information Related products Suppliers

Butadiene, styrene, divinylbenzene polymer

MSDS FOR: LN-601 REVISED: 07-JAN-2004

SECTION 1:

PRODUCT IDENTIFIER: LN-601 FOR PROJECTS & CONSTRUCION

DATE OF PREPARATION: JANUARY 7, 2004
PRODUCT USE: ADHESIVE
MANUFACTURED BY: MACCO ADHESIVES
925 EUCLID AVENUE
CLEVELAND, OHIO 44115, U.S.A.

ICI PAINTS CANADA
8200 KEELE STREET
CONCORD, ONTARIO L4K 2A5, CANADA

EMERGENCY AND MSDS TELEPHONE NUMBER: 1-800-545-2643

MSDS PREPARED BY: PRODUCT SAFETY AND TOXICOLOGY DEPARTMENT
ICI PAINTS NORTH AMERICA

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENT WT%

CHEMICAL NAME: 2-METHYLPENTANE 5-10
COMMON NAME: 2-METHYLPENTANE
CAS NUMBER: 107-83-5

CHEMICAL NAME: LIMESTONE 20-30
COMMON NAME: LIMESTONE
CAS NUMBER: 1317-65-3

CHEMICAL NAME: KAOLIN 20-30
COMMON NAME: CLAY
CAS NUMBER: 1332-58-7

CHEMICAL NAME: QUARTZ .1-1.0
COMMON NAME: QUARTZ
CAS NUMBER: 14808-60-7

CHEMICAL NAME: BENZENE, 1,3-DIETHENYL-, POLYMER WITH 1,3- 1-5
BUTADIENE AND ETHENYLBENZENE
COMMON NAME: STYRENE-BUTADIENE POLYME CAS NUMBER: 26471-45-4

CHEMICAL NAME: SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC 10-20
COMMON NAME: LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)
CAS NUMBER: 64742-89-8

CHEMICAL NAME: DISTILLATES (PETROLEUM), STEAM-CRACKED, POLYMERS 10-20
WITH LIGHT STEAM-CRACKED PETROLEUM NAPHTHA
COMMON NAME: AROMATIC HYDROCARBON RESIN
CAS NUMBER: 68410-16-2
CHEMICAL NAME: 2,2-DIMETHYLBUTANE 1-5
COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 75-83-2

CHEMICAL NAME: 2,3-DIMETHYLBUTANE 1-5
COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 79-29-8

CHEMICAL NAME: BENZENE, ETHENYL-, POLYMER WITH 1,3-BUTADIENE 1-5
COMMON NAME: STYRENE-BUTADIENE POLYME CAS NUMBER: 9003-55-8

CHEMICAL NAME: 3-METHYLPENTANE 1-5
COMMON NAME: 3-METHYL PENTANE
CAS NUMBER: 96-14-0

SECTION 3: HAZARDS IDENTIFICATION

PRIMARY ROUTE(S) OF EXPOSURE: INHALATION, SKIN CONTACT, EYE CONTACT,
INGESTION

EFFECTS OF OVEREXPOSURE

INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION
MAY LEAD TO LOSS OF APPETITE, MUCOUS MEMBRANE
IRRITATION, FATIGUE, DROWSINESS, DIZZINESS AND/O LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION, NAUSEA,
VOMITING, COUGHING, CENTRAL NERVOUS SYSTEM DEPRESSION,
INTOXICATION, ANESTHETIC EFFECT OR NARCOSIS, DIFFICULTY
OF BREATHING, CONVULSIONS, PNEUMOCONIOSIS, LOSS OF
CONSCIOUSNESS, DEATH.

SKIN CONTACT: IRRITATION OF SKIN. PROLONGED OR REPEATED CONTACT CAN
CAUSE DERMATITIS, DEFATTING.

EYE CONTACT: IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT CAN
CAUSE CONJUNCTIVITIS, BLURRED VISION, TEARING OF EYES,
REDNESS OF EYES, SEVERE EYE IRRITATION.

INGESTION: INGESTION MAY CAUSE LUNG INFLAMMATION AND DAMAGE DUE
TO ASPIRATION OF MATERIAL INTO LUNGS, DROWSINESS,
DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE,
UNCOORDINATION, NAUSEA, VOMITING, DIARRHEA, GASTRO-
INTESTINAL DISTURBANCES, ABDOMINAL PAIN, CENTRAL
NERVOUS SYSTEM DEPRESSION, INTOXICATION, DIFFICULTY OF
BREATHING, CONVULSIONS, PARALYSIS, CARDIAC FAILURE,
DEATH.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:

EYE, SKIN, RESPIRATORY DISORDERS, LUNG DISORDERS
SECTION 4: FIRST-AID MEASURES

INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUE BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE
TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL
HELP FOR ANY BREATHING DIFFICULTY.

SKIN CONTACT: WASH THOROUGHLY WITH SOAP AND WATER. IF ANY PRODUCT
REMAINS, GENTLY RUB PETROLEUM JELLY, VEGETABLE O MINERAL/BABY OIL ONTO SKIN. REPEATED APPLICATIONS MAY BE
NEEDED. REMOVE CONTAMINATED CLOTHING. WASH
CONTAMINATED CLOTHING BEFORE RE-USE.

EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER,
ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF
IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN MEDICAL
TREATMENT.

INGESTION: IF SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY.

SECTION 5: FIRE-FIGHTING MEASURES

FLASH POINT (SETA): 4 F./ -16 C. LOWER EXPLOSIVE LIMIT: 1.0 %
UPPER EXPLOSIVE LIMIT: 7.0 %

FIRE EXTINGUISHING MEDIA: DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE

UNUSUAL FIRE AND EXPLOSION HAZARDS

CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT OR FIRE.
VAPORS MAY IGNITE EXPLOSIVELY AT AMBIENT TEMPERATURES. VAPORS ARE HEAVIE THAN AIR AND MAY TRAVEL LONG DISTANCES TO A SOURCE OF IGNITION AND FLASH
BACK. VAPORS CAN FORM EXPLOSIVE MIXTURES IN AIR AT ELEVATED TEMPERATURES.
CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. MAY
DECOMPOSE UNDER FIRE CONDITIONS EMITTING IRRITANT AND/OR TOXIC GASES.

FIRE FIGHTING PROCEDURES

WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. FIREFIGHTERS
SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION, AND SELF-CONTAINE BREATHING APPARATUS. HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS
CARBON MONOXIDE, CARBON DIOXIDE, TOXIC GASES. OXIDES OF CALCIUM.

SECTION 6: ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLE
COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS.
ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. VENTILATE AREA WITH
EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING TOOLS. EVACUATE ALL
UNNECESSARY PERSONNEL. PLACE COLLECTED MATERIAL IN PROPER CONTAINER.
COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE USED DURING CLEANUP.
LARGE SPILLS: SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL.
PUMP TO STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO
PICK UP EXCESS RESIDUE. KEEP SALVAGEABLE MATERIAL AN RINSE WATER OUT OF SEWERS AND WATER COURSES.

SMALL SPILLS: USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY.

SECTION 7: HANDLING AND STORAGE

STORE BELOW 80F. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME.

OTHER PRECAUTIONS:

USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP
OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AN BREATHING OF VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING,
ESPECIALLY BEFORE EATING OR SMOKING. KEEP CONTAINERS TIGHTLY CLOSE AND UPRIGHT WHEN NOT IN USE. EMPTY CONTAINERS MAY CONTAIN
HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN TRANSFERRING TO
PREVENT ACCUMULATION OF STATIC CHARGE.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

COMMON NAME: 2-METHYLPENTANE
CAS NUMBER: 107-83-5
ACGIH(TWA): 500 PPM
ACGIH(STEL): C 1000 PPM

COMMON NAME: LIMESTONE
CAS NUMBER: 1317-65-3
ACGIH(TWA): 10 MG/M3 OSHA(TWA): 5 MG/M3

COMMON NAME: CLAY
CAS NUMBER: 1332-58-7
ACGIH(TWA): 2 MG/M3 OSHA(TWA): 5 MG/M3

COMMON NAME: QUARTZ
CAS NUMBER: 14808-60-7
ACGIH(TWA): .05 MG/M3 OSHA(TWA): 0.1 MG/M3

COMMON NAME: LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)
CAS NUMBER: 64742-89-8
OSHA(TWA): 300 PPM

COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 75-83-2
ACGIH(TWA): 500 PPM
ACGIH(STEL): 1000 PPM

COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 79-29-8
ACGIH(TWA): 500 PPM
ACGIH(STEL): 1000 PPM
COMMON NAME: 3-METHYL PENTANE
CAS NUMBER: 96-14-0
ACGIH(TWA): 500 PPM
ACGIH(STEL): 1000 PPM

RESPIRATORY PROTECTION

CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE EXPOSURE
STANDARDS WHEN USING THIS MATERIAL. WHEN RESPIRATORY PROTECTION IS
DETERMINED TO BE NECESSARY, USE A NIOSH/MSHA (CANADIAN Z94.4) APPROVE ELASTOMERIC SEALING- SURFACE FACEPIECE RESPIRATOR OUTFITTED WITH ORGANIC
VAPOR CARTRIDGES AND PAINT SPRAY (DUST/MIST) PREFILTERS. DETERMINE THE
PROPER LEVEL OF PROTECTION BY CONDUCTING APPROPRIATE AIR MONITORING.
CONSULT 29CFR1910.134 FOR SELECTION OF RESPIRATORS (CANADIAN Z94.4).

VENTILATION: PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT
BUILD-UP OF VAPORS. USE EXPLOSION-PROOF EQUIPMENT. USE NON-
SPARKING EQUIPMENT.

PERSONAL PROTECTIVE EQUIPMENT: EYE WASH, SAFETY SHOWER, SAFETY
GLASSES OR GOGGLES. IMPERVIOUS
GLOVES, IMPERVIOUS CLOTHING

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

VAPOR PRESSURE: NOT AVAILABLE SPECIFIC GRAVITY: 1.132
BOILING RANGE (F/C): 122-185/ 50- 85 WEIGHT PER GALLON: 9.43/ 11.32IMP
%VOLATILE BY VOLUME: 57.74 PHYSICAL STATE: PASTE
APPEARANCE: TAN SOLUBLE IN WATER: N
PH: NOT APPLICABLE

SECTION 10: STABILITY AND REACTIVITY

UNDER NORMAL CONDITIONS: STABLE - SEE SECTION 5 FIRE FIGHTING MEASURES

MATERIALS TO AVOID: OXIDIZERS, ACIDS. STYRENE MONOMER.

CONDITIONS TO AVOID: ELEVATED TEMPERATURES, CONTACT WITH
OXIDIZING AGENT, SPARKS, OPEN FLAME, IGNITION
SOURCES

HAZARDOUS POLYMERIZATION: WILL NOT OCCU

SECTION 11: TOXICOLOGICAL INFORMATION

COMMON NAME: 2-METHYLPENTANE
CAS NUMBER: 107-83-5
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO

COMMON NAME: LIMESTONE
CAS NUMBER: 1317-65-3
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
LD50: 6450.00 MG/KG ORL RAT
COMMON NAME: CLAY
CAS NUMBER: 1332-58-7
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO

COMMON NAME: QUARTZ
CAS NUMBER: 14808-60-7
CARCINOGENICITY LISTED BY: NTP YES IARC YES 1 OSHA NO ACGIH NO

COMMON NAME: LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)
CAS NUMBER: 64742-89-8
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO
LD50:> 3.16 GM/KG SKN RBT
LD50:> 5.00 GM/KG ORL RAT

COMMON NAME: AROMATIC HYDROCARBON RESIN
CAS NUMBER: 68410-16-2
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO

COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 75-83-2
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO

COMMON NAME: DIMETHYLBUTANE
CAS NUMBER: 79-29-8
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO

COMMON NAME: STYRENE-BUTADIENE POLYME CAS NUMBER: 9003-55-8
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO

COMMON NAME: 3-METHYL PENTANE
CAS NUMBER: 96-14-0
CARCINOGENICITY LISTED BY: NTP NO IARC NO OSHA NO ACGIH NO

SUPPLEMENTAL HEALTH INFORMATION

CONTAINS A CHEMICAL THAT MAY BE ABSORBED THROUGH SKIN.

NOTICE: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGE OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN
AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE
HARMFUL OR FATAL. OTHER EFFECTS OF OVEREXPOSURE MAY INCLUDE
TOXICITY TO CENTRAL NERVOUS SYSTEM.

CARCINOGENICITY: CONTAINS CRYSTALLINE SILICA WHICH IS CONSIDERED A
HAZARD BY INHALATION. IARC HAS CLASSIFIE CRYSTALLINE SILICA AS CARCINOGENIC TO HUMANS
(GROUP 1). CRYSTALLINE SILICA IS ALSO A KNOWN CAUSE
OF SILICOSIS, A NONCANCEROUS LUNG DISEASE. THE
NATIONAL TOXICOLOGY PROGRAM (NTP) HAS CLASSIFIE CRYSTALLINE SILICA AS A KNOWN HUMAN CARCINOGEN.

REPRODUCTIVE EFFECTS: NO REPRODUCTIVE EFFECTS ARE ANTICIPATE MUTAGENICITY: NO MUTAGENIC EFFECTS ARE ANTICIPATE
TERATOGENICITY: NO TERATOGENIC EFFECTS ARE ANTICIPATE

SECTION 12: ECOLOGICAL INFORMATION

NO ECOLOGICAL TESTING HAS BEEN DONE BY ICI PAINTS ON THIS PRODUCT
AS A WHOLE.

SECTION 13: DISPOSAL CONSIDERATIONS

WASTE DISPOSAL: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
AVOID DISCHARGE TO NATURAL WATERS.

SECTION 14: TRANSPORT INFORMATION

DOT: ADHESIVES, 3, UN1133, PGIII

IMDG: ADHESIVES, CLASS 3, UN1133, PGIII, LIMITED QUANTITY,
ADHESIVES, CLASS 3, UN1133, PGIII

IATA: CONSUMER COMMODITY, 9, ID8000

TDG: NOT AVAILABLE

SECTION 15: REGULATORY INFORMATION

SARA SARA CERCLA HAZ AIR MARINE
302 313 302.4 POLLUTANT POLTNT

THIS PRODUCT CONTAINS NO SARA 302, CERCLA 302.4 OR HAZARDOUS AIR POLLUTANT
CHEMICALS. IT ALSO CONTAINS NO CHEMICALS WHICH ARE SUBJECT TO THE
REPORTING REQUIREMENTS UNDER SARA 313. AS OF THE DATE OF THIS MSDS, ALL OF
THE COMPONENTS IN THIS PRODUCT ARE LISTED (OR ARE OTHERWISE EXEMPT FROM
LISTING) ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN CLASSIFIED IN
ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR (CONTROLLED PRODUCTS
REGULATIONS) & THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.

SECTION 16: OTHER INFORMATION

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE AT THE TIME OF
PREPARATION OF THIS DATA SHEET AND WHICH ICI PAINTS BELIEVES TO BE RELIABLE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THIS DATA. ICI PAINTS SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS
INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS MENTIONED AND YOU
MUST MAKE YOUR OWN DETERMINATION OF ITS SUITABILITY AND COMPLETENESS FO YOUR OWN USE, FOR THE PROTECTION OF THE ENVIRONMENT, AND THE HEALTH AN SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL. COMPLIES WITH OSHA
HAZARD COMMUNICATION STANDARD 29CFR1910.1200.

;