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Benzene,1,1'-(2,2-dichloroethylidene)bis[4-chloro-

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

4,4'-DDD PESTANAL,250 MG (2,2-BIS(4-CHL&

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Acute toxicity, Dermal (Category 4)

Acute toxicity, Oral (Category 3)

Carcinogenicity (Category 2)

Acute aquatic toxicity (Category 1)

Chronic aquatic toxicity (Category 1)

According to European Directive 67/548/EEC as amended.

Harmful in contact with skin. Toxic if swallowed. Limited evidence of a carcinogenic effect. Very toxic to aquatic

organisms, may cause long-term adverse effects in the aquatic environment.

Label elements

Pictogram

Signal word

Hazard statement(s)

H301

H312

H351

H410

Precautionary statement(s)

P273

P280

P301 + P310

P501

Hazard symbol(s)

R-phrase(s)

R21

R25

R40

R50/53

Danger

Toxic if swallowed.

Harmful in contact with skin.

Suspected of causing cancer.

Very toxic to aquatic life with long lasting effects.

Avoid release to the environment.

Wear protective gloves/protective clothing.

IF SWALLOWED: Immediately call a POISON CENTER or

doctor/physician.

Dispose of contents/container to an approved waste disposal plant.

Toxic

Dangerous for the environment

Harmful in contact with skin.

Toxic if swallowed.

Limited evidence of a carcinogenic effect.

Very toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

S-phrase(s)

S36/37

S45

S60

S61

Wear suitable protective clothing and gloves.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

This material and its container must be disposed of as hazardous waste.

Avoid release to the environment. Refer to special instructions/ Safety data

sheets.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms

Formula

Molecular Weight

1,1-Dichloro-2,2-bis(4-chlorophenyl)ethane

4,4 ′ -DDD

TDE

C14H10Cl4

320,04 g/mol

CAS-No.

EC-No.

Classification

Concentration

2,2-bis(4-Chlorophenyl)-1,1-dichloro-ethane

72-54-8

200-783-0

Acute Tox. 4; Acute Tox. 3;

Carc. 2; Aquatic Acute 1;

Aquatic Chronic 1; H301,

H312, H351, H410

T, N, R21 - R25 - R40 -

R50/53

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation.

Evacuate personnel to safe areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

environment must be avoided.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire

protection.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator

type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the

respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and

components tested and approved under appropriate government standards such as NIOSH (US) or CEN

(EU).

Hand protection

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Handle with gloves.

Eye protection

Face shield and safety glasses

Skin and body protection

Choose body protection according to the amount and concentration of the dangerous substance at the

work place.

Hygiene measures

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the

product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Vapour pressure

Density

Water solubility

Partition coefficient:

solid

no data available

94,0 - 96,0 °C

193,0 °C at 1,3 hPa

no data available

< 0,00001 hPa at 25,0 °C

1,38 g/cm3

no data available

log Pow: 6,02

n-octanol/water

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

no data available

Materials to avoid

Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen chloride gas

Hazardous decomposition products formed under fire conditions. - Nature of decomposition products not

known.

11. TOXICOLOGICAL INFORMATION

Acute toxicity

LD50 Oral - Hamster - > 5.000 mg/kg

TDLo Oral - Human - 428,5 mg/kg

Remarks: Endocrine:Adrenal cortex hypoplasia.

TDLo Oral - rat - 6.000 mg/kg

Remarks: Cardiac:Other changes. Gastrointestinal:Other changes. Kidney, Ureter, Bladder:Changes in both

tubules and glomeruli.

TDLo Oral - rat - 14 mg/kg

Remarks: Liver:Changes in liver weight. Endocrine:Estrogenic. Musculoskeletal:Other changes.

TDLo Oral - rat - 2.100 mg/kg

Remarks: Behavioral:Altered sleep time (including change in righting reflex).

LD50 Dermal - rabbit - 1.200 mg/kg

Remarks: Behavioral:Excitement. Behavioral:Convulsions or effect on seizure threshold. Skin irritation

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

This product is or contains a component that has been reported to be possibly carcinogenic based on its IARC,

ACGIH, NTP, or EPA classification.

Limited evidence of carcinogenicity in animal studies

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. May cause respiratory tract irritation.

Toxic if swallowed.

Harmful if absorbed through skin. May cause skin irritation.

May cause eye irritation.

Signs and Symptoms of Exposure

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

investigated.

Additional Information

RTECS: KI0700000

12. ECOLOGICAL INFORMATION

Toxicity

Toxicity to fish

Toxicity to daphnia

LC50 - other fish - 1,18 - 9 mg/l - 96,0 h

LC50 - Lepomis macrochirus (Bluegill) - 0,04 - 0,05 mg/l - 96,0 h

LC50 - Oncorhynchus mykiss (rainbow trout) - 0,06 - 0,09 mg/l - 96,0 h

LC50 - Pimephales promelas (fathead minnow) - 3,47 - 5,58 mg/l - 96,0 h

EC50 - Daphnia pulex (Water flea) - 0,01 mg/l - 48 h

and other aquatic

invertebrates.

Persistence and degradability

no data available

Bioaccumulative potential

Indication of bioaccumulation.

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

13. DISPOSAL CONSIDERATIONS

Product

Observe all federal, state, and local environmental regulations. Contact a licensed professional waste

disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn

in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

UN-Number: 2811 Class: 6.1

Packing group: III

Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. (2,2-bis(4-Chlorophenyl)-1,1-dichloro-ethane)

IMDG

UN-Number: 2811 Class: 6.1

Packing group: III EMS-No: F-A, S-A

Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. (2,2-bis(4-Chlorophenyl)-1,1-dichloro-ethane)

Marine pollutant: No

IATA

UN-Number: 2811 Class: 6.1

Packing group: III

Proper shipping name: Toxic solid, organic, n.o.s. (2,2-bis(4-Chlorophenyl)-1,1-dichloro-ethane)

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Aquatic Acute

Aquatic Chronic

Carc.

H301

H312

H351

H410

R21

R25

R40

R50/53

Acute toxicity

Acute aquatic toxicity

Chronic aquatic toxicity

Carcinogenicity

Toxic if swallowed.

Harmful in contact with skin.

Suspected of causing cancer.

Very toxic to aquatic life with long lasting effects.

Dangerous for the environment

Toxic

Harmful in contact with skin.

Toxic if swallowed.

Limited evidence of a carcinogenic effect.

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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