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Aluminum, [ethyl3-(oxo-kO)butanoato-kO']bis(2-propanolato)-, (T-4)-

Material Safety Data Sheet
acc. to OSHA and ANSI

1 Identification of substance:
Product details:
Product name: Aluminum di(isopropoxide)acetoacetic ester chelate
2 Composition/Data on components:
Chemical characterization:
Description: (CAS#)
Aluminum di(isopropoxide)acetoacetic ester chelate
(CAS# 14782-75-3); 100%
Identification number(s):
EINECS Number: 238-851-7

3 Hazards identification
Hazard description:

Xi Irritant

Information pertaining to particular dangers for man and environment
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH 2 Health (acute effects) = 2
Flammability = 2
FIRE 2
Reactivity = 1
REACTIVITY 1

4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep
patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a
doctor.

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Aluminum di(isopropoxide)acetoacetic ester chelate

After swallowing Seek immediate medical advice.

5 Fire fighting measures
Suitable extinguishing agents
CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents Water
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.

6 Accidental release measures
Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Measures for environmental protection:
Do not allow material to be released to the environment without proper
governmental permits.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders,
universal binders, sawdust).
Ensure adequate ventilation.
Keep away from ignition sources.
Additional information:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage
Handling
Information for safe handling:
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Keep ignition sources away.
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from water/moisture.
Store away from oxidizing agents.
Do not store together with acids.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Aluminum di(isopropoxide)acetoacetic ester chelate

8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals
and having an average face velocity of at least 100 feet per minute.
Components with limit values that require monitoring at the workplace:
Not required.
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be
followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands: Impervious gloves
Eye protection: Safety glasses
Body protection: Protective work clothing.

9 Physical and chemical properties:
General Information
Form: Liquid
Color: Light yellow
Odor: Alcohol-like
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: 400??C (752??F)
Sublimation temperature / start: Not determined
Flash point: 50??C (122??F)
Ignition temperature: Not determined
Decomposition temperature: Not determined
Danger of explosion: Product is not explosive. However,
formation of explosive air/vapor
mixtures is possible.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not determined
Density at 20??C (68??F): 1.035 g/cm3
Solubility in / Miscibility with
Water: Reacts

10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to
specifications.

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Aluminum di(isopropoxide)acetoacetic ester chelate

Materials to be avoided:
Water/moisture
Acids
Oxidizing agents
Dangerous reactions Contact with acids releases flammable gases
Dangerous products of decomposition:
Carbon monoxide and carbon dioxide
Flammable gases/vapors

11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Subacute to chronic toxicity:
Aluminum may be implicated in Alzheimers disease. Inhalation of aluminum
containing dusts may cause pulmonary disease.
Subacute to chronic toxicity:
Corrosive materials are acutely destructive to the respiratory tract,
eyes, skin and digestive tract. Eye contact may result in permanent
damage and complete vision loss. Inhalation may result in respiratory
effects such as inflammation, edema, and chemical pneumonitis. May cause
coughing, wheezing, laryngitis, shortness of breath, headache, nausea and
vomiting. Ingestion may cause damage to the mouth, throat and esophagus.
May cause skin burns or irritation depending on the severity of the
exposure.
Isopropyl alcohol, if formed, may act as a local irritant and in high
concentrations as a narcotic with symptoms such as headache, nausea,
dizziness, vomiting, mental depression, anesthesia, and coma. Similar
symptoms may be caused by ingestion. It can cause corneal burns on
contact with the eyes and has caused teratogenic, mutagenic and
reproductive effects in laboratory animals.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
No classification data on carcinogenic properties of this material is
available from the EPA, IARC, NTP, OSHA or ACGIH.

12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper
governmental permits.

13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Aluminum di(isopropoxide)acetoacetic ester chelate

14 Transport information
DOT regulations:

Hazard class: 3
Identification number: UN2924
Packing group: III
Proper shipping name (technical
name): Flammable liquid, corrosive, n.o.s.,
aluminum di(isopropoxide)acetoacetic
esterchelate
Land transport ADR/RID (cross-border)

ADR/RID class: 3 Flammable liquids
Item: 33c
Danger code (Kemler): 38
UN-Number: 2924
Description of goods: Flammable liquid, corrosive, n.o.s.,
aluminum di(isopropoxide)acetoacetic
esterchelate
Maritime transport IMDG:

IMDG Class: 3
UN Number: 2924
Packaging group: III
Proper shipping name: Flammable liquid, corrosive, n.o.s.,
aluminum di(isopropoxide)acetoacetic
esterchelate
Air transport ICAO-TI and IATA-DGR:

ICAO/IATA Class: 3
UN/ID Number: 2924
Packaging group: III
Proper shipping name: Flammable liquid, corrosive, n.o.s.,
aluminum di(isopropoxide)acetoacetic
esterchelate

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Aluminum di(isopropoxide)acetoacetic ester chelate

15 Regulations
Product related hazard informations:
Hazard symbols:
Xi Irritant
Risk phrases:
10 Flammable.
36/37/38 Irritating to eyes, respiratory system and skin.
Safety phrases:
26 In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
National regulations
All components of this product are listed in the U.S. Environmental
Protection Agency Toxic Substances Control Act Chemical substance
Inventory.
Information about limitation of use:
For use only by technically qualified individuals.

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