Allyl acetate

1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING Product Name Allyl acetate 2.HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Flammable liquids (Category 2) Acute toxicity, Inhalation (Category 2) Acute toxicity, Dermal (Category 4) Acute toxicity, Oral (Category 3) Eye irritation (Category 2) According to European Directive 67/548/EEC as amended. Highly flammable. Harmful in contact with skin. Toxic by inhalation and if swallowed. Irritating to eyes. Label elements Pictogram Signal word Hazard statement(s) H225 H301 H312 H319 H330 Precautionary statement(s) P210 P260 P280 P284 P305 + P351 + P338 P310 Hazard symbol(s) F Danger Highly flammable liquid and vapour. Toxic if swallowed. Harmful in contact with skin. Causes serious eye irritation. Fatal if inhaled. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wear protective gloves/ protective clothing. Wear respiratory protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Highly flammable T R-phrase(s) R11 R21 R23/25 R36 S-phrase(s) S16 S26 S45 S36 Toxic Highly flammable. Harmful in contact with skin. Toxic by inhalation and if swallowed. Irritating to eyes. Keep away from sources of ignition - No smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Wear suitable protective clothing. Other hazards - none 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Molecular Weight : : C5H8O2 100,12 g/mol CAS-No. EC-No. Index-No. Classification Concentration Allyl acetate 591-87-7 209-734-8 - Flam. Liq. 2; Acute Tox. 2; - Acute Tox. 4; Acute Tox. 3; Eye Irrit. 2; H225, H301, H312, H319, H330 F, T, R11 - R21 - R23/25 - R36 For the full text of the H-Statements mentioned in this Section, see Section 16. 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8 °C 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Eye protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour clear, liquid colourless Safety data pH Melting point Boiling point Flash point Ignition temperature Lower explosion limit Upper explosion limit Density Water solubility 7 at 1 g/l at 20 °C no data available 103 - 104 °C - lit. 11 °C - closed cup 374 °C no data available no data available 0,928 g/cm3 at 25 °C insoluble 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Materials to avoid Strong oxidizing agentsOxidizing agents, Bases, Peroxides Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides 11. TOXICOLOGICAL INFORMATION Acute toxicity LD50 Oral - rat - 130 mg/kg LC50 Inhalation - rat - 1 h - 1000 ppm Skin corrosion/irritation Skin - rabbit - Serious eye damage/eye irritation Eyes - rabbit - Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be fatal if inhaled. May cause respiratory tract irritation. Toxic if swallowed. Harmful if absorbed through skin. May cause skin irritation. Causes serious eye irritation. Signs and Symptoms of Exposure Damage to the lungs. Additional Information RTECS: AF1750000 12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available PBT and vPvB assessment no data available Other adverse effects no data available 13. DISPOSAL CONSIDERATIONS Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION ADR/RID UN-Number: 2333 Class: 3 (6.1) Proper shipping name: ALLYL ACETATE IMDG Packing group: II UN-Number: 2333 Class: 3 (6.1) Proper shipping name: ALLYL ACETATE Marine pollutant: No IATA UN-Number: 2333 Class: 3 (6.1) Packing group: II Packing group: II EMS-No: F-E, S-D Proper shipping name: Allyl acetate 15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Acute Tox. Eye Irrit. Acute toxicity Eye irritation Flam. Liq. H225 H301 H312 H319 H330 F T R11 R21 R23/25 R36 Flammable liquids Highly flammable liquid and vapour. Toxic if swallowed. Harmful in contact with skin. Causes serious eye irritation. Fatal if inhaled. Highly flammable Toxic Highly flammable. Harmful in contact with skin. Toxic by inhalation and if swallowed. Irritating to eyes. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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