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Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, hydrolysis products with silica

XEROX Material Safety Data Sheet MSDS No: A15
Date: 11/19/97
Revision: 12/20/02

Manufacturer: Xerox Corporation Telephone # (s): Safety Information: (800) 828-6571
Rochester, NY 14644 Health Emergency: (585) 422-2177
Transportation Emergency (Chemtrec): (800) 424-9300

Section I - Product Identification

Trade Names/Synonyms: Xerox 00A/03A/06A/09A/27X/29X/75A/82X/91A/ Part No.: 6R900, 6R901, 6R903,
92A/96A/98A/98X HP Compatible Printer Toner Cartridge / 6R904, 6R905, 6R906
Xerox FX1, Canon Compatible Fax Toner Cartridge 6R907, 6R908, 6R925
6R926, 6R927, 6R928
Chemical Name: None 6R929, 6R930, 6R1062

WHMIS Status: This is not a WHMIS controlled product.
Ingredients (% by wt.) CAS No.
Styrene/acrylate copolymer (>40%) 25036-16-2/25767-47-9/58048-89-9/25153-46-2
Magnetite (>30%) 1317-61-9/1309-38-2/12227-89-3
Polypropylene wax (>1%) 9003-
07-0
Amorphous silica (<3%) 67762/90-7/68909-20-6

Section II - Emergency and First Aid

Primary Route of Entry: Symptoms of Overexposure:
Inhalation Minimal respiratory tract irritation may occur as with
Eyes: exposure to large amounts of any non-toxic dust.
Flush thoroughly with water.
Skin: Medical Conditions Generally Aggravated by Exposure:
Wash with soap and water. None when used as described by product literature.
Inhalation:
Remove from exposure. Additional Information:
Ingestion: None
Dilute stomach contents with several glasses of water.

Section III - Toxicology and Health Information

This material has been evaluated by Xerox Corporation. The toxicity data noted below is based on test results of similar
xerographic toner materials.
10 mg/m3 (total dust)
Oral LD50: >5 g/kg (rats) practically non-toxic. TLV:
15 mg/m3 (total dust)
Dermal LD50: >5 g/kg (rabbits) practically non-toxic. PEL:
5 mg/m3 (respirable dust)
Inhalation LC50: >5 mg/l (rats, 4 hr exposure) practically non-toxic.
>20 mg/l (rats, calculated 1 hr exposure) non-poisonous, DOT. STEL: N.E.
Eye Irritation: Not an irritant. Ceiling: N.E.
XEL1: 2.5 mg/m3 (total dust)
Skin Sensitization: Not a sensitizer.
0.4 mg/m3 (respirable dust)
Skin Irritation: Not an irritant.
Human Patch: Non-irritating, non-sensitizing.
Mutagenicity: No mutagenicity in Ames.
Carcinogens: None present
Aquatic LC50: N.D.
Additional Information: The results obtained from a Xerox sponsored Chronic Toner Inhalation Study, demonstrated no lung change in rats for the
lowest (1mg/m3) exposure level (i.e. the level most relevant to potential human exposure). A very slight degree of fibrosis was noted in 25% of the
animals at the middle (4mg/m3) exposure level, while a slight degree of fibrosis was noted in all the animals at the highest (16 mg/m3) exposure level.
These findings are attributed to "lung overloading", a generic response to excessive amounts of any dust retained in the lungs for a prolonged period. This
study was conducted using a special test toner to comply with EPA testing protocol. The test toner was ten times more respirable than commercially
available Xerox toner, and would not be functionally suitable for Xerox equipment.
1
XEL-Xerox Exposure Limit. N.A. - Not Applicable N.E. -None Established N.D. -Not Determined
XEROX Trade Name: Xerox 00A/03A/06A/09A/27X/29X/75A/82X/91A/92A/96A/98A/98X MSDS No.: A15
HP Compatible Printer Toner Cartridge / Xerox FX1, Canon
Compatible Fax Toner Cartridge

Section IV - Physical Data

Appearance/Odor: Black powder/ faint odor Softening Range: 125 to 150 ??F
Boiling Point: N.A. Melting Point: N.A.
Solubility in Water: Negligible Specific Gravity (H2O=1): 1.8
Evaporation Rate: N.A. Vapor Pressure (mm Hg): N.A.
Vapor Density (Air=1): N.A. pH: N.A.
Volatile: N.D. % (Wt.) N.D. % (Vol.)

Section V - Fire and Explosion Data

Flash Point (Method Used): N.A.
Flammable Limits: LEL: N.A., UEL: N.A.
NFPA 704: Health - 0, Fire - 1, Reactivity - 0 (for uncontained toner: Health - 0, Fire - 3, Reactivity - 0)
Extinguishing Media: Water fog, chemical foam, or carbon dioxide.
Special Fire Fighting Procedures: Avoid inhalation of smoke. Wear protective clothing and
self-contained breathing apparatus.
Fire and Explosion Hazards: Toner is a combustible powder. Like most organic materials in powder form, it can form
explosive mixtures when dispersed in air.

Section VI -Reactivity Data

Stability: Stable
Hazardous Polymerization: Will Not Occur
Hazardous Decomposition Products: CO and CO2
Incompatibility (Materials to Avoid): None known.

Section VII - Special Protection Information

Respiratory Protection: None required when used as intended.
Eye Protection: None required when used as intended.
Protective Gloves: None required when used as intended.
Other: For use other than normal customer - operating procedures (such as in bulk toner processing
facilities), goggles and respirators may be required. For more information, contact Xerox.

Section VIII - Special Precautions

Handling and Storage: Use with adequate ventilation.
Conditions to Avoid: Avoid prolonged inhalation of excessive dust.

Section IX- Spill, Leak, and Disposal Procedures
For Spills or Leakage: Sweep up or vacuum spilled toner and carefully transfer into sealable waste container. Sweep slowly
to minimize generation of dust during clean up. If a vacuum is used, the motor must be rated as dust
tight. A conductive hose bonded to the machine should be used to reduce static buildup (See Section
V). Residue can be removed with soap and cold water. Garments may be washed or dry-cleaned,
after removal of loose toner.
Waste Disposal Method: This cartridge intended to be reclaimed by Xerox Corporation. Return instructions can be found as
part of the initial packaging. This material is not a hazardous waste according to Federal Regulation
40 CFR 261 when disposed. State and Local requirements may however be more restrictive.
Consult with the appropriate State and Local waste disposal authorities for additional information.

Section X - Transportation Information

DOT Proper Shipping Name: N.A. (Not Regulated) ID Number: N.A.
Hazard Classification: N.A. Packing Group: N.A.

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