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Benzenamine,2-chloro-N-methyl-

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

2-Chloro- N -methylaniline

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Skin irritation (Category 2)

Eye irritation (Category 2)

Specific target organ toxicity - single exposure (Category 3)

According to European Directive 67/548/EEC as amended.

Irritating to eyes, respiratory system and skin.

Label elements

Pictogram

Signal word

Hazard statement(s)

H315

H319

H335

Precautionary statement(s)

P261

P305 + P351 + P338

Warning

Causes skin irritation.

Causes serious eye irritation.

May cause respiratory irritation.

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Hazard symbol(s)

R-phrase(s)

R36/37/38

S-phrase(s)

S26

S36

Irritant

Irritating to eyes, respiratory system and skin.

In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

Wear suitable protective clothing.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula

Molecular Weight

C7H8ClN

141,6 g/mol

CAS-No.

EC-No.

Classification

Concentration

2-Chloro-N-methylaniline

932-32-1

Skin Irrit. 2; Eye Irrit. 2; STOT

SE 3; H315, H319, H335

Xi, R36/37/38

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.

Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires,

apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray;

solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

Use water spray to cool unopened containers.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.

Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form

explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up

Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place

in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers

for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic

charge.

Conditions for safe storage

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully

resealed and kept upright to prevent leakage. Store in cool place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with

multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to

engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

Hand protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without

touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves

after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Eye protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and

approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection

impervious clothing, The type of protective equipment must be selected according to the concentration

and amount of the dangerous substance at the specific workplace.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at

the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Density

Water solubility

liquid

colourless

no data available

218 °C - lit.

92 °C - closed cup

no data available

1,15 g/cm3 at 25 °C

no data available

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

Heat, flames and sparks.

Materials to avoid

Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx),

Hydrogen chloride gas

11. TOXICOLOGICAL INFORMATION

Acute toxicity

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

Inhalation - May cause respiratory irritation.

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. Causes respiratory tract irritation.

May be harmful if swallowed.

May be harmful if absorbed through skin. Causes skin irritation.

Causes serious eye irritation.

Signs and Symptoms of Exposure

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

investigated.

Additional Information

RTECS: Not available

12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

no data available

13. DISPOSAL CONSIDERATIONS

Product

This combustible material may be burned in a chemical incinerator equipped with an afterburner and

scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed

professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

Not dangerous goods

IMDG

Not dangerous goods

IATA

Not dangerous goods

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Eye Irrit.

H315

H319

H335

Skin Irrit.

STOT SE

R36/37/38

Eye irritation

Causes skin irritation.

Causes serious eye irritation.

May cause respiratory irritation.

Skin irritation

Specific target organ toxicity - single exposure

Irritant

Irritating to eyes, respiratory system and skin.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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