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Turpentine oil

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

Oil of turpentine

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Flammable liquids (Category 3)

Acute toxicity, Inhalation (Category 4)

Acute toxicity, Dermal (Category 4)

Acute toxicity, Oral (Category 4)

Aspiration hazard (Category 1)

Eye irritation (Category 2)

Skin irritation (Category 2)

Skin sensitization (Category 1)

Chronic aquatic toxicity (Category 2)

According to European Directive 67/548/EEC as amended.

Flammable. Harmful by inhalation, in contact with skin and if swallowed. Harmful: may cause lung damage if

swallowed. Irritating to eyes and skin. May cause sensitization by skin contact. Toxic to aquatic organisms,

may cause long-term adverse effects in the aquatic environment.

Label elements

Pictogram

Signal word

Hazard statement(s)

H226

H302

H304

H312

H315

H317

H319

H332

H411

Precautionary statement(s)

P273

P280

P301 + P310

P305 + P351 + P338

P331

Hazard symbol(s)

R-phrase(s)

R10

R20/21/22

R36/38

R43

R51/53

R65

S-phrase(s)

S36/37

S46

S61

S62

Danger

Flammable liquid and vapour.

Harmful if swallowed.

May be fatal if swallowed and enters airways.

Harmful in contact with skin.

Causes skin irritation.

May cause an allergic skin reaction.

Causes serious eye irritation.

Harmful if inhaled.

Toxic to aquatic life with long lasting effects.

Avoid release to the environment.

Wear protective gloves/ protective clothing.

IF SWALLOWED: Immediately call a POISON CENTER or doctor/

physician.

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Do NOT induce vomiting.

Harmful

Dangerous for the environment

Flammable.

Harmful by inhalation, in contact with skin and if swallowed.

Irritating to eyes and skin.

May cause sensitization by skin contact.

Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

Harmful: may cause lung damage if swallowed.

Wear suitable protective clothing and gloves.

If swallowed, seek medical advice immediately and show this container or

label.

Avoid release to the environment. Refer to special instructions/ Safety data

sheets.

If swallowed, do not induce vomiting: seek medical advice immediately

and show this container or label.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms

Fir oil

Pine oil

Turpentine

Oil of turpentine

CAS-No.

EC-No.

Classification

Concentration

Turpentine, oil any of the volatile predominantly terpenic fractions or distillates resulting from the

solvent extraction of, gum c

8006-64-2

232-350-7

- Flam. Liq. 3; Acute Tox. 4;

Asp. Tox. 1; Eye Irrit. 2; Skin

Irrit. 2; Skin Sens. 1; Aquatic

Chronic 2; H226, H302,

H304, H312, H315, H317,

H319, H332, H411

Xn, N, R10 - R20/21/22 -

R36/38 - R43 - R51/53 - R65

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.

Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires,

apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray;

solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

Use water spray to cool unopened containers.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.

Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form

explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

environment must be avoided.

Methods and materials for containment and cleaning up

Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place

in container for disposal according to local regulations (see section 13).

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic

charge.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are

opened must be carefully resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with

multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to

engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

Hand protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without

touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves

after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Eye protection

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate

government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of

protective equipment must be selected according to the concentration and amount of the dangerous

substance at the specific workplace.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at

the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

Odour

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Vapour pressure

Density

Water solubility

liquid

colourless

pungent

no data available

-55 °C - lit.

153 - 175 °C - lit.

36 °C - closed cup

233 °C

0,8 %(V)

6 %(V)

5 hPa at 20 °C

0,86 g/cm3 at 25 °C

insoluble

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

Heat, flames and sparks.

Materials to avoid

Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Nature of decomposition products not

known.

11. TOXICOLOGICAL INFORMATION

Acute toxicity

LC50 Inhalation - rat - 6 h - 12.000 mg/m3

Remarks: Behavioral:Convulsions or effect on seizure threshold. Lungs, Thorax, or Respiration:Dyspnea.

Skin corrosion/irritation

Skin - rabbit - Severe skin irritation - Draize Test

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

May cause allergic skin reaction.

Germ cell mutagenicity

no data available

Carcinogenicity

Carcinogenicity - mouse - Skin

Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Skin and Appendages: Other: Tumors.

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

May be fatal if swallowed and enters airways.

Potential health effects

Inhalation

Ingestion

Skin

Eyes

Harmful if inhaled. Causes respiratory tract irritation.

Harmful if swallowed. Aspiration hazard if swallowed - can enter lungs and cause

damage.

Harmful if absorbed through skin. Causes skin irritation.

Causes serious eye irritation.

Signs and Symptoms of Exposure

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

investigated.

Additional Information

RTECS: YO8400000

12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

Toxic to aquatic life.

13. DISPOSAL CONSIDERATIONS

Product

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as

this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.

Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

UN-Number: 1299 Class: 3

Proper shipping name: TURPENTINE

IMDG

Packing group: III

UN-Number: 1299 Class: 3

Proper shipping name: TURPENTINE

Marine pollutant: No

IATA

UN-Number: 1299 Class: 3

Packing group: III

EMS-No: F-E, S-E

Proper shipping name: Turpentine

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Aquatic Chronic

Asp. Tox.

Eye Irrit.

Flam. Liq.

H226

H302

H304

H312

H315

H317

H319

H332

H411

Skin Irrit.

R10

R20/21/22

R36/38

R43

R51/53

R65

Acute toxicity

Chronic aquatic toxicity

Aspiration hazard

Eye irritation

Flammable liquids

Flammable liquid and vapour.

Harmful if swallowed.

May be fatal if swallowed and enters airways.

Harmful in contact with skin.

Causes skin irritation.

May cause an allergic skin reaction.

Causes serious eye irritation.

Harmful if inhaled.

Toxic to aquatic life with long lasting effects.

Skin irritation

Dangerous for the environment

Harmful

Flammable.

Harmful by inhalation, in contact with skin and if swallowed.

Irritating to eyes and skin.

May cause sensitization by skin contact.

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

Harmful: may cause lung damage if swallowed.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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