Acetic acid, zirconiumsalt (1:?)

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand : : : Zirconium acetate solution 413801 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Skin irritation (Category 2) Eye irritation (Category 2) Classification according to EU Directives 67/548/EEC or 1999/45/EC Irritating to eyes and skin. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H315 H319 Precautionary statement(s) P305 + P351 + P338 Supplemental Hazard Warning Causes skin irritation. Causes serious eye irritation. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. none Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R36/38 S-phrase(s) S26 Irritating to eyes and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 2.3 3. 3.2 Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Mixtures Component Acetic acid Classification Concentration CAS-No. EC-No. Index-No. 64-19-7 200-580-7 607-002-00-6 Flam. Liq. 3; Skin Corr. 1A; H226, H314 C, R10 - R35 10 - 20 % Zirconium dioxide CAS-No. EC-No. 1314-23-4 215-227-2 Skin Irrit. 2; Eye Irrit. 2; STOT SE 3; H315, H319, H335 10 - 20 % Xi, R36/37/38 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 4. 4.1 4.2 4.3 5. 5.1 5.2 5.3 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Cough, Shortness of breath, sensation of heat, Nausea, Vomiting, Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Inhalation may provoke the following symptoms:, spasm, inflammation and edema of the larynx, Lung oedema, Pneumonia Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture no data available Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 7.3 8. 8.1 8.2 Further information no data available ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). 9. 9.1 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: liquid Colour: colourless no data available no data available no data available no data available no data available no data available no data available i) Flammability (solid, gas) no data available j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density no data available no data available no data available m) Relative density 1,279 g/mL at 25 °C n) o) p) q) r) s) t) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties no data available no data available no data available no data available no data available no data available no data available 9.2 10. 10.1 10.2 10.3 10.4 10.5 10.6 Other safety information no data available STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - no data available 11. 11.1 TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if swallowed. Causes burns. May be harmful if absorbed through skin. Causes skin burns. Causes eye burns. Signs and Symptoms of Exposure Cough, Shortness of breath, sensation of heat, Nausea, Vomiting, Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Inhalation may provoke the following symptoms:, spasm, inflammation and edema of the larynx, Lung oedema, Pneumonia Additional Information RTECS: Not available 12. 12.1 12.2 12.3 12.4 12.5 ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available 12.6 13. 13.1 14. 14.1 Other adverse effects no data available DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. TRANSPORT INFORMATION UN number 14.2 ADR/RID: 2790 UN proper shipping name IMDG: 2790 IATA: 2790 ADR/RID: IMDG: IATA: ACETIC ACID SOLUTION ACETIC ACID, SOLUTION Acetic acid solution 14.3 Transport hazard class(es) 14.4 14.5 14.6 15. ADR/RID: 8 Packaging group ADR/RID: III Environmental hazards ADR/RID: no Special precautions for user no data available REGULATORY INFORMATION IMDG: 8 IMDG: III IMDG Marine pollutant: no IATA: 8 IATA: III IATA: no This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 15.2 16. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Eye Irrit. Flam. Liq. H226 H314 H315 H319 H335 Skin Corr. Skin Irrit. STOT SE C R10 R35 R36/37/38 Xi Eye irritation Flammable liquids Flammable liquid and vapour. Causes severe skin burns and eye damage. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Skin corrosion Skin irritation Specific target organ toxicity - single exposure Corrosive Flammable. Causes severe burns. Irritating to eyes, respiratory system and skin. Irritant Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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