Benzenesulfonylchloride, 3,5-dimethyl-

MSDS  :
 3,5-Dimethylbenzenesulfonyl chloride
CAS  
:
 2905-27-3
SYNONYMS  
:
 3,5-Xylenesulfonyl chloride.

Section 1 - Chemical Product and Company Identification
MSDS Name: 3,5-Dimethylbenzenesulfonyl chloride
Catalog Numbers: AC391590000, AC391590010, AC391590050
Synonyms:
3,5-Xylenesulfonyl chloride.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
2905-27-3 3,5-Dimethylbenzenesulfonyl chloride 97 unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: Not available.
Danger! Causes burns by all exposure routes. Water-reactive. Contact with water liberates toxic gas.
Target Organs: Respiratory system, gastrointestinal system, eyes, skin.


Potential Health Effects
Eye: Causes eye burns.
Skin: Causes skin burns. May be harmful if absorbed through the skin.
Ingestion: Causes gastrointestinal tract burns. May be harmful if swallowed.
Inhalation: Causes chemical burns to the respiratory tract. May be harmful if inhaled.
Chronic: No information found.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. Get medical aid immediately. Call a poison control center.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water reactive. Material will react with water and may release a flammable and/or toxic gas.
Extinguishing Media: Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 1; Instability: 2; Special Hazard: -W-

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Avoid generating dusty conditions. Provide ventilation. Do not expose spill to water. Do not get water inside containers. Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Do not allow water to get into the container because of violent reaction. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Do not allow contact with water. Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Store under nitrogen.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use only under a chemical fume hood.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
3,5-Dimethylbenzenesulfonyl chloride none listed none listed none listed

OSHA Vacated PELs: 3,5-Dimethylbenzenesulfonyl chloride: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:93 - 95 deg C
Decomposition Temperature:Not available.
Solubility: Reacts.
Specific Gravity/Density:Not available.
Molecular Formula:C8H9ClO2S
Molecular Weight:200.64

Section 10 - Stability and Reactivity


Chemical Stability: Reacts with water.
Conditions to Avoid: Incompatible materials, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials: Strong oxidizing agents, strong bases.
Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 2905-27-3 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 2905-27-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S. (3,5-Dimethylbenzenesulfonyl chloride) WATER-REACTIVE SOLID, CORROSIVE, N.O.S. (3,5-Dimethylbenzenesulfonyl chloride)
Hazard Class: 4.3 4.3
UN Number: UN3131 UN3131
Packing Group: II II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 2905-27-3 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 2905-27-3 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     C
Risk Phrases:

     R 29 Contact with water liberates toxic gas.
     R 34 Causes burns.

Safety Phrases:

     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
     otection.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).

WGK (Water Danger/Protection)

     CAS# 2905-27-3: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     This product has a WHMIS classification of E, F.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 2/08/2007
Revision #2 Date: 4/11/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

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Recommended suppliers

Dayang Chem (Hangzhou) Co.,Ltd.

China (Mainland) Assessed Supplier

3,5-dimethylbenzenesulfonyl chloride

  • Assay:Industrial Grade,
  • Appearance:detailed in specifications
  • Package:according to the clients requirement
  • Storage:Store in dry, dark and ventilated place.
  • Transportation:by air or by ocean shipping
  • Application:An important raw material and intermediate used in Organic Synthesis, Pharmaceuticals
Contact Supplier

Simagchem Corporation

China (Mainland) Assessed Supplier

High quality 3,5-Dimethylbenzenesulfonyl chloride with high purity

  • Assay:99%
  • Appearance:white-off solid or colorless liquid ( referto COA)
  • Package:25kgs/fiber drum or 200kgs/UN drum
  • Storage:in a cool and dry place
  • Transportation:by sea or by air
  • Application:organic intermediates
Contact Supplier

Amadis Chemical Co., Ltd.

China (Mainland) Assessed Supplier

3,5-Dimethylbenzenesulfonyl chloride

  • Assay:97%
  • Appearance:Powder or liquid
  • Package:According to customer
  • Storage:Store in a tightly closed container, in a cool and dry place.
  • Transportation:Fedex,DHL,TNT,BY SEA and BY AIR
  • Application:Medicinal Chemistry Biomedicine Pharmaceutical intermediates Chemistry experiment Biological experiments Chemical reagent For R&D use only.
Contact Supplier

Zhuozhou Wenxi import and Export Co., Ltd

China (Mainland) Assessed Supplier

Manufacturer supply CAS 2905-27-3 with best quality

  • Assay:98%,99%,
  • Appearance:White powder
  • Package: [Packaging]20mg, 50mg,100mg,1g,10g,100g,according to customers' requirements
  • Storage: should be stored in a well-closed container at low temperature, keep away from moisture, heat and light.
  • Transportation:1. Samples 1kg-10kg are shipped by international express. 2. 50kg-100kg of goods are transported by dedicated line logistics. 3. Cargo 100kg-1ton is transported by dedicated line logistics.
  • Application:Chemical raw materials, pharmaceutical intermediates, cosmetic raw materials, etc.
Contact Supplier

Suzhou Senfeida Chemical Co., Ltd

China (Mainland) Assessed Supplier

3,5-DIMETHYLBENZENESULFONYL CHLORIDE

  • Assay:99.0%
  • Appearance:Clear, colorless liquid
  • Package:according to your requirement
  • Storage:Store in a dry, dark and ventilated place
  • Transportation:by air/by sea /by train
  • Application:lt is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.
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