1H-Pyrazole-5-carboxamide,3-bromo-N-[4-chloro-2-methyl-6-[(methylamino)carbonyl]phenyl]-1-(3-chloro-2-pyridinyl)-

1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING Product Name 3-bromo-N-[4-chloro-2-methyl-6- 2.HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Eye irritation (Category 2) Specific target organ toxicity - single exposure (Category 3) According to European Directive 67/548/EEC as amended. Harmful if swallowed. Irritating to eyes and respiratory system. Label elements Pictogram Signal word Hazard statement(s) H319 H335 Precautionary statement(s) P261 P305 + P351 + P338 Warning Causes serious eye irritation. May cause respiratory irritation. Avoid breathing dust/fume/gas/mist/vapours/spray. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Hazard symbol(s) Xn R-phrase(s) R22 R36/37 S-phrase(s) S26 Harmful Harmful if swallowed. Irritating to eyes and respiratory system. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Other hazards - none 3. COMPOSITION/INFORMATION ON INGREDIENTS Formula Molecular Weight : : C18H14BrCl2N5O2 483,15 g/mol CAS-No. EC-No. Index-No. Classification Concentration 3-bromo-N-[4-chloro-2-methyl-6-[(methylamino)carbonyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H- pyrazole-5-carboxamide 500008-45-7 - - Eye Irrit. 2; STOT SE 3; - H319, H335 Xn, R22 - R36/37 For the full text of the H-Statements mentioned in this Section, see Section 16. 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection. Conditions for safe storage Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves. Eye protection Safety glasses with side-shields conforming to EN166 Skin and body protection Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour Safety data pH Melting point Boiling point Flash point Ignition temperature Lower explosion limit Upper explosion limit Density Water solubility Partition coefficient: n-octanol/water Solubility powder light yellow characteristic no data available 192 - 215 °C no data available no data available no data available no data available no data available 1,519 g/cm3 at 20 °C 0,001 g/l log Pow: 2,76 3,4 g/l acetone-like 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid no data available Materials to avoid Acids, Reducing agents Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx), Hydrogen chloride gas, Hydrogen bromide gas 11. TOXICOLOGICAL INFORMATION Acute toxicity LD50 Oral - rat - male - > 5.000 mg/kg LD50 Oral - rat - female - > 5.000 mg/kg LC50 Inhalation - rat - 4 h - > 5,1 mg/l Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation. Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. Causes respiratory tract irritation. Harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. Causes eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: no data available 12. ECOLOGICAL INFORMATION Toxicity Toxicity to fish Toxicity to algae - Oncorhynchus mykiss (rainbow trout) - > 13,8 mg/l - 96 h - Lepomis macrochirus (Bluegill sunfish) - > 15,1 mg/l - 96 h EC50 - Algae - > 2 mg/l Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available PBT and vPvB assessment no data available Other adverse effects no data available 13. DISPOSAL CONSIDERATIONS Product Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION ADR/RID Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods 15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Eye Irrit. H319 H335 STOT SE Xn R22 R36/37 Eye irritation Causes serious eye irritation. May cause respiratory irritation. Specific target organ toxicity - single exposure Harmful Harmful if swallowed. Irritating to eyes and respiratory system. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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