information Related products Suppliers

2-Aminobenzotrifluoride

MSDS

EN
**** MATERIAL SAFETY DATA SHEET ****

2-Aminobenzotrifluoride

**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****

MSDS Name: 2-Aminobenzotrifluoride
Catalog Numbers:
10318-0000, 10318-0050, 10318-1000, 10318-5000
Synonyms:
2-(Trifluoromethyl)aniline
Company Identification (Europe): Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification (USA): Acros Organics
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For information in Europe, call: 0032(0) 14575211
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in Europe, call: 0032(0) 14575299

**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+-----------+---------------+
| CAS# | Chemical Name | % | EINECS# |Haz Symbols| Risk Phrases |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
| 88-17-5 |2-Aminobenzotrifluoride | 99% | 201-806-7 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
Hazard Symbols: XN
Risk Phrases: 10 20/21/22 33 36/37/38

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed. Danger of cumulative effects. Irritating to eyes,
respiratory system and skin.

Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood). May cause burning sensations, coughing,
wheezing, laryngitis, shortness of breath and headache.
Inhalation:
Harmful if inhaled. May cause cyanosis (bluish discoloration of skin
due to deficient oxygenation of the blood). Causes respiratory tract
irritation. May cause burning sensation, coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Prolonged exposure may produce a narcotic effect. Prolonged or
repeated exposure may cause nausea, dizziness, and headache. There is
a danger of cumulative effects.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:

http://newsearchfr2.chemexper.com/cheminfo/servlet/org....n%3D%7E%3F%29&searchValue=88-17-5&options=brandqtyoffer (1 of 4)2008-2-3 0:52:37
MSDS

Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Flammable liquid
and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Use spark-proof tools and explosion proof equipment. Avoid prolonged
or repeated contact with skin. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place. Do
not store in direct sunlight. Store in a tightly closed container.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Personal Protective Equipment

Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: clear colorless to light amber

http://newsearchfr2.chemexper.com/cheminfo/servlet/org....n%3D%7E%3F%29&searchValue=88-17-5&options=brandqtyoffer (2 of 4)2008-2-3 0:52:37
MSDS

Odor: amine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 170 - 173 deg C @15mmHg
Freezing/Melting Point: -33 deg C
Autoignition Temperature: > 500 deg C (> 932.00 deg F)
Flash Point: 55 deg C ( 131.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 4 g/l (20?C)
Specific Gravity/Density: 1.296
Molecular Formula: C7H6F3N
Molecular Weight: 161.13

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Light sensitive.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Oxidizing agents, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride
gas.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 88-17-5 unlisted.
LD50/LC50:
Not available.
Oral, rat: LD50 = 1890 mg/kg
Carcinogenicity:
2-Aminobenzotrifluoride -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Other
Avoid entering into waters or underground water. Do not empty into
drains.

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.*
Hazard Class: 3
UN Number: 1992
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1992
Packing Group: III
RID/AD Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3

http://newsearchfr2.chemexper.com/cheminfo/servlet/org....n%3D%7E%3F%29&searchValue=88-17-5&options=brandqtyoffer (3 of 4)2008-2-3 0:52:37
MSDS

UN Number: 1992
Packing group: III

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 88-17-5: 1
United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada
CAS# 88-17-5 is listed on Canada's NDSL List.
CAS# 88-17-5 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 88-17-5 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 7/16/1996 Revision #2 Date: 5/25/2004

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.

http://newsearchfr2.chemexper.com/cheminfo/servlet/org....n%3D%7E%3F%29&searchValue=88-17-5&options=brandqtyoffer (4 of 4)2008-2-3 0:52:37

;