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1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

Tetramethylammonium hydrogenphthalate

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Specific target organ toxicity - repeated exposure (Category 2)

Acute aquatic toxicity (Category 1)

Acute toxicity, Oral (Category 3)

According to European Directive 67/548/EEC as amended.

Very toxic to aquatic organisms. Toxic if swallowed. Harmful: danger of serious damage to health by prolonged

exposure if swallowed.

Label elements

Pictogram

Signal word

Hazard statement(s)

H373

H400

H301

Precautionary statement(s)

P273

P301 + P310

Danger

May cause damage to organs through prolonged or repeated exposure.

Very toxic to aquatic life.

Toxic if swallowed.

Avoid release to the environment.

IF SWALLOWED: Immediately call a POISON CENTER or

doctor/physician.

Hazard symbol(s)

R-phrase(s)

R25

R48/22

R50

S-phrase(s)

S25

S36

S45

S61

Toxic

Dangerous for the environment

Toxic if swallowed.

Harmful: danger of serious damage to health by prolonged exposure if

swallowed.

Very toxic to aquatic organisms.

Avoid contact with eyes.

Wear suitable protective clothing.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

Avoid release to the environment. Refer to special instructions/ Safety data

sheets.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms

Formula

Molecular Weight

Phthalic acid mono(tetramethylammonium)salt

Tetramethylammonium phthalatemonobasic

C12H17NO4

239,27 g/mol

CAS-No.

EC-No.

Classification

Concentration

Tetramethylammonium hydrogenphthalate

79723-02-7

416-900-5

STOT RE 2; Aquatic Acute 1;

Acute Tox. 3; H373, H400,

H301

T, N, R25 - R48/22 - R50

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation.

Evacuate personnel to safe areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

environment must be avoided.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire

protection.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator

type N99 (US) or type P2 (EN 143) respirator cartridges as a backup to engineering controls. If the

respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and

components tested and approved under appropriate government standards such as NIOSH (US) or CEN

(EU).

Hand protection

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Handle with gloves.

Eye protection

Face shield and safety glasses

Skin and body protection

Choose body protection according to the amount and concentration of the dangerous substance at the

work place.

Hygiene measures

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the

product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Water solubility

crystalline

white

no data available

148 - 150 °C - lit.

no data available

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

no data available

Materials to avoid

Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx)

11. TOXICOLOGICAL INFORMATION

Acute toxicity

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. May cause respiratory tract irritation.

Toxic if swallowed.

May be harmful if absorbed through skin. May cause skin irritation.

May cause eye irritation.

Signs and Symptoms of Exposure

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

investigated.

Additional Information

RTECS: no data available

12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

Very toxic to aquatic organisms.

Avoid release to the environment.

13. DISPOSAL CONSIDERATIONS

Product

Observe all federal, state, and local environmental regulations. Contact a licensed professional waste

disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn

in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

UN-Number: 2811 Class: 6.1

Packing group: III

Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. (Tetramethylammonium hydrogenphthalate)

IMDG

UN-Number: 2811 Class: 6.1

Packing group: III EMS-No: F-A, S-A

Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. (Tetramethylammonium hydrogenphthalate)

Marine pollutant: No

IATA

UN-Number: 2811 Class: 6.1

Packing group: III

Proper shipping name: Toxic solid, organic, n.o.s. (Tetramethylammonium hydrogenphthalate)

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Aquatic Acute

H301

H373

H400

STOT RE

R25

R48/22

R50

Further information

Acute toxicity

Acute aquatic toxicity

Toxic if swallowed.

May cause damage to organs through prolonged or repeated exposure.

Very toxic to aquatic life.

Specific target organ toxicity - repeated exposure

Dangerous for the environment

Toxic

Toxic if swallowed.

Harmful: danger of serious damage to health by prolonged exposure if swallowed.

Very toxic to aquatic organisms.

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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