3-Pyridinecarboxamide,N-(2,4-difluorophenyl)-2-[3-(trifluoromethyl)phenoxy]-

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name
:
Diflufenican
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
According to Regulation (EC) No1272/2008
Chronic aquatic toxicity (Category 3)
According to European Directive 67/548/EEC as amended.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Label elements
Pictogram
Signal word
Hazard statement(s)
H412
Precautionary statement(s)
P273
Hazard symbol(s)
R-phrase(s)
R52/53
none
none
Harmful to aquatic life with long lasting effects.
Avoid release to the environment.
none
Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
S61
Avoid release to the environment. Refer to special instructions/ Safety data
sheets.
Other hazards - none
3. COMPOSITION/INFORMATION ON INGREDIENTS
Formula
Molecular Weight
:
:
C19H11F5N2O2
394,3 g/mol
CAS-No.
EC-No.
Classification
Concentration
Diflufenican
83164-33-4
-
-
Aquatic Chronic 3; H412
-
R52/53
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
If inhaled
If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Avoid dust formation.
Environmental precautions
Do not let product enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.
7. HANDLING AND STORAGE
Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire
protection.
Conditions for safe storage
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protective equipment
Respiratory protection
Use respirators and components tested and approved under appropriate government standards such as
NIOSH (US) or CEN (EU).
Hand protection
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
standard EN 374 derived from it.
Handle with gloves.
Eye protection
Safety glasses with side-shields conforming to EN166
Skin and body protection
Choose body protection according to the amount and concentration of the dangerous substance at the
work place.
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
the end of workday.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form
Safety data
pH
Melting point
Boiling point
Flash point
Ignition temperature
Lower explosion limit
Upper explosion limit
Water solubility
solid
no data available
161 - 162 °C
no data available
no data available
no data available
no data available
no data available
insoluble
10. STABILITY AND REACTIVITY
Chemical stability
Stable under recommended storage conditions.
Conditions to avoid
no data available
Materials to avoid
no data available
Hazardous decomposition products
no data available
11. TOXICOLOGICAL INFORMATION
Acute toxicity
LD50 Oral - rat - 2.000 mg/kg
LD50 Dermal - rat - 2.000 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Reproductive toxicity - rat - Oral
Effects on Newborn: Delayed effects.
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
Ingestion
Skin
Eyes
May be harmful if inhaled. May cause respiratory tract irritation.
May be harmful if swallowed.
May be harmful if absorbed through skin. May cause skin irritation.
May cause eye irritation.
Additional Information
RTECS: US4589800
12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
PBT and vPvB assessment
no data available
Other adverse effects
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
13. DISPOSAL CONSIDERATIONS
Product
Observe all federal, state, and local environmental regulations. Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn
in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
ADR/RID
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
16. OTHER INFORMATION
Text of H-code(s) and R-phrase(s) mentioned in Section 3
Aquatic Chronic
H412
R52/53
Chronic aquatic toxicity
Harmful to aquatic life with long lasting effects.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Further information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.
;

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