Pyridine,3-(tributylstannyl)-

1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING Product Name 3-(Tributylstannyl)pyridine 2.HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Acute toxicity, Dermal (Category 4) Acute toxicity, Oral (Category 3) Skin irritation (Category 2) Eye irritation (Category 2) Specific target organ toxicity - repeated exposure (Category 1) Acute aquatic toxicity (Category 1) According to European Directive 67/548/EEC as amended. Toxic if swallowed. Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Harmful in contact with skin. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label elements Pictogram Signal word Hazard statement(s) H301 H312 H315 H319 H372 H400 Precautionary statement(s) P273 P280 P301 + P310 P305 + P351 + P338 Danger Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Avoid release to the environment. Wear protective gloves/protective clothing. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Hazard symbol(s) T N R-phrase(s) R21 R25 R36/38 R48/23/25 R50/53 Get medical advice/attention if you feel unwell. Toxic Dangerous for the environment Harmful in contact with skin. Toxic if swallowed. Irritating to eyes and skin. Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S35 S36/37/39 S45 S60 S61 This material and its container must be disposed of in a safe way. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ Safety data sheets. Other hazards - none 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Formula Molecular Weight : : : 3-Pyridyltributylstannane C17H31NSn 368,14 g/mol CAS-No. EC-No. Index-No. Classification Concentration 3-(Tributylstannyl)pyridine 59020-10-9 - 050-008-00-3 Acute Tox. 4; Acute Tox. 3; - Skin Irrit. 2; Eye Irrit. 2; STOT RE 1; Aquatic Acute 1; H301, H312, H315, H319, H372, H400 T, N, R21 - R25 - R36/38 - R48/23/25 - R50/53 For the full text of the H-Statements mentioned in this Section, see Section 16. 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Normal measures for preventive fire protection. Conditions for safe storage Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: -20 °C Handle and store under inert gas. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves. Eye protection Face shield and safety glasses Skin and body protection Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Safety data pH Melting point Boiling point Flash point Ignition temperature Lower explosion limit Upper explosion limit Density Water solubility liquid colourless no data available no data available no data available > 110 °C no data available no data available no data available 1,153 g/cm3 at 25 °C no data available 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid no data available Materials to avoid Strong oxidizing agentsStrong oxidizing agents Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx), Tin/tin oxides 11. TOXICOLOGICAL INFORMATION Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure Causes damage to organs through prolonged or repeated exposure. Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes Toxic if inhaled. May cause respiratory tract irritation. Toxic if swallowed. Harmful if absorbed through skin. Causes skin irritation. Causes eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: no data available 12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available PBT and vPvB assessment no data available Other adverse effects Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS Product Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION ADR/RID UN-Number: 2788 Class: 6.1 Packing group: III Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (3-(Tributylstannyl)pyridine) IMDG UN-Number: 2788 Class: 6.1 Packing group: III EMS-No: F-A, S-A Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (3-(Tributylstannyl)pyridine) Marine pollutant: Marine pollutant IATA UN-Number: 2788 Class: 6.1 Packing group: III Proper shipping name: Organotin compound, liquid, n.o.s. (3-(Tributylstannyl)pyridine) 15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Acute Tox. Aquatic Acute Eye Irrit. H301 H312 H315 H319 H372 H400 Skin Irrit. STOT RE N T R21 R25 R36/38 R48/23/25 R50/53 Acute toxicity Acute aquatic toxicity Eye irritation Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Skin irritation Specific target organ toxicity - repeated exposure Dangerous for the environment Toxic Harmful in contact with skin. Toxic if swallowed. Irritating to eyes and skin. Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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