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Thiosulfuric acid(H2S2O3), ammonium salt (1:2)

MATERIAL SAFETY DATA SHEET
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RA FILM FIXER REPLENISHE
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIE
RA Film Fixer Replenisher
Product Name
200861
Product Code
-
Other Names
Photographic Processing
Product Use
Australian Photographic Engineering Pty Ltd
Importer Name
1052 Dayboro Rd
Address
Kurwongbah QLD 4503
07 3889 8272
Telephone Number
1300 727 906
Emergency Telephone

2. HAZARDS IDENTIFICATION

HAZARDOUS SUBSTANCE. NON DANGEROUS GOODS.
Classified as hazardous according to the criteria of NOHSC.

Xn ?? Harmful
Hazards
R20 - Harmful by inhalation.
Risk Phrases
S2 - Keep out of reach of children.
Safety Phrases

3. COMPOSITION / INFORMATION ON INGREDIENTS

Ingredient (common name) CAS Number Proportion
ammonium thiosulphate 7783-18-8 10-30%
sodium sulphite 7757-83-7 1-5%
EDTA acid 60-00-4 >1%

4. FIRST AID MEASURES

Inhalation of the product is not likely to occur. In the event of
Inhalation
inhalation, move to fresh air and seek medical attention if
symptoms occur.
Immediately give 2-4 glasses of water. Induce vomiting by placing
Ingestion
the finger far back on tongue. Seek immediate medical attention.
Never give anything by mouth to an unconscious person.
Flush with running water for at least 20 minutes. Seek medical
Skin
attention if symptoms persist.
Flush with running water for at least 20 minutes holding the eyelids
Eyes
apart. Seek immediate medical attention.

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RA FILM FIXER REPLENISHE MATERIAL SAFETY DATA SHEET
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5. FIRE FIGHTING MEASURES

For major fires call the Fire Brigade. Ensure that an escape path is
available from any fire.
Suitable for the surrounding fire.
Suitable Extinguishing
Media
Oxides of sulphur, carbon, nitrogen and cyanide.
Hazardous Combustion
Products
Self-contained breathing apparatus and protective clothing.
Firefighting Equipment
No information available.
Unusual Fire or
Explosion Hazards
Not allocated.
Hazchem Code

6. ACCIDENTAL RELEASE MEASURES

Contain leak and spill from spreading. Wear protective clothing to
Spills
prevent contact with skin and eyes. Ensure spill area is well
ventilated. Prevent spillages from entering drain by absorption
using inert absorbent material (e.g. dry sand or earth) and transfer
to an approved container. Wash area with soap and water.

7. HANDLING AND STORAGE

Avoid contact with eyes, skin and clothing. Do not eat, drink, or
Handling
smoke when using this product. Ensure adequate ventilation,
especially over mixing vessels and processing tanks. Re-cap
containers after use.
Keep container tightly closed. Store in a dry, cool place and away
Storage
from acids, oxidizers and alkalis.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Standards Cyanide:
TWA: - ppm / 5mg/m3
(NOHSC)
STEL:- ppm / - mg/m3
Ensure good ventilation of the whole working area.
Engineering Controls

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RA FILM FIXER REPLENISHE MATERIAL SAFETY DATA SHEET
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Not required under normal circumstances. A self contained
Respiratory Protection
respirator should be used if high levels of the product are present in
the air. See Australian Standard AS/NZS 1716 for more
information.
Wear safety glasses with side-shield as the minimum level of
Eye Protection
protection.
Wear impervious gloves when handling concentrates and to
Skin Protection
prevent contact with the working strength solution, rubber or plastic
apron and protective boots.
Food, beverages and tobacco products should not be stored or
Hygienic Practices
consumed where this material is in use. Provide eyewash fountains
and safety showers in close proximity to points of potential
exposure.

9. PHYSICAL AND CHEMICAL PROPERTIES

Clear liquid.
Appearance
Odourless
Odour
No information available
Solubility in water
~100??C
Boiling Point
> 0??C
Freezing Point
17
Vapour Pressure (mm
Hg)
0.6
Vapour Density (Air = 1)
1.18
Specific Gravity
7.1
pH
<1
Evaporation Rate (Butyl
acetate = 1)
Not applicable
Flash Point
Not applicable
Flammable Limit ?? Lower
Not applicable
Flammable Limit ?? Upper

10. STABILITY AND REACTIVITY

Stable under recommended storage and use conditions.
Chemical Stability
Incompatible with strong acids and alkalis and oxidisers.
Incompatible Materials
Sulphur dioxide, ammonia and cyanide.
Hazardous Decomposition
Products
No information available.
Hazardous Polymerization
Conditions to Avoid No information available.

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11. TOXICOLOGICAL INFORMATION

Toxicity Ammonium thiosulfate:
LD50 = 2850 mg/kg (oral-rat)
Sodium sulfite:
LDLo = 2825 mg/kg (oral-rat)
EDTA:
LD50 = 2850 mg/kg (oral-rat)
Inhalation, ingestion, eye and skin
Routes of Exposure
Inhalation: May cause irritation.
Health effects from likely
Ingestion: Likely to be harmful.
routes of exposure
Eye: May cause irritation.
Skin: May cause irritation.
Effects of Overexposure. Prolonged or repeated contact with skin may cause allergic
reaction.
No information available.
Existing Conditions
Aggravated by Exposure
No information available.
Carcinogenicity

12. ECOLOGICAL INFORMATION

No information available.
Ecotoxicity
No information available.
Mobility

13. DISPOSAL CONSIDERATIONS

Dispose according to applicable local and state government
Disposal methods and
regulations.
containers
Please consult your state Land Waste Management Authority for
Special precautions for
more information
landfill or incineration

14. TRANSPORT INFORMATION

Not classified as a dangerous good according to the Australian Code for the Transport of
Dangerous goods by road or rail.
Not applicable
UN Number
Not applicable
Proper Shipping Name
Not applicable
Dangerous Goods Class
Not applicable
Hazchem Code
Not applicable
Packing Group
Not applicable
Special Precautions

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15. REGULATORY INFORMATION

Ammonium thiosulphate, sodium sulphite and EDTA acid are listed in the Australian Inventory of
Chemical Substances (AICS).

16. OTHER INFORMATION

Rev 1.0 (11/11/2006)
Last Revision of MSDS
MSDS.COM.AU Pty Ltd www.msds.com.au
Prepared by
IARC: International Agency for Research on Cancer
Abbreviations Used
NOHSC: National Occupational Health and Safety Commission
NTP: National Toxicology Program (U.S.)
OSHA: Occupational Safety and Health Administration (U.S.)
STEL: Short term exposure limit
TWA: Time weighted average
Emergency Contacts

Australian Photographic Engineering Pty Ltd 07 3889 8272
Australian Photographic Engineering Pty Ltd ?? 1300 727 906
Emergency Number
Police and Fire Brigade 000
Poisons Information Centre 13 11 26

The information contained in this material safety data sheet is provided in good faith and is
believed to be accurate at the date of issuance. Australian Photographic Engineering Pty Ltd
makes no representation of the accuracy or comprehensiveness of the information and to the full
extent allowed by law excludes all liability for any loss or damage related to the supply or use of
the information in this material safety data sheet. MSDS.COM.AU Pty Ltd is not in a position to
warrant the accuracy of the data herein. The user is cautioned to make their own determinations
as to the suitability of the information provided to the particular circumstances in which the product
is used.

Please read instructions / label before using product.

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RA FILM FIXER REPLENISHE
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