Propane,1,1,1,3,3-pentafluoro-
ER FOAM 902072-1 Winter
MSDS Number: foam902072-1W February 27, 2006
________________________________________
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
______________________
Product Identification
Product Name: ER FOAM 902072-1 Winter
Product Number: 2.0 pound density foam
Chemical Name: Polyurethane System Resin
Component
Chemical Family: NA
CAS Number: Blend
Company Identification
______________________
ERSystems- Elastomeric Roofing Systems, Inc.
6900 Bleck Dr
Rockford, MN 55373
1-800-403-7747 (For product information)
1-800-535-5053 Infotrac (For emergencies)
SPECIAL NOTES:
2.0 pound density polyurethane foam system resin component.
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT LISTING:
_____________
Chemical Name Amount
________ __________
CAS Number
AROMATIC AMINO POLYOL 15.0 - 25.0 % proprietary
POLYMER 15.0 - 25.0 % proprietary
HYRDOFLUOROCARBON 7.0 - 13.0 % 460-73-1
CHLORINATED PHOSPHATE ESTER 5.0 - 10.0 % proprietary
BROMINATED FLAME RETARDANT 3.0 - 7.0 % proprietary
ETHANOL, 2-[2-(DIMETHYLAMINO)ETHOXY]- < 2.0 % 1704-62-7
TERTIARY AMINE < 2.0 %
GLYCOL 1.0 - 5.0 % proprietary
(See Section 8 for exposure guidelines)
(See Section 15 for regulatory information)
HAZARDS DISCLOSURE
ER FOAM 902072-1 Winter
MSDS Number: foam902072-1W February 27, 2006
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(section 2 continued)
As defined under Sara 311 and 312, this product contains materials that
are acute, chronic hazards.
3. HAZARDS IDENTIFICATION
***************** EMERGENCY OVERVIEW *****************
* *
* WARNING *
* *
* May cause eye, skin and respiratory tract *
* irritation. May cause eye, skin and respiratory *
* tract irritation. Corrosive to skin. Severely *
* irritating to eyes, skin, respiratory tract. *
* Sensitizer. *
* *
**********************************************************
HMIS Rating - Health: 2*
Flammability: 1
Reactivity: 0
NFPA Rating - Health: 2
Flammability: 1
Reactivity: 0
POTENTIAL HEALTH EFFECTS
EYE:
Contact may cause eye irritation with symptoms of reddening, tearing,
stinging, and swelling. Possible permanent damage.
SKIN:
May cause allergic skin reaction. Dimethylaminoethanol is extremely
irritating to the skin. Direct contact with the skin is corrosive. Can
cause moderate skin irritation. Repeated skin contact may result in
sensitization.
INHALATION:
Avoid breathing vapors or mists. Prolonged or excessive inhalation may
cause respiratory tract irritation. Inhalation of high concentrations has
been known to produce respiratory difficulties, loss of coordination and
decreased motor activity in rats.
ER FOAM 902072-1 Winter
MSDS Number: foam902072-1W February 27, 2006
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(section 3 continued)
INGESTION:
Harmful if swallowed. Symptoms may include abdominal pain, nausea,
vomiting and diarrhea. Chronic ingestion may cause liver or kidney damage.
CHRONIC EFFECTS:
Repeated skin contact may result in sensitization. Repeated inhalation
has been known to produce effects on the eyes and nasal mucosa as well as
respiratory and olfactory lesions in experimental animals.
MISCELLANEOUS:
At levels above the recommended exposure limit, the fluorocarbon acts as a
weak narcotic. Acute overexposure causes tremors, confusion, irritation,
suffocation, and may result in cardiac sensitization.
4. FIRST AID MEASURES
EYE CONTACT FIRST AID:
After initial flushing, remove any contact lenses and continue flushing
for at least 15 minutes. Get medical attention.
SKIN CONTACT FIRST AID:
Remove and launder contaminated clothing and shoes before reuse. Wash
affected area immediately with large amounts of soap and water. Get
medical attention if irritation develops or persists.
INHALATION FIRST AID:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. Get immediate medical attention.
INGESTION FIRST AID:
If swallowed, do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get
immediate medical attention.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
TCC Flash Point: > 93.3 C (> 199.9 F)
Autoignition Temperature: N/A
ER FOAM 902072-1 Winter
MSDS Number: foam902072-1W February 27, 2006
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(section 5 continued)
FLAMMABLE LIMITS IN AI
LEL: N/A
UEL: N/A
EXTINGUISHING MEDIA:
Carbon dioxide, dry chemical, foam, water spray for large fires.
FIRE FIGHTING INSTRUCTIONS:
As in any fire, wear self-contained breathing apparatus pressure-demand
MSHA/NIOSH (approved or equivalent) and full protective gear.
MISCELLANEOUS:
Use cold water spray to cool fire-exposed containers to minimize risk of
rupture.
6. ACCIDENTAL RELEASE MEASURES
SAFEGUARDS (PERSONNEL):
Wear safety goggles. Wear appropriate personal protective equipment.
Ventilate spill area.
INITIAL CONTAINMENT:
Contain spilled material. Absorb spills with inert material.
LARGE SPILLS PROCEDURE:
Absorb spill with inert material (e g, dry sand or earth), then place in a
chemical waste container. Treat or dispose of waste material in
accordance with all local, state/provincial, and national requirements.
7. HANDLING AND STORAGE
RECOMMENDED STORAGE TEMPERATURE
Minimum: 7 C (44.6 F)
Maximum: 29 C (84.2 F)
SHELF LIFE: (in original, sealed containers)
6 months @ 7 C
6 months @ 29 C
HANDLING (PERSONNEL):
Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated
contact with skin. Wash hands thoroughly after handling.
ER FOAM 902072-1 Winter
MSDS Number: foam902072-1W February 27, 2006
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(section 7 continued)
HANDLING (PHYSICAL ASPECTS):
Avoid extreme temperatures. Close container after each use. Keep out of
reach of children. If contamination with isocyanates is suspected, do not
reseal containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS:
Use local exhaust to control vapors/mists.
EYE / FACE PROTECTION REQUIREMENTS:
Wear chemical goggles; also wear a face shield if splashing hazard exists.
SKIN PROTECTION REQUIREMENTS:
Selection of specific items such as gloves, boots, apron or full-body suit
will depend on operation. Wash hands thoroughly after handling.
RESPIRATORY PROTECTION REQUIREMENTS:
When there is potential for airborne exposures in excess of applicable
limits, wear NIOSH/MSHA approved respiratory protection.
EXPOSURE GUIDELINES:
No Information Available.
9. PHYSICAL AND CHEMICAL PROPERTIES
FORM ..................: Liquid, viscous
COLOR .................: Amber
ODOR ..................: Etherlike
BOILING POINT .........: NA F
SOLUBILITY IN WATER ...: Slight
SPECIFIC GRAVITY ......: 1.14 (Water = 1)
BULK DENSITY ..........: 9.5 lb/gallon
PH ....................: >7
10. STABILITY AND REACTIVITY
STABILITY:
Stable. Do not heat.
ER FOAM 902072-1 Winter
MSDS Number: foam902072-1W February 27, 2006
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(section 10 continued)
POLYMERIZATION:
Hazardous polymerization will not occur.
INCOMPATIBILITY WITH OTHER MATERIALS:
Avoid oxidizing agents, isocyanates.
DECOMPOSITION:
Decomposition products may be CO and CO2.
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL EFFECTS:
Aromatic Amino Polyol - LD50=2120 mg/kg (rat)
Polymer - LD50=1000 - 3000 mg/kg (rat)
Polyether Polyol - LD50= >5000 mg/kg (rat)
Chlorinated Phosphate Ester - LD50=632 mg/kg (rat)
2-(2-(dimethylamino)ethoxy)Ethanol - LD50=2000 - 5000 mg/kg (rat)
Tertiary Amine - LD50=1400 mg/kg (rat)
Glycol - LD50= >5000 mg/kg (rat) -- Lowest lethal dose: 1 ml/kg (human).
ACUTE INHALATION EFFECTS:
Polymer - LC50= >200 mg/L, 1hrs (rat)
Polyether Polyol - LC0=2516 mg/m3, 6hrs (rat)
Hydrofluorocarbon - LC50= >200,000 ppm, 4hrs (rat)
Chlorinated Phosphate Ester - LC50= >17,800 mg/L, 1hrs (rat)
Tertiary Amine - LC50=1.9 mg/L, 4hrs (rat).
12. ECOLOGICAL INFORMATION
No information available.
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Waste disposal should be in accordance with existing federal, state and
local environmental control laws.
ER FOAM 902072-1 Winter
MSDS Number: foam902072-1W February 27, 2006
____________________________________________________________________________________________________
(section 13 continued)
CONTAINER DISPOSAL:
Steel drums must be emptied (as defined by RCRA, Section 261.7 or state
regulations that may be more stringent) and can be sent to a licensed
drum reconditioner for reuse, a scrap metal dealer, or an approved
landfill. Drums destined for a scrap dealer or landfill must be
punctured or crushed to prevent reuse.
14. TRANSPORTATION INFORMATION
PRODUCT LABEL .............: ER FOAM 902072-1 Winter
D.O.T. SHIPPING NAME ......: N/A
TECHNICAL SHIPPING NAME ...: N/A
D.O.T. HAZARD CLASS .......: N/A
UN NUMBER .................: N/A
15. REGULATORY INFORMATION
No information available.
16. OTHER INFORMATION
PREPARED BY .......: Laura Vollenweider
APPROVED BY .......: Laura Vollenweider
TITLE .............: Chemist
APPROVAL DATE .....: February 10, 2006
SUPERCEDES DATE ...: New
MSDS NUMBER .......: foam902072-1W
RTN NUMBER ........: 00000120 (Official Copy)
ADDITIONAL INFORMATION:
The data in this Material Safety Data Sheet relates only to the specific
material designated herein.
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To the best of our knowledge, the information contained in this MSDS is
accurate. It is intended to assist the user in his evaluation of the
product's hazards, and safety precautions to be taken in its use. The
data in this MSDS relate only to the specific material designated herein.
We do not assume liability for the use of, or reliance on this
information, nor do we guarantee its accuracy or completeness.
ER FOAM 902072-1 Winter
MSDS Number: foam902072-1W February 27, 2006
____________________________________________________________________________________________________
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END OF MSDS
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