Terephthaloyl chloride

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand REACH No. CAS-No. : : : : : Terephthaloyl chloride 120871 Anonymous 01-2119488670-30-XXXX 100-20-9 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Acute toxicity, Inhalation (Category 3) Skin corrosion (Category 1A) Classification according to EU Directives 67/548/EEC or 1999/45/EC Toxic by inhalation. Causes severe burns. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H314 H331 Precautionary statement(s) P261 P280 P305 + P351 + P338 P310 Danger Causes severe skin burns and eye damage. Toxic if inhaled. Avoid breathing dust. Wear protective gloves/ protective clothing/ eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Supplemental Hazard none Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R23 R35 S-phrase(s) S26 S36/37/39 S45 Toxic by inhalation. Causes severe burns. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 2.3 3. 3.1 Other hazards Lachrymator. COMPOSITION/INFORMATION ON INGREDIENTS Substances Formula Molecular Weight Component Terephthaloyl dichloride : : C8H4Cl2O2 203,02 g/mol Concentration CAS-No. EC-No. Registration number 100-20-9 202-829-5 01-2119488670-30-XXXX - 4. 4.1 4.2 4.3 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed burning sensation, Cough, wheezing, laryngitis, Shortness of breath, spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Indication of any immediate medical attention and special treatment needed no data available 5. 5.1 5.2 5.3 5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 7.3 8. 8.1 FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, Hydrogen chloride gas Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Components with DNEL Component CAS-No. Applicatio Exposure Exposure Value Health effect n Area routes time Terephthaloyl 100-20-9 Workers Skin contact 1 d 12mg/kg Long-term dichloride systemic effects Workers Inhalation 10,75 mg/m3 Long-term systemic effects Components with PNEC Component CAS-No. Compartment Exposure Value time Terephthaloyl 100-20-9 Fresh water 0,668 mg/l dichloride Marine water 0,067 mg/l 8.2 Exposure controls Fresh water sediment Marine sediment Soil 1d 1d 1d 3,626 mg/kg 0,363 mg/kg 0,332 mg/kg Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Immersion protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 480 min Material tested:Dermatril? (Anonymous Z677272, Size M) Splash protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 30 min Material tested:Dermatril? (Anonymous Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 873000, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). 9. 9.1 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) Appearance Odour Odour Threshold pH Form: flakes Colour: white pungent no data available 4 e) f) g) h) Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Melting point/range: 79 - 81 °C - lit. 266 °C - lit. no data available no data available i) Flammability (solid, gas) The product is not flammable. j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density no data available 0,01 hPa at 20 °C no data available m) Relative density no data available n) o) p) q) r) s) t) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties no data available no data available no data available no data available no data available Not explosive The substance or mixture is not classified as oxidizing. 9.2 Other safety information Bulk density 872 kg/m3 10. 10.1 10.2 10.3 10.4 10.5 10.6 11. 11.1 STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid Avoid moisture. Incompatible materials Alcohols, Oxidizing agents, Strong bases Hazardous decomposition products Other decomposition products - no data available TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral - rat - > 5.000 mg/kg LC50 Inhalation - rat - 4 h - 0,7 mg/l Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Eye:Lacrimation. Lungs, Thorax, or Respiration:Dyspnea. Lungs, Thorax, or Respiration:Respiratory stimulation. LD50 Dermal - rat - > 2.000 mg/kg Skin corrosion/irritation Skin - rabbit - Causes severe burns. Serious eye damage/eye irritation no data available Respiratory or skin sensitization Maximisation Test - guinea pig - Did not cause sensitization on laboratory animals. Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Reproductive toxicity - rat - Oral Maternal Effects: Menstrual cycle changes or disorders. Reproductive toxicity - rat - Oral Paternal Effects: Spermatogenesis (including genetic material, sperm morphology,motility, and count). no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if swallowed. Causes burns. May be harmful if absorbed through skin. Causes skin burns. Causes eye burns. Signs and Symptoms of Exposure burning sensation, Cough, wheezing, laryngitis, Shortness of breath, spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Additional Information RTECS: Not available 12. 12.1 ECOLOGICAL INFORMATION Toxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates LC50 - Leuciscus idus (Golden orfe) - 961 mg/l - 96 h EC50 - Daphnia magna (Water flea) - > 967 mg/l - 48 h 12.2 12.3 12.4 Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available 12.5 12.6 13. 13.1 14. 14.1 Results of PBT and vPvB assessment no data available Other adverse effects no data available DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. TRANSPORT INFORMATION UN number 14.2 ADR/RID: 2923 UN proper shipping name IMDG: 2923 IATA: 2923 ADR/RID: IMDG: IATA: CORROSIVE SOLID, TOXIC, N.O.S. (Terephthaloyl dichloride) CORROSIVE SOLID, TOXIC, N.O.S. (Terephthaloyl dichloride) Corrosive solid, toxic, n.o.s. (Terephthaloyl dichloride) 14.3 Transport hazard class(es) 14.4 14.5 14.6 15. ADR/RID: 8 (6.1) Packaging group ADR/RID: I Environmental hazards ADR/RID: no Special precautions for user no data available REGULATORY INFORMATION IMDG: 8 (6.1) IMDG: I IMDG Marine pollutant: no IATA: 8 (6.1) IATA: I IATA: no This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 15.2 16. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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