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Glycine,N-[(9H-fluoren-9-ylmethoxy)carbonyl]-, 2,3,4,5,6-pentafluorophenyl ester

Conforms to 93/112/EC and ISO 11014-1

SAFETY DATA SHEET
Order Number Customer Number

Identification of the substance/preparation and of the company/undertaking
1.
Fmoc-Gly-OPfp : 04-12-1507
Product name : Catalog #
: Manufactured by Merck Biosciences AG
Supplier
Weidenmattweg 4
Chemical formula C23H14NO4F5
: CH-4448 L?ufelfingen
Switzerland
+41 62 285 2525
FAX: +41 62 285 2520
EMD Biosciences, Inc.
P.O. Box 12087
La Jolla, CA 92039-2087
(858) 450-5558/(800) 854-3417
FAX: (858) 453-3552

Not available.
Synonym :

Emergency : Call Chemtrec?
telephone number (800)424-9300 (within U.S.A.)
(703)527-3887 (outside U.S.A.)

Composition / information on ingredients
2.
: Substance
Substance/Preparation

Chemical name* CAS No. EC Number Symbol R-Phrases
Fmoc-Gly-OPfp 86060-85-7 Not available. Xi R38

Hazards identification
3.
: Not applicable.
Physical/chemical hazards
: CAUTION!
Human health hazards
MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED.
MAY CAUSE SKIN IRRITATION.

First-aid measures
4.
First-Aid measures
: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
Inhalation
attention.
: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
Ingestion
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a
collar, tie, belt or waistband.
: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
Skin Contact
contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
Eye Contact
minutes. Get medical attention.

Effects and symptoms
: Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or,
Skin Contact
occasionally, blistering.
: Repeated or prolonged exposure is not known to aggravate medical condition.
Aggravating conditions

5. Fire-fighting measures
: May be combustible at high temperature.
Flammability of the Product
Extinguishing Media
: SMALL FIRE: Use DRY chemical powder.
Suitable
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), halogenated compounds, hydrogen fluoride.
Hazardous thermal (de)composition
products

04-12-1507
Catalog #
: Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
Special fire-fighting procedures
: Be sure to use an approved/certified respirator or equivalent.
Protection of fire-fighters

Accidental release measures
6.
: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid
Personal precautions
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Small Spill and Leak

: Use a shovel to put the material into a convenient waste disposal container.
Large Spill and Leak

Handling and storage
7.
: Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under
Handling
a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Avoid contact with skin.
Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label.
: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above -20??C (-4??F).
Storage
Packaging materials
: Use original container.
Recommended use

Exposure controls/personal protection
8.
: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
Engineering measures
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
: Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using lavatory, and at
Hygiene measures
the end of day.
Ingredient Name Occupational Exposure Limits
Fmoc-Gly-OPfp Not available.

Personal protective equipment
: Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation
Respiratory system
is inadequate.
: Lab coat.
Skin and body
: Gloves.
Hands
: Safety glasses.
Eyes
Protective Clothing (Pictograms) :

Physical and chemical properties
9.
: Solid. (Contains Pentafluorophenol.)
Physical state
Color : White to yellowish. (Light.)
: 463.4 g/mole
Molecular Weight

: 150 to 160??C (302 to 320??F)
Melting Point
: Insoluble in cold water.
Solubility
Flash point : Not available.
: Risks of explosion of the product in presence of mechanical impact: Not available.
Explosive properties
Risks of explosion of the product in presence of static discharge: Not available.

10. Stability and reactivity
: The product is stable.
Stability
: Not available.
Conditions to avoid
: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), halogenated compounds, hydrogen fluoride.
Hazardous Decomposition Products

04-12-1507
Catalog #
11. Toxicological information
: SM6680000 (Pentafluoropheno
RTECS #
Local effects
Skin irritation : Hazardous in case of skin contact (irritant).
: LD50: Not available.
Acute toxicity
LC50: Not available.
: Repeated or prolonged exposure is not known to aggravate medical condition.
Chronic toxicity
: Not available.
Other Toxic Effects on Humans
Hazardous in case of skin contact (irritant).

Not available.

To the best of our knowledge, the toxicological properties of this product have not been thoroughly investigated.

Carcinogenic effects : Not available.
: Not available.
Mutagenic effects
Reproduction toxicity : Not available.
: Not available.
Teratogenic effects

12. Ecological information
: Not available.
Ecotoxicity
: The products of degradation are as toxic as the product itself.
Toxicity of the Products of
Biodegradation

13. Disposal considerations
: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Methods of disposal; Waste of residues;
Contaminated packaging

14. Transport information
International transport regulations
Land - Road/Railway
: Not controlled under ADR (Europe).
ADR/RID Class
Sea
: Not controlled under IMDG.
IMDG Class
Air
: Not controlled under IATA.
IATA-DGR Class
Not applicable.
Special Provisions for
Transport

15. Regulatory information
EU Regulations
Hazard symbol(s) :

: Irritant
Classification
: R38- Irritating to skin.
Risk Phrases
: S36- Wear suitable protective clothing.
Safety Phrases
U.S. Federal Regulations : TSCA: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
: CLASS: Irritating substance.
HCS Classification

State Regulations :

04-12-1507
Catalog #
: CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).
WHMIS (Canada)

No products were found.

16. Other information
Hazardous Material 2 National Fire
Health
Fire Hazard
1
Information System Protection Association
1
Fire Hazard
(U.S.A.) (U.S.A.) 2 0
Health Reactivity
0
Reactivity
Specific Hazard
E
Personal Protection
Personal Protection

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. **This product is intended for research
use only.**

04-12-1507
Catalog # Date of issue 6/2/2004.

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