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Acetic acid,manganese(3+) salt (3:1)

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

Manganese(III) acetate dihydrate

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Skin irritation (Category 2)

Eye irritation (Category 2)

Specific target organ toxicity - single exposure (Category 3)

According to European Directive 67/548/EEC as amended.

Irritating to eyes, respiratory system and skin.

Label elements

Pictogram

Signal word

Hazard statement(s)

H315

H319

H335

Precautionary statement(s)

P261

P305 + P351 + P338

Warning

Causes skin irritation.

Causes serious eye irritation.

May cause respiratory irritation.

Avoid breathing dust/fume/gas/mist/vapours/spray.

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Hazard symbol(s)

R-phrase(s)

R36/37/38

S-phrase(s)

S26

S36

Irritant

Irritating to eyes, respiratory system and skin.

In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

Wear suitable protective clothing.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula

Molecular Weight

C6H9MnO6 · 2H2O

268,1 g/mol

CAS-No.

EC-No.

Classification

Concentration

Manganese(III) acetate dihydrate

19513-05-4

213-602-5

Skin Irrit. 2; Eye Irrit. 2; STOT

SE 3; H315, H319, H335

Xi, R36/37/38

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire

protection.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Handle under inert gas. Protect from moisture.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or

type P1 (EN 143) respirator. Use respirators and components tested and approved under appropriate

government standards such as NIOSH (US) or CEN (EU).

Hand protection

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Handle with gloves.

Eye protection

Safety glasses with side-shields conforming to EN166

Skin and body protection

Choose body protection according to the amount and concentration of the dangerous substance at the

work place.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at

the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Water solubility

powder

no data available

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

no data available

Materials to avoid

Strong reducing agents, Powdered metals, Strong acids

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Manganese/manganese

oxides

11. TOXICOLOGICAL INFORMATION

Acute toxicity

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

Inhalation - May cause respiratory irritation.

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. Causes respiratory tract irritation.

May be harmful if swallowed.

May be harmful if absorbed through skin. Causes skin irritation.

Causes eye irritation.

Signs and Symptoms of Exposure

Men exposed to manganese dusts showed a decrease in fertility. Chronic manganese poisoning primarily

involves the central nervous system. Early symptoms include languor, sleepiness and weakness in the legs. A

stolid mask-like appearance of the face, emotional disturbances such as uncontrollable laughter and a spastic

gait with tendency to fall in walking are findings in more advanced cases. High incidence of pneumonia has

been found in workers exposed to the dust or fume of some manganese compounds.

Additional Information

RTECS: no data available

12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

no data available

13. DISPOSAL CONSIDERATIONS

Product

Observe all federal, state, and local environmental regulations. Contact a licensed professional waste

disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn

in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

Not dangerous goods

IMDG

Not dangerous goods

IATA

Not dangerous goods

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Eye Irrit.

H315

H319

H335

Skin Irrit.

STOT SE

R36/37/38

Eye irritation

Causes skin irritation.

Causes serious eye irritation.

May cause respiratory irritation.

Skin irritation

Specific target organ toxicity - single exposure

Irritant

Irritating to eyes, respiratory system and skin.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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