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2-Chlorophenol

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

2-Chlorophenol

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Acute toxicity (Category 4)

Chronic aquatic toxicity (Category 2)

According to European Directive 67/548/EEC as amended.

Harmful by inhalation, in contact with skin and if swallowed. Toxic to aquatic organisms, may cause long-term

adverse effects in the aquatic environment.

Label elements

Pictogram

Signal word

Hazard statement(s)

H302

H312

H332

H411

Precautionary statement(s)

P273

Hazard symbol(s)

R-phrase(s)

R20/21/22

R51/53

Warning

Harmful if swallowed.

Harmful in contact with skin.

Harmful if inhaled.

Toxic to aquatic life with long lasting effects.

Avoid release to the environment.

Harmful

Dangerous for the environment

Harmful by inhalation, in contact with skin and if swallowed.

Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

S-phrase(s)

S28

S61

After contact with skin, wash immediately with plenty of water.

Avoid release to the environment. Refer to special instructions/ Safety data

sheets.

Other hazards

Stench.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula

Molecular Weight

C6H5ClO

128,56 g/mol

CAS-No.

EC-No.

Classification

Concentration

2-Chlorophenol

95-57-8

202-433-2

Acute Tox. 4; Aquatic Chronic

2; H302, H312, H332, H411

Xn, N, R20/21/22 - R51/53

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

environment must be avoided.

Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed

containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic

charge.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are

opened must be carefully resealed and kept upright to prevent leakage.

Stench.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with

multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to

engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

Hand protection

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Handle with gloves.

Eye protection

Face shield and safety glasses

Skin and body protection

Choose body protection according to the amount and concentration of the dangerous substance at the

work place.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at

the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Vapour pressure

Density

Water solubility

Partition coefficient:

liquid, clear

light yellow

no data available

8 °C - lit.

175 - 176 °C - lit.

64,0 °C - closed cup

no data available

1,3 hPa at 121,0 °C

1,241 g/cm3 at 25 °C

no data available

log Pow: 2,32

n-octanol/water

log Pow: 2,17

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

no data available

Materials to avoid

Acid chlorides, Acid anhydrides, Oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen chloride gas

11. TOXICOLOGICAL INFORMATION

Acute toxicity

LD50 Oral - rat - 670,0 mg/kg

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

Harmful if inhaled. May cause respiratory tract irritation.

Harmful if swallowed.

Harmful if absorbed through skin. May cause skin irritation.

May cause eye irritation.

Signs and Symptoms of Exposure

Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and

skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,

pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,

Headache, Nausea, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological

properties have not been thoroughly investigated.

Additional Information

RTECS: SK2625000

12. ECOLOGICAL INFORMATION

Toxicity

Toxicity to fish

Toxicity to daphnia

LC50 - Lepomis macrochirus (Bluegill) - 5,7 - 12 mg/l - 96,0 h

LC50 - Pimephales promelas (fathead minnow) - 6 - 16 mg/l - 96,0 h

LC50 - Carassius auratus (goldfish) - 10,7 - 15,2 mg/l - 96,0 h

EC50 - Daphnia magna (Water flea) - 6,30 - 17,90 mg/l - 24 h

and other aquatic

invertebrates.

Immobilization EC50 - Daphnia magna (Water flea) - 3,91 mg/l - 48 h

Toxicity to algae

EC50 - Pseudokirchneriella subcapitata (green algae) - 70,00 mg/l - 96 h

EC50 - Chlorella vulgaris (Fresh water algae) - 170,00 mg/l - 96 h

Persistence and degradability

Bioaccumulative potential

Bioaccumulation

Lepomis macrochirus (Bluegill) - 28 d

Bioconcentration factor (BCF): 214

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

13. DISPOSAL CONSIDERATIONS

Product

This combustible material may be burned in a chemical incinerator equipped with an afterburner and

scrubber. Observe all federal, state, and local environmental regulations. Contact a licensed professional

waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

UN-Number: 2021 Class: 6.1

Packing group: III

Proper shipping name: CHLOROPHENOLS, LIQUID

IMDG

UN-Number: 2021 Class: 6.1

Packing group: III

EMS-No: F-A, S-A

Proper shipping name: CHLOROPHENOLS, LIQUID

Marine pollutant: No

IATA

UN-Number: 2021 Class: 6.1

Packing group: III

Proper shipping name: Chlorophenols, liquid

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Aquatic Chronic

H302

H312

H332

H411

R20/21/22

R51/53

Acute toxicity

Chronic aquatic toxicity

Harmful if swallowed.

Harmful in contact with skin.

Harmful if inhaled.

Toxic to aquatic life with long lasting effects.

Dangerous for the environment

Harmful

Harmful by inhalation, in contact with skin and if swallowed.

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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