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Maduramycin ammonium

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

Maduramicin ammonium

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Acute toxicity, Dermal (Category 2)

Acute toxicity, Oral (Category 2)

Eye irritation (Category 2)

According to European Directive 67/548/EEC as amended.

Toxic if swallowed. Very toxic in contact with skin. Irritating to eyes.

Label elements

Pictogram

Signal word

Hazard statement(s)

H300

H310

H319

Precautionary statement(s)

P264

P280

P302 + P350

P305 + P351 + P338

P310

Hazard symbol(s)

T+

R-phrase(s)

R25

R27

R36

S-phrase(s)

S26

S28

S36/37

S45

Danger

Fatal if swallowed.

Fatal in contact with skin.

Causes serious eye irritation.

Wash hands thoroughly after handling.

Wear protective gloves/protective clothing.

IF ON SKIN: Gently wash with plenty of soap and water.

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER or doctor/physician.

Very toxic

Toxic if swallowed.

Very toxic in contact with skin.

Irritating to eyes.

In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

After contact with skin, wash immediately with plenty of soap and water.

Wear suitable protective clothing and gloves.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

Caution - substance not yet tested completely.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula

Molecular Weight

C47H83NO17

934,16 g/mol

CAS-No.

EC-No.

Classification

Concentration

Maduramicin

84878-61-5

Acute Tox. 2; Eye Irrit. 2;

H300, H310, H319

T+, R25 - R27 - R36

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation.

Evacuate personnel to safe areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire

protection.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator

type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the

respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and

components tested and approved under appropriate government standards such as NIOSH (US) or CEN

(EU).

Hand protection

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Handle with gloves.

Eye protection

Face shield and safety glasses

Skin and body protection

Choose body protection according to the amount and concentration of the dangerous substance at the

work place.

Hygiene measures

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the

product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Water solubility

solid

off-white

no data available

165 °C

207 °C at 1.013 hPa

no data available

insoluble

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

no data available

Materials to avoid

Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx)

11. TOXICOLOGICAL INFORMATION

Acute toxicity

LD50 Oral - rat - 33 mg/kg

Skin corrosion/irritation

Serious eye damage/eye irritation

Eyes - rabbit - Moderate eye irritation

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. May cause respiratory tract irritation.

Toxic if swallowed.

May cause skin irritation. May be fatal if absorbed through skin.

Causes eye irritation.

Additional Information

RTECS: no data available

12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

no data available

13. DISPOSAL CONSIDERATIONS

Product

Observe all federal, state, and local environmental regulations. Contact a licensed professional waste

disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn

in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

UN-Number: 2811 Class: 6.1

Packing group: I

Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. (Maduramicin)

IMDG

UN-Number: 2811 Class: 6.1

Packing group: I

EMS-No: F-A, S-A

Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. (Maduramicin)

Marine pollutant: No

IATA

UN-Number: 2811 Class: 6.1

Packing group: I

Proper shipping name: Toxic solid, organic, n.o.s. (Maduramicin)

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Eye Irrit.

H300

H310

H319

T+

R25

R27

R36

Acute toxicity

Eye irritation

Fatal if swallowed.

Fatal in contact with skin.

Causes serious eye irritation.

Very toxic

Toxic if swallowed.

Very toxic in contact with skin.

Irritating to eyes.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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