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Phosphorodithioic acid,O-ethyl S,S-bis(1-methylpropyl) ester

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

Cadusafos PESTANAL?

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Acute toxicity, Inhalation (Category 1)

Acute toxicity, Dermal (Category 1)

Acute toxicity, Oral (Category 2)

Acute aquatic toxicity (Category 1)

According to European Directive 67/548/EEC as amended.

Toxic if swallowed. Very toxic by inhalation. Very toxic in contact with skin. Very toxic to aquatic organisms,

may cause long-term adverse effects in the aquatic environment.

Label elements

Pictogram

Signal word

Hazard statement(s)

H300

H310

H330

H400

Precautionary statement(s)

P260

P264

P273

P280

P284

P302 + P350

Hazard symbol(s)

T+

R-phrase(s)

R25

R26

R27

R50/53

Danger

Fatal if swallowed.

Fatal in contact with skin.

Fatal if inhaled.

Very toxic to aquatic life.

Do not breathe dust/fume/gas/mist/vapours/spray.

Wash hands thoroughly after handling.

Avoid release to the environment.

Wear protective gloves/protective clothing.

Wear respiratory protection.

IF ON SKIN: Gently wash with plenty of soap and water.

Very toxic

Toxic if swallowed.

Very toxic by inhalation.

Very toxic in contact with skin.

Very toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

S-phrase(s)

S28

S36/37

S45

S60

S61

After contact with skin, wash immediately with plenty of soap and water.

Wear suitable protective clothing and gloves.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

This material and its container must be disposed of as hazardous waste.

Avoid release to the environment. Refer to special instructions/ Safety data

sheets.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Synonyms

Formula

Molecular Weight

S,S-di-sec-butyl O-ethyl phosphorodithioate

O-Ethyl S,S-bis(1-methylpropyl) phosphorodithioate

C10H23O2PS2

270,4 g/mol

CAS-No.

EC-No.

Classification

Concentration

S,S-di-sec-butyl O-ethyl phosphorodithioate

95465-99-9

- -

Acute Tox. 1; Acute Tox. 2;

Aquatic Acute 1; H300, H310,

H330, H400

T+, R25 - R26 - R27 - R50/53

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate

personnel to safe areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed

containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid inhalation of vapour or mist.

Normal measures for preventive fire protection.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are

opened must be carefully resealed and kept upright to prevent leakage.

Recommended storage temperature: 2 - 8 °C

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with

multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to

engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

Hand protection

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Handle with gloves.

Eye protection

Face shield and safety glasses

Skin and body protection

Choose body protection according to the amount and concentration of the dangerous substance at the

work place.

Hygiene measures

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the

product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

liquid

colourless

yellow

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Density

Water solubility

Partition coefficient:

no data available

112 - 114 °C at 1,1 hPa

129,4 °C

no data available

1,054 g/cm3 at 20 °C

0,248 g/l

POW: 3,9 at 20 °C

n-octanol/water

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

no data available

Materials to avoid

Strong acids and oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, Sulphur oxides, Oxides of

phosphorus

11. TOXICOLOGICAL INFORMATION

Acute toxicity

LD50 Oral - rat - 37,1 mg/kg

LD50 Oral - mouse - 71,4 mg/kg

LC50 Inhalation - rat - 4 h - 0,026 mg/l

LD50 Dermal - rabbit - male - 24,4 mg/kg

LD50 Dermal - rabbit - female - 41,8 mg/kg

Skin corrosion/irritation

Skin - rabbit - No skin irritation

Serious eye damage/eye irritation

Eyes - rabbit - No eye irritation

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be fatal if inhaled. May cause respiratory tract irritation.

Toxic if swallowed.

May cause skin irritation. May be fatal if absorbed through skin.

May cause eye irritation.

Signs and Symptoms of Exposure

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

investigated.

Additional Information

RTECS: no data available

12. ECOLOGICAL INFORMATION

Toxicity

Toxicity to fish

Toxicity to daphnia

and other aquatic

invertebrates.

Toxicity to algae

LC50 - Oncorhynchus mykiss (rainbow trout) - 0,13 mg/l - 96,0 h

LC50 - Lepomis macrochirus (Bluegill sunfish) - 0,17 mg/l - 96,0 h

LC50 - Daphnia - 0,0013 mg/l - 48 h

EC50 - Algae - 5,3 mg/l - 96 h

Persistence and degradability

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

13. DISPOSAL CONSIDERATIONS

Product

Observe all federal, state, and local environmental regulations. Contact a licensed professional waste

disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn

in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

UN-Number: 3381 Class: 6.1

Packing group: I

Proper shipping name: TOXIC BY INHALATION LIQUID, N.O.S. (S,S-di-sec-butyl O-ethyl phosphorodithioate)

IMDG

UN-Number: 3381 Class: 6.1

Packing group: I EMS-No: F-A, S-A

Proper shipping name: TOXIC BY INHALATION LIQUID, N.O.S. (S,S-di-sec-butyl O-ethyl phosphorodithioate)

Marine pollutant: No

IATA

UN-Number: 3381 Class: 6.1

Proper shipping name: Toxic by inhalation liquid, n.o.s. (S,S-di-sec-butyl O-ethyl phosphorodithioate)

IATA Passenger: Not permitted for transport

IATA Cargo: Not permitted for transport

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Aquatic Acute

H300

H310

H330

H400

T+

R25

R26

R27

R50/53

Further information

Acute toxicity

Acute aquatic toxicity

Fatal if swallowed.

Fatal in contact with skin.

Fatal if inhaled.

Very toxic to aquatic life.

Very toxic

Toxic if swallowed.

Very toxic by inhalation.

Very toxic in contact with skin.

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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