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Cemedine 540

LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET
Permatex(R) Copper SPRAY-A-GASKET(R)
80696

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Permatex(R) Copper SPRAY-A-GASKET(R)
Item No.: 80696
Part No.: 101H
Product Type: Sealant

2. COMPOSITION, INFORMATION ON INGREDIENTS

Ingredients CAS No. %

ACETONE 67-64-1 65-70
Synthetic rubber 9003-18-3 10-15
Phenolic resin Proprietary 10-15
COPPER* 7440-50-8 3-5
ZINC OXIDE* 1314-13-2 0.1-0.5

* This component is listed as a SARA Section 313 Toxic Chemical.

Ingredients which have exposure limits

Exposure Limits (TWA) ACGIH OSHA OTHE Ingredients (TLV) (PEL)

ACETONE 750 ppm TWA 750 ppm TWA None
1780 mg/m3 1800 mg/m3
COPPER 1 mg/m3 dust 1 mg/m3 dust None
ZINC OXIDE 5 mg/m3 fume 10 mg/m3 dust None
10 mg/m3 dust 5 mg/m3 respir

Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)

ACETONE 1000 ppm 1000 ppm
2380 mg/m3 2400 mg/m3
ZINC OXIDE 10 mg/m3 fume 10 mg/m3 fume

3. HAZARDS IDENTIFICATION

Toxicity: Eye irritant. Moderately toxic by ingestion and
inhalation.
Primary Routes of Entry: Skin, ingestion, inhalation.
Signs and symptoms
of Exposure: Headache, nausea, dizziness, irritation of mucous
membranes. Liquid may cause eye injury and may
cause dermatitis.
Existing Conditions
Aggravated by Exposure: None known
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET
Product Name: Permatex(R) Copper SPRAY-A-GASKET(R)
Item No.: 80696

3. HAZARDS IDENTIFICATION (continued)

Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA

ACETONE BLO CNS IRR NO NO NO
Synthetic rubber No Data NO NO NO
Phenolic resin No Data NO NO NO
COPPER BLO CNS GAS IMM IRR KID LIV MUT NO NO NO
SEN SKI
ZINC OXIDE BLO GAS IMM IRR KID PAN RES SKI NO NO NO
-------------------------------------------------------------------------------

Abbreviations

BLO Blood CNS Central nervous system
GAS Gastrointestinal IMM Immune system
IRR Irritant KID Kidney
LIV Liver MUT Mutagen
PAN Pancreas RES Respiratory
SEN Sensory SKI Skin

ADDITIONAL INFORMATION:
Inhalation of phenolic resin dust has been shown to cause pulmonary
effects.
It is our best technical judgment that, with proper precautions,
normal use of the is product poses no such hazards.

4. FIRST AID MEASURES

Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush with water for at least 15 minutes. Obtain
medical attention.

5. FIRE FIGHTING MEASURES

Flash Point: Approximately -4??F Method: Open Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Metal fumes
Unusual Fire or
Explosion Hazards: None
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET
Product Name: Permatex(R) Copper SPRAY-A-GASKET(R)
Item No.: 80696

5. FIRE FIGHTING MEASURES (continued)

Explosive Limits:
(% by volume in air)Lower Approximately 2%
(% by volume in air)Upper Approximately 13%

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken in case
of spill or leak: Remove sources of ignition. Allow solvent to
evaporate with adequate ventilation. Scrape up
remainder and store in a closed container until
disposal.

7. HANDLING AND STORAGE

Safe Storage: Store away from heat or flame.
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged breathing of vapors. Keep away
from eyes. Avoid skin contact. Do not use use
near heat or flame.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

Eyes: Safety glasses or goggles.
Skin: Impervious rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration below
TLV.

See Section 2 for Exposure Limits.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Brown liquid
Odor: Acetone
Boiling Point: Approximately 133??F
pH: Does not apply
Solubility in Water: Slightly
Specific Gravity 0.91 at 60??F
Volatile Organic Compound
(EPA Method 24) 65.9%
Vapor Pressure: 400mm at 100??F
Vapor Density: 2.0
Evaporation Rate
(Ether = 1) Not available
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET
Product Name: Permatex(R) Copper SPRAY-A-GASKET(R)
Item No.: 80696

10. STABILITY AND REACTIVITY

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers.
Hazardous Decomposition
Products (non-thermal): None

11. TOXICOLOGICAL INFORMATION

See Section 3.

12. ECOLOGICAL INFORMATION

No data available

13. DISPOSAL CONSIDERATIONS

Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number D001 - Hazardous waste per 40CFR 261.21

14. TRANSPORT INFORMATION

DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity (Not more than one liter);
Resin solution (More than one liter)
Hazard Class or
Division: ORM-D (Not more than one liter);
Class 3, Packing Group II (More than one liter)
Identification Number: None (Not more than one liter);
UN 1866 (More than one liter)
Marine Pollutant: None
IATA
Proper Shipping Name: Resin Solution
Class or Division: Class 3, Packing Group II
UN or ID Number: UN 1866

15. REGULATORY INFORMATION

CA Proposition 65: Warning: This product contains a chemical known to
the State of California to cause cancer.

16. OTHER INFORMATION

Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 3
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET
Product Name: Permatex(R) Copper SPRAY-A-GASKET(R)
Item No.: 80696

16. OTHER INFORMATION (continued)

Reactivity Hazard: 1
Specific Hazard: Does not apply

Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 3
Reactivity Hazards: 1
Personal Protection: See Section 8.

NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.

Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0025

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