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Onium compounds, 1-[2-(2-carboxyethoxy)ethyl]-1(or3)-(2-carboxyethyl)-4,5-dihydro-2-norcoco alkylimidazoliumhydroxides, disodium salts

Material Safety Data Sheet

MIRANOL FBS
Date Prepared: 2/20/03 Supersedes Date: 7/18/01

1. PRODUCT AND COMPANY DESCRIPTION

RHODIA INC.
HOME, PERSONAL CARE & INDUSTRIAL INGREDIENTS
CN 7500
Prospect Plains Road
Cranbury NJ 08512-7500

Emergency Phone Numbers:
FOR EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT CONTACT: CHEMTREC (800-424-9300
within the United States or 703-527-3887 for international collect calls) or Rhodia CAERS (Communication and Emergency
Response System) at 800-916-3232.

For Product Information:
(800) 973-7873

Chemical Name or Synonym:
DISODIUM COCOAMPHO DIPROPIONATE

2. COMPOSITION/INFORMATION ON INGREDIENTS

OSHA
Component CAS Reg Number Percentage
Hazard
DISODIUM COCOAMPHO DIPROPIONATE 68604-71-7 N > 38
METHANOL 67-56-1 Y <5
WATER/INERTS ************ N < 57

3. HAZARDS IDENTIFICATION

A. EMERGENCY OVERVIEW:

Physical Appearance and Odor:
amber thin liquid, alcohol-like odor.

Warning Statements:
WARNING!! COMBUSTIBLE LIQUID. EYE IRRITANT.

B. POTENTIAL HEALTH EFFECTS:

Acute Eye:
Irritant. Can cause redness, irritation, tearing.

Acute Skin:
Low acute dermal toxicity. Non-irritating. May cause redness, irritation, on prolonged contact.
Acute Inhalation:
Low acute inhalation toxicity. Mists may cause dizziness, headache, upper respiratory tract irritation.

Acute Ingestion:
Practically non-toxic. May cause blindness.

Chronic Effects:
This product does not contain any ingredient designated by IARC, NTP, ACGIH or OSHA as probable or suspected human
carcinogens.

4. FIRST AID MEASURES

FIRST AID MEASURES FOR ACCIDENTAL:

Eye Exposure:
Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek medical attention.

Skin Exposure:
In case of contact, immediately wash with plenty of soap and water for at least 5 minutes. Seek medical attention. Remove
contaminated clothing and shoes. Clean contaminated clothing and shoes before re-use.

Inhalation:
Inhalation is not an expected route of exposure. If respiratory irritation or distress occurs remove victim to fresh air. Seek medical
attention if respiratory irritation or distress continues.

Ingestion:
If victim is conscious and alert, give 1-2 glasses of water to drink. Do not give anything by mouth to an unconscious person. Seek
medical attention. Do not leave victim unattended.

MEDICAL CONDITIONS POSSIBLY AGGRAVATED BY EXPOSURE:
Skin contact may aggravate existing skin disease.

NOTES TO PHYSICIAN:
All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the
possibility that overexposure to materials other than this product may have occurred.

Treat symptomatically. No specific antidote available.

5. FIRE FIGHTING MEASURES

FIRE HAZARD DATA:

Flash Point:
62 C (144 F). Flammability Class: COMBUSTIBLE.

Method Used:
Closed cup

Flammability Limits (vol/vol%): Lower: Upper:
No Data No Data

Extinguishing Media:
Recommended (small fires): dry chemical, carbon dioxide, Recommended (large fire): alcohol foam, universal foam, water spray,
Not recommended: water jet (frothing possible).
Special Fire Fighting Procedures:
Firefighters should wear NIOSH/MSHA approved self-contained breathing apparatus and full protective clothing.

Unusual Fire and Explosion Hazards:
Product will burn under fire conditions. Closed containers may explode (due to the build-up of pressure) when exposed to extreme
heat.

Hazardous Decomposition Materials (Under Fire Conditions):
oxides of nitrogen
oxides of carbon

6. ACCIDENTAL RELEASE MEASURES

Evacuation Procedures and Safety:
Wear appropriate protective gear for the situation. See Personal Protection information in Section 8.

Containment of Spill:
Follow procedure described below under Cleanup and Disposal of Spill.

Cleanup and Disposal of Spill:
Absorb with an inert absorbent. Sweep up and place in an appropriate closed container (see Section 7: Handling and Storage).
Clean up residual material by washing area with water. Collect washings for disposal.

Environmental and Regulatory Reporting:
Do not flush to drain. Spills may be reportable to the National Response Center (800-424-8802) and to state and/or local
agencies.

7. HANDLING AND STORAGE

Minimum/Maximum Storage Temperatures:
10 to 49 C (50 to 120 F)

Handling:
Avoid breathing vapors and mists. Avoid direct or prolonged contact with skin and eyes. DO NOT ALLOW TO FREEZE. Use
nonsparking tools and grounded/bonded equipment and containers when transferring.

Storage:
SHIP AND STORE BETWEEN 50-120 F. Store in tightly closed containers. Store in an area that is dry, well-ventilated, away from
ignition sources, away from incompatible materials (see Section 10. Stability and Reactivity).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Introductory Remarks:
These recommendations provide general guidance for handling this product. Because specific work environments and material
handling practices vary, safety procedures should be developed for each intended application. While developing safe handling
procedures, do not overlook the need to clean equipment and piping systems for maintenance and repairs. Waste resulting from
these procedures should be handled in accordance with Section 13: Disposal Considerations.

Assistance with selection, use and maintenance of worker protection equipment is generally available from equipment
manufacturers.

Exposure Guidelines:
Exposure limits represent regulated or recommended worker breathing zone concentrations measured by validated sampling and
analytical methods, meeting the regulatory requirements. The following limits apply to this material, where, if indicated, S=skin and
C=ceiling limit:

METHANOL
Notes TWA STEL
ACGIH S 200 ppm 250 ppm
OSHA S 200 ppm 325 mg/cu m
OSHA S 260 mg/cu m 250 ppm

Engineering Controls:
Where engineering controls are indicated by use conditions or a potential for excessive exposure exists, the following traditional
exposure control techniques may be used to effectively minimize employee exposures: general area dilution/exhaust ventilation.

Respiratory Protection:
When respirators are required, select NIOSH/MSHA approved equipment based on actual or potential airborne concentrations
and in accordance with the appropriate regulatory standards and/or industrial recommendations.

For reasonably foreseeable industrial end uses of this material, respiratory protection should not be necessary.

Eye/Face Protection:
Eye and face protection requirements will vary dependent upon work environment conditions and material handling practices.
Appropriate ANSI Z87 approved equipment should be selected for the particular use intended for this material.

Eye contact should be prevented through use of chemical safety glasses with side shields or splash proof goggles. An emergency
eye wash must be readily accessible to the work area.

Skin Protection:
Skin contact should be minimized through use of gloves and suitable long-sleeved clothing (i.e., shirts and pants). Consideration
must be given both to durability as well as permeation resistance.

Work Practice Controls:
Personal hygiene is an important work practice exposure control measure and the following general measures should be taken
when working with or handling this material:
(1) Do not store, use, and/or consume foods, beverages, tobacco products, or cosmetics in areas where this material is
stored.
(2) Wash hands and face carefully before eating, drinking, using tobacco, applying cosmetics, or using the toilet.
(3) Wash exposed skin promptly to remove accidental splashes or contact with this material.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical and Chemical properties here represent typical properties of this product. Contact the business area using the Product
Information phone number in Section 1 for its exact specifications.

Physical Appearance:
amber thin liquid.

Odor:
alcohol-like odor.

pH:
9.4 to 9.8 at 100 wt/wt%.

Specific Gravity:
Not Available

Density:
1.05 to 1.09 g/ml at 25 C (77 F).
Water Solubility:
soluble

Melting Point Range:
Not Available

Freezing Point Range:
< 0 C (32 F)

Boiling Point Range:
> 98 C (208 F) at 760 mmHg

Vapor Pressure:
< 23.5 mmHg at 25 C (77 F)

Vapor Density:
Not Available

Percent Volatiles by Volume:
< 62

10. STABILITY AND REACTIVITY

Chemical Stability:
This material is stable under normal handling and storage conditions described in Section 7.

Conditions To Be Avoided:
heat
open flame
spark
static electricity

Materials/Chemicals To Be Avoided:
strong acids
strong oxidizing agents

The Following Hazardous Decomposition Products Might Be Expected:

Decomposition Type: thermal
oxides of nitrogen
oxides of carbon

Hazardous Polymerization Will Not Occur.

Avoid The Following To Inhibit Hazardous Polymerization:
not applicable

11. TOXICOLOGICAL INFORMATION

Acute Eye Irritation:
Toxicological Information and Interpretation:
eye - eye irritation, rabbit. Moderately irritating.

Acute Skin Irritation:
Toxicological Information and Interpretation:
skin - skin irritation, rabbit. Non-irritating.

Acute Dermal Toxicity:
No test data found for product.

Acute Respiratory Irritation:
No test data found for product.

Acute Inhalation Toxicity:
The following data is for the specified ingredients.
Toxicological Information and Interpretation:
LC50 - lethal concentration 50% of test species, 64000 ppm/1 hr, rat. Data for methyl alcohol.

Acute Oral Toxicity:
Ingestion of methanol can cause blindness in humans.
Toxicological Information and Interpretation:
LD50 - lethal dose 50% of test species, > 5 ml/kg, rat.

Chronic Toxicity:
This product does not contain any substances that are considered by OSHA, NTP, IARC or ACGIH to be "probable" or
"suspected" human carcinogens.

No additional test data found for product.

12. ECOLOGICAL INFORMATION

Ecotoxicological Information:
Ecotoxological Information and Interpretation:
EC50 - effective concentration 50% of test species, > 100 mg/l/48 hr, Daphnia magna.

Chemical Fate Information:
Inherently biodegradable.

13. DISPOSAL CONSIDERATIONS

Waste Disposal Method:
Chemical additions, processing or otherwise altering this material may make the waste management information presented in this
MSDS incomplete, inaccurate or otherwise inappropriate. Please be advised that state and local requirements for waste disposal
may be more restrictive or otherwise different from federal laws and regulations. Consult state and local regulations regarding the
proper disposal of this material.

Container Handling and Disposal:
Any containers or equipment used should be decontaminated immediately after use.

EPA Hazardous Waste - NO

14. TRANSPORTATION INFORMATION

Transportation Status: IMPORTANT! Statements below provide additional data on listed DOT classification.
The listed Transportation Classification does not address regulatory variations due to changes in package size, mode of shipment
or other regulatory descriptors.
US Department of Transportation
Hazard Class..... COMBUSTIBLE LIQUI Shipping Name:
COMBUSTIBLE LIQUID, N.O.S. (NOT REG'D IN CONTAINERS < 119 GALS)
Technical Shipping Name:
CONTAINS METHANOL
ID Number....... NA1993
Packing Group.... III
Labels........... NONE
Emergency Guide #.... 128

15. REGULATORY INFORMATION

Inventory Status
Inventory Status
UNITED STATES (TSCA) Y
CANADA (DSL) Y
EUROPE (EINECS/ELINCS) Y
AUSTRALIA (AICS) Y
JAPAN (MITI) N
SOUTH KOREA (KECL) Y

Y = All ingredients are on the inventory.
E = All ingredients are on the inventory or exempt from listing.
P = One or more ingredients fall under the polymer exemption or are on the no longer polymer list. All other ingredients are on the
inventory or exempt from listing.
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing.

FEDERAL REGULATIONS

Inventory Issues:
All functional components of this product are listed on the TSCA Inventory.

SARA Title III Hazard Classes:
Fire Hazard - YES
Reactive Hazard - NO
Release of Pressure - NO
Acute Health Hazard - YES
Chronic Health Hazard - NO

SARA 313 Chemicals
METHANOL (

SARA Extremely Hazardous Substances (EHS)/CERCLA Hazardous Substances
Ingredient CERCLA/SARA RQ SARA EHS TPQ
METHANOL 5000 lbs

STATE REGULATIONS:
This product does not contain any components that are regulated under California Proposition 65.

16. OTHER INFORMATION

National Fire Protection Association Hazard Ratings--NFPA(R):
Health Hazard Rating--Moderate
2
Flammability Rating--Moderate
2
Instability Rating--Minimal
0

National Paint & Coating Hazardous Materials Identification System--HMIS(R):

Health Hazard Rating--Moderate
2
Flammability Rating--Moderate
2
Reactivity Rating--Minimal
0

Reason for Revisions:
Change and/or addition made to Section 12.

Key Legend Information:
ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
TLV - Threshold Limit Value
PEL - Permissable Exposure Limit
TWA - Time Weighted Average
STEL - Short Term Exposure Limit
NTP - National Toxicology Program
IARC - International Agency for Research on Cancer
ND - Not determined
RPI - Rhodia Established Exposure Limits

Disclaimer:
The information herein is given in good faith but no warranty, expressed or implied, is made.

** End of MSDS Document **

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