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Phosphoric acid,manganese(2+) salt (2:1)

MATERIAL SAFETY DATA SHEET
PHOS DIP - 330
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SECTION I - IDENTIFICATION
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TRANSPORTATION EMERGENCY: HMIS HEALTH ............ 3
CHEM-TEL 1-800-255-3924 HMIS FLAMMABILITY ...... 0
INFORMATION: 860-347-2505 HMIS REACTIVITY ........ 2
HMIS PROTECTION ....... X
DU-LITE CORPORATION
171 RIVER ROAD PREPARED BY: WALTER J. SMITH
DATE: 5/01/2006
MIDDLETOWN, CT 06457

PRODUCT NAME .........PHOS DIP - 330
DESCRIPTION ..........Chemical product for producing manganese phosphate
coatings.
DOT CLASS: CORROSIVE LIQUIDS, ACIDIC, INORGANIC, N.O.S.,
(CONTAINS PHOSPHORIC ACID, NITRIC ACID),
8, UN 3264, PG II
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SECTION II - HAZARDOUS INGREDIENTS
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HAZARDOUS COMPONENT CAS NUMBER TLV(MG/M3) PEL(MG/M3) PERCENT
MANGANESE DIHYDROGEN PHOS. 18718-07-5 5.0(Mn) 5.0(Mn) 20-30
NICKEL NITRATE 13478-00-7 0.1(NI) 0.1(NI) <1.0
NITRIC ACID 7697-37-2 2.0 PPM 2.0 PPM 1 - 10
PHOSPHERIC ACID 7664-38-2 1.0 1.0 1 - 10
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N/E = NOT ESTABLISHED N/A = NOT APPLICABLE
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SECTION III - PHYSICAL DATA
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BOILING POINT(F)........>212 F SPECIFIC GRAVITY (H20=1)... 1.36
VAPOR PRESSURE (mm Hg)....N/E MELTING POINT.............. N/A
VAPOR DENSITY (Air=1)....N/E EVAPORATION RATE........... N/E
SOLUBILITY IN H20..Complete miscible PH.........................<1.0
APPEARANCE/ODOR...........odorless, green liquid.
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SECTION IV - REACTIVITY DATA
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CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: None
INCOMPATIBLE MATERIALS: Strong alkali, sulfides, cyanides.
DECOMPOSITION PRODUCTS: Steam, hydrogen, phosphoric oxides, oxides of
nitrogen.
HAZARDOUS POLYMERIZATION: WILL NOT OCCU ===========================================================================
SECTION V - FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT................None FLAMMABLE LIMITS........None
LOWER FLAME LIMIT..........N/A HIGHER FLAME LIMIT......N/A
IN CASE OF FIRE: Non-flammable. Use extinguishing media appropriate to
surrounding conditions.
SPECIAL FIREFIGHTING PROCEDURES: Wear protective clothing with self-?contained
breathing apparatus.
UNUSUAL FIRE HAZARDS: Prolonged contact with some metals (i.e. aluminum,
tin zinc etc.) may release flammable hydrogen gas. Hazardous fumes may be
released under thermal decomposition.
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SECTION VI - HEALTH HAZARD DATA PHOS DIP - 330 ===========================================================================
ROUTES OF ENTRY: Eye contact, skin contact, inhalation, ingestion.
HEALTH HAZARDS (ACUTE, CHRONIC): Contains STRONG ACID.
Causes severe eye, skin and tissue burns. May be harmful or fatal if
swallowed. May cause respiratory tract irritation. Avoid contact with eyes,
skin or clothing. Contains OXIDIZER. Contact with other material may cause
fire. Contains Manganese compound, chronic inhalation of manganese can
cause central nervous system disorders similar to Parkinson's disease.
Contains Nickel compound which are suspect carcinogens.
CARCINOGENICITY: Nickel NTP?: Yes. IARC?: Yes. OSHA REGULATED?: No.
SYMPTOMS OF EXPOSURE: Eye, skin and respiratory tract irritation. Eye,
skin and tissue burns. May cause dermatitis in some individuals who are
allergic or sensitive to nickel compounds.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory ailments.
FIRST AID: INHALATION: Move victim to fresh air. If not breathing, use
artificial respiration. If breathing is difficult, give oxygen. Seek
medical attention. EYES: Flush with running water for at least 15 minutes.
Seek medical attention. SKIN: Wash affected area with plenty of water.
Remove contaminated clothing. If irritation or burns are present, seek
medical attention. INGESTION: If conscious, give plenty of water. Do not
induce vomiting. Seek medical attention.
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SECTION VII - PRECAUTIONS/PROCEDURES
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IN CASE OF SPILL: Wear proper protective clothing. Contain spills with
inert absorbent. Recover material into a chemical waste container.
Neutralize spill area with ash or lime. Flush spill area with water.
WASTE DISPOSAL METHOD: Neutralize with soda ash or lime and dispose of in
accordance with federal, state and local regulations.
PRECAUTIONS: Wear proper protective clothing when using this product. Use
with adequate ventilation. Wash thoroughly after handling. Store away
from strong alkali. When making a solution, never add water to acid.
Always add acid slowly to water with constant stirring.
OTHER PRECAUTIONS: Emptied containers of this product may contain
hazardous vapors and residue. Clean thoroughly before reusing or
discarding. Do not use a welding torch to cut container. Do not use for
water or food storage.
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SECTION VIII - SPECIAL PROTECTION
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RESPIRATORY PROTECTION: Use NIOSH/MSHA approved respirator if dust, FUMES
or vapors are excessive. VENTILATION: Maintain below PEL, TLV.
MECHANICAL EXHAUST...X PROTECTIVE GLOVES: Rubber.
LOCAL EXHAUST........X EYE PROTECTION: Safety goggles, face shield.
OTHER PROTECTIVE EQUIP. apron, boots, coveralls. Eye wash and safety shower.
WORK/HYGIENIC PRACTICES.. Wash after handling, launder clothes.
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SECTION IX - SARA TITLE III INFORMATION
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HAZARDOUS CERCLA SECT 302 SECT 313 SECT 311/312
COMPONENT RQ LBS. TPQ LBS. TOXIC HAZARDS
MANGANESE DIHHYDROGEN PHOS. N/A N/A YES A,B
NICKEL NITRATE 100 N/A YES A,B,C
NITRIC ACID 1000 1000 YES A,B,C
PHOSPHORIC ACID 5000 N/A YES A

A=IMMEDIATE (ACUTE HEALTH HAZARD) B=DELAYED (CHRONIC) HEALTH HAZAR C=FIRE HAZARD D= SUDDEN RELEASE OF PRESSURE HAZARD E=REACTIVE HAZAR
? Du-Lite Corporation 2006

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