Reactivity

no data available

Chemical stability

no data available

Possibility of hazardous reactions

no data available

Conditions to avoid

Heat, flames and sparks.

Incompatible materials

Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents

Hazardous decomposition products

Other decomposition products - no data available

TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

LD50 Oral - rat - 1.260 mg/kg

Remarks: Behavioral:Somnolence (general depressed activity). Cyanosis Blood:Changes in spleen.

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC:

No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard

no data available

Potential health effects

Inhalation

Toxic if inhaled. May cause respiratory tract irritation.

Ingestion

Skin

Eyes

Harmful if swallowed.

Toxic if absorbed through skin. May cause skin irritation.

May cause eye irritation.

Signs and Symptoms of Exposure

Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes

cyanosis. Onset may be delayed 2 to 4 hours or longer., To the best of our knowledge, the chemical,

physical, and toxicological properties have not been thoroughly investigated.

Additional Information

RTECS: BX9800000

12.

12.1

ECOLOGICAL INFORMATION

Toxicity

Toxicity to daphnia and

other aquatic

invertebrates

LC50 - Daphnia magna (Water flea) - 8,05 mg/l - 48 h

12.2

12.3

12.4

12.5

12.6

13.

13.1

14.

14.1

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

Results of PBT and vPvB assessment

no data available

Other adverse effects

no data available

DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

This combustible material may be burned in a chemical incinerator equipped with an afterburner and

scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed

professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

TRANSPORT INFORMATION

UN number

ADR/RID: 2273

14.2

UN proper shipping name

ADR/RID:

2-ETHYLANILINE

IMDG:

2-ETHYLANILINE

IATA:

2-Ethylaniline

14.3

Transport hazard class(es)

ADR/RID: 6.1

14.4

Packaging group

ADR/RID: III

14.5

Environmental hazards

ADR/RID: no

14.6

Special precautions for user

no data available

IMDG: 2273

IMDG: 6.1

IMDG: III

IMDG Marine pollutant: no

IATA: 2273

IATA: 6.1

IATA: III

IATA: no

15.

15.1

15.2

16.

REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

Chemical Safety Assessment

no data available

OTHER INFORMATION

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

;