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2-Propenoic acid, butylester, homopolymer

Material Safety Data Sheet

PARASEAL LG
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006

SECTION 1 - PRODUCT IDENTIFICATION

Trade name : PARASEAL LG
Product code : 512120 503

COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300

Product use : Waterproofing

SECTION 2 - HAZARDS IDENTIFICATION

Emergency Overview
Gray. Solid ply rolls. Not applicable under normal conditions of use. Generally not required under normal
conditions of use.

Acute Potential Health Effects/ Routes of Entry
Inhalation Not applicable under normal conditions of use.
:
Eyes Not applicable under normal conditions of use.
:
Ingestion Not applicable under normal conditions of use.
:
Skin May cause mild irritation.
:

Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.

Chronic Health Effects
This product contains granular materials which may cause mechanical skin, eye or respiratory irritation.
Inhalation of crystalline silica (quartz) can cause cancer based on animal data, and IARC concludes sufficient
evidence in humans (Group 1). Prolonged and repeated overexposure to free crystalline silica dust above the
TLV level may cause scarring of the lungs with cough and shortness of breath. A delayed lung injury, silicosis
may result from breathing free silica.
Target Organs: Skin, Eye, Lung

SECTION 3 - PRODUCT COMPOSITION

Chemical Name CAS-No. Weight %
Bentonite 1302-78-9 > 60.0
Water 7732-18-5 10.0 - 30.0
n-Butyl acrylate resin 9003-49-0 3.0 - 7.0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 1.0 - 5.0
Silica (crystalline-tridymite) 15468-32-3 - <1.0
Silica (crystalline-cristobalite) 14464-46-1 - <1.0

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Material Safety Data Sheet

PARASEAL LG
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006

SECTION 4 - FIRST AID MEASURES

Get immediate medical attention for any significant overexposure.

Inhalation : Generally not required under normal conditions of use.
Eye contact : Generally not required under normal conditions of use.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Not applicable under normal conditions of use.

Notes to physician : Not applicable.

SECTION 5 - FIRE FIGHTING MEASURES

Flash point : Not available.
Method : Not available.
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Hazardous combustion : Hydrogen sulfide and hydrocarbon fractions.
products
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Scrape up and transfer to appropriate container for disposal.

SECTION 7 - HANDLING AND STORAGE

Store under normal warehouse conditions.

SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Personal protection equipment
Respiratory protection : Not required under normal conditions of use.
Hand protection : Use suitable impervious leather gloves and protective apparel to reduce
exposure.
Eye protection : Wear appropriate eye protection.
Skin and body protection : Not required.
Protective measures : Other equipment not normally required.
Engineering measures : General ventilation is sufficient.

Exposure Limits

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Material Safety Data Sheet

PARASEAL LG
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006

Chemical Name CAS Number Regulation Limit Form
Bentonite 1302-78-9 ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.

Crystalline Silica 14808-60-7 ACGIH TWA: 0.05 mg/m3 Respirable fraction.
(Quartz)/ Silica Sand OSHA TWA: 0.1 mg/m3 Respirable.
OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.

Silica (crystalline- 14464-46-1 ACGIH TWA: 0.05 mg/m3 Respirable fraction.
cristobalite) OSHA TWA: 0.05 mg/m3 Respirable.
OSHA TWA: 0.15 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.

Silica (crystalline- 15468-32-3 ACGIH TWA: 0.05 mg/m3 Respirable fraction.
tridymite) OSHA TWA: 0.05 mg/m3 Respirable.
OSHA TWA: 0.15 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Form : Solid ply rolls
Color : Gray
Odor : None
pH : Not available.
Vapour pressure : Not available.
Vapor density : Not available.
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Gels
Specific Gravity : 1.7
% Volatile Weight : 0%

SECTION 10 - REACTIVITY / STABILITY

Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.

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Material Safety Data Sheet

PARASEAL LG
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006

SECTION 11 - TOXICOLOGICAL INFORMATION

No Data Available

SECTION 12 - ECOLOGICAL INFORMATION

No Data Available

SECTION 13 - DISPOSAL CONSIDERATIONS

Disposal Method : As purchased, this product, when discarded, is not a listed or characteristic hazardous
waste according to Federal regulations (40 CFR 261). Check local, regional, state or
provincial regulations for applicable requirements for disposal. Any processing, using,
alteration or chemical additions to the product, as purchased, may alter the disposal
requirements. Under Federal regulations, it is the generator's responsibility to
determine if a waste is a hazardous waste. Empty containers may retain product
residue. Do not reuse.

SECTION 14 - TRANSPORTATION / SHIPPING DATA

TDG / DOT Shipping Description:
NOT REGULATE

SECTION 15 - REGULATORY INFORMATION

North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.

U.S. Federal Regulations:
SARA 313 Components : None present or none present in regulated quantities.

SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard

OSHA Hazardous Components :
Bentonite 1302-78-9
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Silica (crystalline-cristobalite) 14464-46-1
Silica (crystalline-tridymite) 15468-32-3

OSHA Status: Considered : Carcinogen
hazardous based on the Irritant
following criteria:

OSHA Flammability : Not Regulated

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Material Safety Data Sheet

PARASEAL LG
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006

Regulatory VOC (less water and : 0 g/l
exempt solvent)
VOC Method 310 : Not available.

Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Silica (crystalline-cristobalite) 14464-46-1
Silica (crystalline-tridymite) 15468-32-3

U.S. State Regulations:
MASS RTK Components : Crystalline Silica (Quartz)/ Silica Sand 14808-60-7

Penn RTK Components : Bentonite 1302-78-9
Water 7732-18-5
n-Butyl acrylate resin 9003-49-0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7

NJ RTK Components : Bentonite 1302-78-9
Water 7732-18-5
n-Butyl acrylate resin 9003-49-0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Silica (crystalline-tridymite) 15468-32-3
Silica (crystalline-cristobalite) 14464-46-1

Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
14464-46-1 Silica (crystalline-cristobalite)
15468-32-3 Silica (crystalline-tridymite)

SECTION 16 - OTHER INFORMATION

HMIS Rating :
Health 1 0 = Minimum
1 = Slight
Flammability 0
2 = Moderate
Reactivity 0
3 = Serious
PPE
4 = Severe

Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.

Prepared by: Rich Mikol

Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and
RCRA - Resource Conservation and Recovery Act
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value

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Material Safety Data Sheet

PARASEAL LG
Version 1.2 Print Date 09/11/2006
REVISION DATE: 09/01/2006

IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration

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