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2-(2,4-Diaminophenoxy)ethanol sulfate

WELLA AG
Safety Data Sheet
according to ANSI Z400.1-1998

MIDWAY HAIR COLO Print date : 18.04.2005 Product code : MIDWAY
1. Product and Company Identification

1.1 Commercial product name
MIDWAY HAIR COLO Further product name
SHADES AND FORMULA NUMBERS:
1N Black=73726000300 ; 2/3N Dark Brown=73726010300 ; 3/4G Dark Golden Brown=73726080300 ;
4/5A Ash Brown=73726050400 ; 4/5N Brown=73726020400 ; 5/6G Golden Brown=73726090300 ; 5/6RV
Red Brown=73726130300 ; 6/7A Ash Blonde=73726060300 ; 6/7N Blonde=73726030400 ; 7/8G Golden
Blonde=73726100400 ; 7/8RG Red Blonde=73726110400 ; 8/9A Light Ash Blonde=73726070400 ; 8/9N
Light Blonde=73726040400 ; Cleartone=73726140400

( preparation )
Chemical characterization :
Finished product: maximum 4% dyes
1.2 Information manufacturer / supplier
WELLA CORPORATION - 6109 De Soto Avenue - Woodland Hills, CA 91367
Company name :
Telephone: (818) 999-5112
Prepared by: WELLA AG - Berliner Allee 65 - D--64274 Darmstadt
Telephone : 0049 -(0)6151-34-0
Contact person : RD-PSCE-Herr Schoder
Telefax : 0049-(0)6151-
e-mail : WSchoder@Wella.de
342748
Internet : www.wella.de
Inquiry office : Emergency telephone USA only: call CHEMTREC 1-800-424-9300
Emergency telephone : 0049-(0)-6151-340-
Germany

2. Composition / Information on Components

Hazardous components
CAS No. Components Quantity
2835-95-2 5-AMINO-O-CRESOL (4-AMINO-2-HYDROXYTOLUENE) max.<1%
608-25-3 2-METHYLRESORCINOL max.<1%
90-15-3 1-NAPHTHOL max.<1%
2835-99-6 4-AMINO-M-CRESOL max.<1%
1310-73-2 SODIUM HYDROXIDE max.<1%
6369-59-1 2-METHYL-P-PHENYLENE DIAMINE SULFATE (TOLUENE-2,5-DIAMINE SULFATE) max.<2%
1336-21-6 AMMONIA,AQUEOUS SOLUTION 25% 1% - 5%
6358-09-4 2-AMINO-6-CHLORO-4- NITROPHENOL max.<1%
68140-00-1 AMIDES,COCO-,N-(HYDROXYETHYL)- (COCAMIDE MEA) 1% - 5%
9002-92-0 2-[2-(DODECYLOXY)ETHOXY]ETHANOL (LAURETH-2) 1% - 5%
108-46-3 RESORCINOL max.<1%
70643-20-8 [4-(2-HYDROXYETHOXY)-1,3-PHENYLENE]DIAMMONIUMSULPHATE (2,4- max.<1%
DIAMINOPHENOXYETHANOL SULFATE)
591-27-5 3-AMINOPHENOL (M-AMINOPHENOL) max.<1%
83763-48-8 (3-AMMONIO-4-METHOXYPHENYL)(2-HYDROXYETHYL)AMMONIUM SULPHATE (2-AMINO- max.<0.1%
4-HYDROXYETHYLAMINOANISOLE SULFATE)
1335-72-4 SODIUM 2-(2-(DODECYLOXY ETHOXY)ETHYL SULPHATE,28% (SODIUM LAURETH 5% - 10%
SULFATE)

Revision no. : USA - EN Revision date : 18.04.2005
WELLA AG
Safety Data Sheet
according to ANSI Z400.1-1998

MIDWAY HAIR COLO Print date : 18.04.2005 Product code : MIDWAY
3. Hazards Identification

Route(s) of Entry
Inhalation Yes
Ingestion: Yes
Skin: Yes
Signs and Symptoms of Exposure
Harmful if swallowed.
May cause sensitization by skin contact.
May produce an allergic reaction.
Irritating to eyes.
May cause skin irritation.

Carcinogenicity (NTP) : No
Carcinogenicity (IARC) : No
Carcinogenicity (OSHA) : No

4. First Aid Measures

General information
Immediately rinse any splashes on the skin and clothing
After inhalation
Move to fresh air.If symptoms persist, call a physician.
After contact with skin
Wash off with soap and water.
If skin irritation persists, call a physician.
After contact with eyes
Flush eye(s) immediately with plenty of water.
If eye irritation persists, consult a specialist.
After ingestion
Do not induce vomiting.
Clean mouth with water and drink afterwards plenty of water.
Call a physician or Poison Control Centre immediately.

5. Fire Fighting Measures

Suitable extinguishing media
sprayed water stream
foam
chemical fire extinguisher
carbon dioxide (CO2)

Special exposure hazards arising from the chemical
The release of the following substances is possible in a fire:
nitrogen oxides (NOx) ;
sulphur oxides ;
carbon oxides
Special protective equipment for firefighters
Wear self-contained breathing apparatus and protective suit.

Revision no. : USA - EN Revision date : 18.04.2005
WELLA AG
Safety Data Sheet
according to ANSI Z400.1-1998

MIDWAY HAIR COLO Print date : 18.04.2005 Product code : MIDWAY
Additional information
Contaminated extinguishing water and soil must be disposed of in accordance with official regulations.

6. Accidental Release Measures

Personal precautions
Avoid contact with skin, eyes and clothing.
Do not breath in vapours.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.
Methods for cleaning up/taking up
Wipe up with absorbent material (e.g. cloth, fleece).
After cleaning, flush away traces with water.

7. Handling and Storage

7.1 Handling
Advice on safe handling
Avoid contact with skin, eyes and clothing.
Do not breathe vapour .
Provide sufficient air exchange and/or exhaust in work rooms.
Advice on protection against fire and explosion
non-combustible
If the components are mixed in a bottle:Do not leave the mixture in the closed bottle(bottle may
expand/burst)
Further information on handling
Follow the instructions
Do not use hair dyes if you have already experienced an adverse reaction to a hair colorant.
Do not use the hairv dye if the scalp is sensitive or shows abrasions or scratches.
Do not use to dye eyelashes or eyebrows.
Use mixture immediately.Do not use any leftovers - Dispose of promptly..
Do not exceed the development time stated
Rinse hair well after application
Do not use when the hair has previously been coloured with metal dyes
Do not perm the hair immediately before or after dyeing the hair.

7.2 Storage
Requirements for storage rooms and vessels
Keep in a dry, cool place.
Protect from heat and direct sunlight.
Keep out of reach of children.
Further information on storage conditions
Keep at temperatures above -10 ??C.
Keep at temperature not exceeding 40 ??C.

8. Exposure Controls / Personal Protection

8.1 Exposure limit values

Revision no. : USA - EN Revision date : 18.04.2005
WELLA AG
Safety Data Sheet
according to ANSI Z400.1-1998

MIDWAY HAIR COLO Print date : 18.04.2005 Product code : MIDWAY
Permissible exposure limits (PEL)
CAS No. Components ml/m3 mg/m3 fib/cc Category Origin
7664-41-7 Ammonia 50 35 TWA (8 h) PEL
1310-73-2 Sodium hydroxide - 2 TWA (8 h) PEL

8.2 Exposure controls
Occupational exposure controls
The maximum occupational exposure limit will not be reached under normal conditions of use
Protective and hygiene measures
When using, do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
preventive skin protection
Hand protection
Wear enclosed gloves.
9. Physical and Chemical Properties

9.1 Appearance
Form : creme ; viscous
Colour : various
Odour : perfumed ; ammoniacal
9.2 Important health, safety and environmental information

Changes in the physical state
Flash point : non-combustible
Test method: Pensky- Martens Closed Cup ASTM, D93

Explosive properties
Not applicable
Oxidizing properties
Not applicable
Density : 0.98 - 1.00 g/cm3
Water solubility : completely miscible

10. Stability and Reactivity
Stability
Stable
Materials to avoid
strong oxidising agents
Possibility of Hazardous Reactions
May occur

11. Toxicological Information
Acute toxicity

Revision no. : USA - EN Revision date : 18.04.2005
WELLA AG
Safety Data Sheet
according to ANSI Z400.1-1998

MIDWAY HAIR COLO Print date : 18.04.2005 Product code : MIDWAY Harmful if swallowed.

2-METHYL-P-PHENYLENE DIAMINE SULFATE (TOLUENE-2,5-DIAMINE SULFATE) :
LD50/oral/rat = 98 mg/kg (RTECS)
LD50/dermal/rabbit = 1120 mg/kg (RTECS)
Irritancy and corrosivenes
Eye irritation:
Irritating to eyes.
Skin irritation:
May cause skin irritation.
Sensitising effect
May cause sensitization by skin contact.
May produce an allergic reaction. .
Subacute, subchronic and prolonged toxicity
Repeated or long term contact can lead to skin irritations.

12. Ecological Information

Ecotoxicity
Contains substances very toxic to aquatic organisms.
Persistence and degradability
Some constituents are not readily biodegradable.

13. Disposal Considerations

Advice on disposal
The bottle must be completely empty before disposal
Dispose of as hazardous waste in compliance with local and national regulations.

14. Transport Information
US DOT 49 CFR 172.101
Propper Shipping Name
DOT Class: not regulated
Land transport (ADR/RID)
Inland waterways transport
Marine transport
Air transport
Futher Information
Not classified as dangerous in the meaning of transport regulations.

15. Regulatory Information
U.S. Regulations

16. Other Information
Other data
Canada:WHMIS classification: D2B

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data
sheet.)

Revision no. : USA - EN Revision date : 18.04.2005

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