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Zinc phosphate tetrahydrate

0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME
0890 100 61 - WURTH B+S METAL PRIMER 250ML

STATEMENT OF HAZARDOUS NATURE
Considered a Hazardous Substance according to the criteria of the New
Zealand Hazardous Substances New Organisms legislation.

OTHER NAMES

primer, "adhesion promoter"

PROPER SHIPPING NAME
RESIN SOLUTION, flammable

PRODUCT USE
Primer/adhesion promoter.
The use of a quantity of material in an unventilated or confined space may result in
increased exposure and an irritating atmosphere developing.
Before starting consider control of exposure by mechanical ventilation.

SUPPLIE Company: Wurth New Zealand Limited
Address:
42 Hobill Avenue
Manukau City
Auckland
NZL
Telephone: 0800 683 040
Fax: 0800 100 104

Section 2 - HAZARDS IDENTIFICATION

GHS Classification
Acute Toxicity (Inhalation) Category 3
Chronic Aquatic Hazard Category 3
Eye Irritation Category 2A
Flammable Liquid Category 2
Respiratory Irritation Category 3
Skin Corrosion/Irritation Category 3

EMERGENCY OVERVIEW

HAZAR DANGE Determined by Chemwatch using GHS/HSNO criteria:
3.1B 6.1C 6.3B 6.4A 9.1C
May cause respiratory irritation
Highly flammable liquid and vapour
Toxic if inhaled
Causes mild skin irritation
Causes serious eye irritation

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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 2 - HAZARDS IDENTIFICATION

Harmful to aquatic life with long lasting effects

PRECAUTIONARY STATEMENTS

Prevention
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge
Avoid breathing dust/fume/gas/mist/vapours/spray.
Use only outdoors or in a well ventilated area.
Wash hands thoroughly after handling.
Keep container tightly closed.
Keep away from heat/sparks/open flame - No smoking.
Wear protective gloves and eye/face protection.
Use explosion-proof electrical/ventilating/lighting/equipment

Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
If eye irritation persists, get medical advice/attention.
Wear eye/face protection.
If skin irritation occurs, seek medical advice/attention.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Specific treatment: refer to Label or MSDS.
In case of fire, use foam for extinction.
If on skin or hair: remove/take off immediately all contaminated clothing. Rinse with
water/shower.
Call a POISON CENTER or doctor/physician if you feel unwell.

Storage
Store locked up.

Disposal
Dispose of contents and container in accordance with relevant legislation.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
ethyl acetate 141-78-6 25-50
n- butyl acetate 123-86-4 25-50
zinc phosphate 7779-90-0 1-2.4^
zinc oxide 1314-13-2 <1^

Section 4 - FIRST AID MEASURES

NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111

SWALLOWE ?? If swallowed do NOT induce vomiting.
?? If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
?? Observe the patient carefully.
?? Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.

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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 4 - FIRST AID MEASURES

?? Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
?? Seek medical advice.

EYE
If this product comes in contact with the eyes:
?? Wash out immediately with fresh running water.
?? Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
?? If pain persists or recurs seek medical attention.
?? Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.

SKIN
If skin contact occurs:
?? Immediately remove all contaminated clothing, including footwear.
?? Flush skin and hair with running water (and soap if available).
?? Seek medical attention in event of irritation.

INHALE ?? If fumes or combustion products are inhaled remove from contaminated area.
?? Lay patient down. Keep warm and rested.
?? Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
?? Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
?? Transport to hospital, or doctor.

NOTES TO PHYSICIAN
Treat symptomatically.
for simple esters:
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
?? Establish a patent airway with suction where necessary.
?? Watch for signs of respiratory insufficiency and assist ventilation as necessary.
?? Administer oxygen by non-rebreather mask at 10 to 15 l/min.
?? Monitor and treat, where necessary, for pulmonary oedema .
?? Monitor and treat, where necessary, for shock.
?? DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml
water (5 ml/kg recommended) for dilution where patient is able to swallow, has a strong
gag reflex and does not drool.
?? Give activated charcoal.
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
?? Consider orotracheal or nasotracheal intubation for airway control in unconscious
patient or where respiratory arrest has occurred.
?? Positive-pressure ventilation using a bag-valve mask might be of use.
?? Monitor and treat, where necessary, for arrhythmias.
?? Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers
solution. Fluid overload might create complications.
?? Drug therapy should be considered for pulmonary oedema.
?? Hypotension with signs of hypovolaemia requires the cautious administration of fluids.
Fluid overload might create complications.
?? Treat seizures with diazepam.
?? Proparacaine hydrochloride should be used to assist eye irrigation.
--------------------------------------------------------------
EMERGENCY DEPARTMENT
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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 4 - FIRST AID MEASURES

--------------------------------------------------------------
?? Laboratory analysis of complete blood count, serum electrolytes, BUN, creatinine,
glucose, urinalysis, baseline for serum aminotransferases (ALT and AST), calcium,
phosphorus and magnesium, may assist in establishing a treatment regime. Other useful
analyses include anion and osmolar gaps, arterial blood gases (ABGs), chest radiographs
and electrocardiograph.
?? Positive end-expiratory pressure (PEEP)-assisted ventilation may be required for acute
parenchymal injury or adult respiratory distress syndrome.
?? Consult a toxicologist as necessary.
BRONSTEIN, A.C. and CURRANCE, P.L. EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd
Ed. 1994.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
?? Alcohol stable foam.
?? Dry chemical powder.
?? BCF (where regulations permit).
?? Carbon dioxide.
?? Water spray or fog - Large fires only.

FIRE FIGHTING
?? Alert Fire Brigade and tell them location and nature of hazard.
?? May be violently or explosively reactive.
?? Wear breathing apparatus plus protective gloves.
?? Prevent, by any means available, spillage from entering drains or water course.
?? Consider evacuation (or protect in place).
?? Fight fire from a safe distance, with adequate cover.
?? If safe, switch off electrical equipment until vapour fire hazard removed.
?? Use water delivered as a fine spray to control the fire and cool adjacent area.
?? Avoid spraying water onto liquid pools.
?? Do not approach containers suspected to be hot.
?? Cool fire exposed containers with water spray from a protected location.
?? If safe to do so, remove containers from path of fire.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 500 metres in all directions.

FIRE/EXPLOSION HAZAR ?? Liquid and vapour are highly flammable.
?? Severe fire hazard when exposed to heat, flame and/or oxidisers.
?? Vapour may travel a considerable distance to source of ignition.
?? Heating may cause expansion or decomposition leading to violent rupture of containers.
?? On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of
burning organic material.

FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.

Personal Protective Equipment
Gloves, boots (chemical resistant).
Breathing apparatus.

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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2

Section 6 - ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES

MINOR SPILLS
?? Remove all ignition sources.
?? Clean up all spills immediately.
?? Avoid breathing vapours and contact with skin and eyes.
?? Control personal contact by using protective equipment.
?? Contain and absorb small quantities with vermiculite or other absorbent material.
?? Wipe up.
?? Collect residues in a flammable waste container.

MAJOR SPILLS
?? Clear area of personnel and move upwind.
?? Alert Fire Brigade and tell them location and nature of hazard.
?? May be violently or explosively reactive.
?? Wear breathing apparatus plus protective gloves.
?? Prevent, by any means available, spillage from entering drains or water course.
?? Consider evacuation (or protect in place).
?? No smoking, naked lights or ignition sources.
?? Increase ventilation.
?? Stop leak if safe to do so.
?? Water spray or fog may be used to disperse /absorb vapour.
?? Contain spill with sand, earth or vermiculite.
?? Use only spark-free shovels and explosion proof equipment.
?? Collect recoverable product into labelled containers for recycling.
?? Absorb remaining product with sand, earth or vermiculite.
?? Collect solid residues and seal in labelled drums for disposal.
?? Wash area and prevent runoff into drains.
?? If contamination of drains or waterways occurs, advise emergency services.

PROTECTIVE ACTIONS FOR SPILL
PROTECTIVE ACTION ZONE

half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE

From IERG (Canada/Australia)
Isolation Distance 25 metres
Downwind Protection Distance 300 metres
IERG Number 14

FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.

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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 6 - ACCIDENTAL RELEASE MEASURES

2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 127 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.

EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing

life-threatening health effects is:
ethyl acetate 2000 ppm
n-butyl acetate 3000 ppm
zinc phosphate 250 mg/m3

irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
ethyl acetate 400 ppm
n-butyl acetate 200 ppm
zinc phosphate 50 mg/m3

other than mild, transient adverse effects without perceiving a clearly defined odour is:
ethyl acetate 400 ppm
n-butyl acetate 5 ppm
zinc phosphate 6 mg/m3

The threshold concentration below which most people will experience no appreciable risk of health effects:
ethyl acetate 400 ppm
n-butyl acetate 5 ppm
zinc phosphate 2 mg/m3

American Industrial Hygiene Association (AIHA)

Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING
Contains low boiling substance:
Storage in sealed containers may result in pressure buildup causing violent rupture of

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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 7 - HANDLING AND STORAGE

containers not rated appropriately.
?? Check for bulging containers.
?? Vent periodically
?? Always release caps or seals slowly to ensure slow dissipation of vapours.
?? Avoid all personal contact, including inhalation.
?? Wear protective clothing when risk of exposure occurs.
?? Use in a well-ventilated area.
?? Prevent concentration in hollows and sumps.
?? DO NOT enter confined spaces until atmosphere has been checked.
?? Avoid smoking, naked lights, heat or ignition sources.
?? When handling, DO NOT eat, drink or smoke.
?? Vapour may ignite on pumping or pouring due to static electricity.
?? DO NOT use plastic buckets.
?? Earth and secure metal containers when dispensing or pouring product.
?? Use spark-free tools when handling.
?? Avoid contact with incompatible materials.
?? Keep containers securely sealed.
?? Avoid physical damage to containers.
?? Always wash hands with soap and water after handling.
?? Work clothes should be laundered separately.
?? Use good occupational work practice.
?? Observe manufacturer's storing and handling recommendations.
?? Atmosphere should be regularly checked against established exposure standards to
ensure safe working conditions.
DO NOT allow clothing wet with material to stay in contact with skin.

SUITABLE CONTAINE ?? Packing as supplied by manufacturer.
?? Plastic containers may only be used if approved for flammable liquid.
?? Check that containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS
?? Store in original containers in approved flame-proof area.
?? No smoking, naked lights, heat or ignition sources.
?? DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
?? Keep containers securely sealed.
?? Store away from incompatible materials in a cool, dry well ventilated area.
?? Protect containers against physical damage and check regularly for leaks.
?? Observe manufacturer's storing and handling recommendations.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m3 STEL ppm STEL mg/m3Peak ppm Peak mg/m3 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
New ethyl 200 720
Zealand acetate
Workplace (Ethyl
Exposure acetate)
Standards
(WES)
New n- butyl 150 713 200 950
Zealand acetate
Workplace (n- Butyl
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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Source Material TWA ppm TWA mg/m3 STEL ppm STEL mg/m3Peak ppm Peak mg/m3 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____

Exposure acetate)
Standards
(WES)

EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
ethyl acetate 2, 000 [LEL]
n- butyl acetate 1, 700 [LEL]

NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit
for safety considerations even though the relevant toxicological data indicated that
irreversible health effects or impairment of escape existed only at higher
concentrations.

ODOUR SAFETY FACTOR (OSF)
OSF=51 (ETHYL ACETATE)
Exposed individuals are reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class A or B.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:

Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested

.

MATERIAL DATA
Not available. Refer to individual constituents.

INGREDIENT DATA
ETHYL ACETATE:
N-BUTYL ACETATE:
Exposed individuals are reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class A or B.
The Odour Safety Factor (OSF) is defined as:
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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:

Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested

.

ETHYL ACETATE:

Odour Threshold Value: 6.4-50 ppm (detection), 13.3-75 ppm (recognition)
The TLV-TWA provides a significant margin of safety from the standpoint of
adverse health effects. Unacclimated subjects found the odour
objectionably strong at 200 ppm. Mild nose, eye and throat irritation was
experienced at 400 ppm. Workers exposed regularly at concentrations
ranging from 375 ppm to 1500 ppm for several months showed no unusual
signs or symptoms.

N-BUTYL ACETATE:

Odour Threshold Value: 0.0063 ppm (detection), 0.038-12 ppm (recognition)
Exposure at or below the recommended TLV-TWA is thought to prevent
significant irritation of the eyes and respiratory passages as well as
narcotic effects. In light of the lack of substantive evidence regarding
teratogenicity and a review of acute oral data a STEL is considered
inappropriate.

PERSONAL PROTECTION

EYE
?? Safety glasses with side shields.
?? Chemical goggles.
?? Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].

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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.

OTHE ?? Overalls.
?? PVC Apron.
?? PVC protective suit may be required if exposure severe.
?? Eyewash unit.
?? Ensure there is ready access to a safety shower.

RESPIRATO Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.

Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 A- AUS -
1000 50 - A- AUS
5000 50 Airline * -
5000 100 - A- 2
10000 100 - A- 3
100+ Airline**

* - Continuous Flow ** - Continuous-flow or positive pressure demand.

The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.

ENGINEERING CONTROLS
For flammable liquids and flammable gases, local exhaust ventilation or a process
enclosure ventilation system may be required. Ventilation equipment should be explosion
-resistant.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE
Yellow highly flammable liquid with an ester odour; does not mix
with water.

PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Sinks in water.

Molecular Weight: Not Applicable Boiling Range (?? Not Av ailable
C):
Melting Range (?? Not Available
C): Specific Gravity (water= 1): ~1.05
Solubility in water (g/L): Immiscible pH (as supplied): Not Available
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): >1 Flash Point (?? - 4
C):
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Autoignition Temp (?? Not Available
C): Decomposition Temp ( ?? Not Available
C):
State: Liquid Viscosity: Not Available

log Kow: 0.66-0.73
log Kow (Prager 1995): 1.82
log Kow (Sangster 1997): 1.78

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION

CONDITIONS CONTRIBUTING TO INSTABILITY
?? Presence of incompatible materials.
?? Product is considered stable.
?? Hazardous polymerisation will not occur.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
Harmful by inhalation. Repeated exposure may cause skin dryness and
cracking.
Irritating to eyes.
HARMFUL- May cause lung damage if swallowed.
Vapours may cause dizziness or suffocation.
Vapours may cause drowsiness and dizziness.

TOXICITY AND IRRITATION
Not available. Refer to individual constituents.

ETHYL ACETATE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 5620 mg/kg Eye (human): 400 ppm
Inhalation (rat) LC50: 1600 ppm/8h
Inhalation (human) TCLo: 400 ppm
Inhalation (Human) TCLo: 400 ppm/4h
Oral (Mouse) LD50: 4100 mg/kg
Intraperitoneal (Mouse) LD50: 709 mg/kg
Oral (Rabbit) LD50: 4935 mg/kg
Oral (Guinea) pig: LD50 5500 mg/kg

N-BUTYL ACETATE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 13100 mg/kg Skin (rabbit): 500 mg/24h- Moderate
Dermal (rabbit) LD50: 3200 mg/kg* Eye (rabbit): 20 mg (open)- SEVERE
Inhalation (human) TCLo: 200 ppm Eye (rabbit): 20 mg/24h - Moderate
Inhalation (rat) LC50: 2000 ppm/4h Eye ( human): 300 mg
Inhalation (Human) TCLo: 200 ppm/4h * [PPG]
Oral (Rat) LD50: 10768 mg/kg
Inhalation (Rat) LC50: 390 ppm/4h
Intraperitoneal (Mouse) LD50: 1230 mg/kg
Oral (Rabbit) LD50: 3200 mg/kg
Oral (Guinea) pig: LD50 4700 mg/kg
Intraperitoneal (Guinea) pig: LD 1500 mg/kg
The material may produce severe irritation to the eye causing pronounced inflammation.
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0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 11 - TOXICOLOGICAL INFORMATION

Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) and swelling the epidermis. Histologically there
may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of
the epidermis.

Section 12 - ECOLOGICAL INFORMATION

DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:

ETHYL ACETATE:
log Pow (Verschueren 1983): 0.66/0.73
ThOD: 50.4
log Pow (Verschueren 1983): 0.66/0.73
BOD5: 15%
COD: 1.54 (83%)
ThOD: 1.82
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 353
Half- life Air - Low (hours): 35.3
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 336
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 672
Aqueous biodegradation - Anaerobic - Low (hours): 96
Aqueous biodegradation - Removal secondary treatment - High (hours): 96%
Aqueous biodegradation - Removal secondary treatment - Low (hours): 99.90%
Photooxidation half- life water - High (hours): 9.60E+05
Photooxidation half- life water - Low (hours): 24090
Photooxidation half- life air - High (hours): 353
Photooxidation half- life air - Low (hours): 35.3
First order hydrolysis half- life (hours): 1.77E+04
Acid rate constant [M(H+)- HR]- 1: 3.05E- 08
Base rate constant [MOH)- HR]- 1: 2.99E- 05

DO NOT discharge into sewer or waterways.
log Kow: 0.66-0.73
Half-life (hr) air: 200
Half-life (hr) H2O surface water: 10
Henry's atm m3 /mol: 1.20E-04
BOD 5 if unstated: 0.1-1.24,16-36%
COD: 1.54,83%
ThOD: 1.82

N-BUTYL ACETATE:
Fish LC50 (96hr.) (mg/l): 18
Daphnia magna EC50 (48hr.) (mg/l): 44
log Kow (Prager 1995): 1.82
Fish LC50 (96hr.) (mg/l): 100- 185
Daphnia magna EC50 (48hr.) (mg/l): 44
Algae IC50 (72hr.) (mg/l): 280
log Kow (Sangster 1997): 1.78
continued...
0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2 Section 12 - ECOLOGICAL INFORMATION

COD: 78%

DO NOT discharge into sewer or waterways.
Half-life (hr) air: 144
Half-life (hr) H2O surface water: 178-27156
Henry's atm m3 /mol: 3.20E-04
BOD 5 if unstated: 0.15-1.02,7%
COD: 78%
ThOD: 2.207
BCF: 4-14
Toxicity Fish: LC50(96)100-185ppm
Toxicity invertebrate: cell mult. inhib.78-3700mg/L
Effects on algae and plankton: cell mult. inhib.21-280mg/L
Degradation Biological: sig
processes Abiotic: hydrol,RxnOH*

Section 13 - DISPOSAL CONSIDERATIONS

?? Consult manufacturer for recycling options and recycle where possible .
?? Consult State Land Waste Management Authority for disposal.
?? Incinerate residue at an approved site.
?? Recycle containers if possible, or dispose of in an authorised landfill.

Section 14 - TRANSPORTATION INFORMATION

Labels Required: FLAMMABLE LIQUI HAZCHEM: 3[Y]E

UNDG:
Dangerous Goods Class: 3 Subrisk: None
UN Number: 1866 Packing Group: II
Shipping Name:RESIN SOLUTION, flammable

Air Transport IATA:
ICAO/IATA Class: 3 ICAO/IATA Subrisk: None
UN/ID Number: 1866 Packing Group: II
ERG Code: 3L
Shipping name:RESIN SOLUTION, flammable

Maritime Transport IMDG:
IMDG Class: 3 IMDG Subrisk: None
UN Number: 1866 Packing Group: II
EMS Number: F- E, S- E
Shipping name:RESIN SOLUTION, flammable

continued...
0890 100 61 - WURTH B+S METAL PRIMER 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 30-Sep-2004 CHEMWATCH 4719-83
NA477ECP Version No:3
CD 2007/2

Section 15 - REGULATORY INFORMATION

REGULATIONS
ethyl acetate (CAS: 141-78-6) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances
(Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals

n-butyl acetate (CAS: 123-86-4) is found on the following regulatory lists;
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume List
New Zealand Hazardous Substances Transfer Notice 2004 - Schedule I, List of Substances
(Dangerous Goods) to be transferred
New Zealand Transferred List of Single Component Substances
New Zealand Workplace Exposure Standards (WES)
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic
Substances - Table II

Specific advice on controls required for materials used in
New Zealand can be found at
http://www.ermanz.govt.nz/search/registers.html

Section 16 - OTHER INFORMATION

NEW ZEALAND POISONS INFORMATION CENTRE
0800 POISON (0800 764 766)
NZ EMERGENCY SERVICES: 111

INGREDIENTS WITH MULTIPLE CAS NUMBERS

Ingredient Name CAS
zinc phosphate 7779- 90- 0, 7543- 51- 3

Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 30-Sep-2004
Print Date: 17-Jul-2007

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