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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

Material Safety Data Sheet
[1,1??-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUMDICHLORIDE MSDS No. C4085
Catalog No. Pd-106
Revision:12/05/05

Section 1 - Chemical Product and Company Identification
Product/Chemical Name: [1,1??-Bis(Diphenylphosphino)Ferrocene]Palladiumdichloride with dichlormethane (1:1)
Chemical Formula: PdCl2(C34H28FeP2) CH2Cl2
CAS Number: 95464-05-4
Trade Name: Dichlor[1,1??-bis(diphenylphosphino)ferrocene]Palladium (II) dichloromethane Complex
Chemical Family: Palladium coordination complex
Manufacturer: Johnson Matthey, 2001 Nolte Drive, West Deptford, NJ 08066, Emergency Phone: (856) 384-7000

Section 2 - Composition / Information on Ingredients
Ingredient Name CAS Number % wt or
% vol
Dichlor[1,1??-bis(diphenylphosphino)ferrocene] Palladiumdichloride 72287-26-4 90

Dichloromethane 75-09-2 10

Hazardous Ingredients:
OSHA PEL ACGIH TLV
TWA TWA
Not established 50 ppm
Dichlor[1,1??-
bis(diphenylphosphino)ferrocene]
Palladiumdichloride

50 ppm 500ppm
Dichloromethane

Section 3 - Hazards Identification
?????? Emergency Overview ????????

Potential Health Effects
Primary Entry Routes:
Target Organs: Not known
Acute Effects Not known
Inhalation: Not known
Eye: Not known
Skin: Not known
Ingestion: Not known
Carcinogenicity: Not known
Medical Conditions Aggravated by Long-Term Exposure: no data
Chronic Effects: Not known
Other: Dichloromethane is reported to cause cancer in laboratory animals. Exercise due care when handling. May be absorbed
through the skin.

Section 4 - First Aid Measures
Inhalation: Remove person to fresh air. If breathing has stopped, administer artificial respiration. If breathing is difficult,
give oxygen. Get immediate medical attention.

Johnson Matthey, Inc.
revision: 7/19/04 [1,1??-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUMDICHLORIDE MSDS No. C4085
Eye Contact: Flush with plenty of water for at least 15 minutes including beneath eyelids. Remove contacts/glasses while
flushing. Get immediate medical attention.
Skin Contact: Flush with copious amounts of soap and water for at least 15 minutes while removing contaminated clothing and
shoes. Get immediate medical attention. Wash clothing/shoes thoroughly before reuse.
Ingestion: Do not induce vomiting. Rinse the mouth out with water. Give milk or water. Do not make an unconscious
person vomit. Get immediate medical attention.

Section 5 - Fire-Fighting Measures
Flash Point: Not applicable
Autoignition Temperature: Not applicable
LEL: Not Applicable
UEL: Not Applicable
Extinguishing Media: Water, foam, CO2, dry chemical. Use extinguishing media appropriate for surrounding fire conditions.
Unusual Fire or Explosion Hazards: Hazardous Combustion Products: Toxic fumes of chloride may be produced if involved
in a fire
Fire-Fighting Instructions: Do not release runoff from fire control methods to sewers or waterways.
Fire-Fighting Equipment: Use normal procedures which include wearing NIOSH/MSHA approved pressure demand self-
contained breathing apparatus, flame and chemical resistant clothing; hat (hard), boots and gloves.

Section 6 - Accidental Release Measures
Spill /Leak Procedures: Prevent wastage; conserve, accumulate spent residues wipes, ect. for recovery of precious metal in
appropriate containers which have chemical identification and hazard warning information.. Wear
protective clothing and respiratory protection.
Containment: For large spills, dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways.
Regulatory Requirements: Follow applicable federal, state and local regulations.

Section 7 - Handling and Storage
Handling Precautions: Follow good industrial hygiene and housekeeping practices. Do not eat, drink, or smoke while working
with this material. Wash hands before eating, drinking, smoking or applying cosmetics and at the end of
the work shift. Do not breath dust or mist and do not get in eyes, on skin or on clothing. A shower and
clothing policy should be established depending on the potential for exposure.
Storage Requirements: Keep in a cool, dry, well ventilated place away from incompatible materials and conditions. Use proper
labeling in accordance with 29 CFR 1910.1200.

Section 8 - Exposure Controls / Personal Protection
Engineering Controls:
Ventilation:
Local Exhaust: Fume Hood at point of generation.
Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs
(Sec. 2). Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area
by controlling it at its source.
Administrative Controls:
Respiratory Protection: If there is a possibility that the TLV??s or PEL??s may be exceeded, a NIOSH/MSHA approved full
face piece respirator with high efficiency particulate filter cartridge is the recommended minimum
level of respiratory protection. To ensure proper respirator selection and use, refer to the
requirements of 29 CFR 1910.134 and the latest edition of ANSI Z 88.2.
Select respirator based on its suitability to provide adequate worker protection for given working
conditions, level of airborne contamination, and presence of sufficient oxygen. For emergency or non-
routine operations (cleaning spills, reactor vessels, or storage tanks), wear an SCBA. Warning! Air-
purifying respirators do not protect workers in oxygen-deficient atmospheres. If respirators are used,
OSHA requires a written respiratory protection program that includes at least: medical certification,
training, fit-testing, periodic environmental monitoring, maintenance, inspection, cleaning, and
convenient, sanitary storage areas.
Protective Clothing/Equipment:
Protective Gloves: Rubber, impervious gloves to chemicals and conditions encountered.
Eye Protection: OSHA, ANSI approved safety goggles/glasses. Contact lenses are not protective devices. Appropriate
eye- and face-protection must be worn instead of, or in conjunction with, contact lenses.

revision: 7/19/04 [1,1??-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUMDICHLORIDE MSDS No. C4085
Protective Clothing: Wear disposable protective clothing to prevent exposure. Protective clothing includes lab coat and
apron, flame and chemical resistant coveralls, and boots/safety shoes to prevent prolonged or repeated
skin contact.
Safety Stations: Where there is a possibility that an employee??s eyes may be exposed to the product, an eyewash fountain
should be provided within the immediate work area for emergency use. Safety drench shower and
hygienic facilities are available in production areas.
Comments: Follow good industrial hygiene and housekeeping practices. Do not eat, drink, or smoke while working
with this material. Wash hands before eating, drinking, smoking or applying cosmetics and at the end of
the work shift. Do not breathe dust or mist and do not get in eyes, on skin or on clothing. A shower
and clothing policy should be established depending on the potential for exposure.

Section 9 - Physical and Chemical Properties

Physical State: Liquid Water Solubility: Insoluble
Appearance and Odor: Orange-red crystal Other Solubilities: Not applicable
Odor Threshold: Not applicable Boiling Point: Not applicable
Vapor Pressure: Not applicable Freezing/Melting Point: Not applicable
Vapor Density (Air=1): Not applicable Viscosity: Not applicable
Formula Weight: Not applicable Refractive Index: Not applicable
Density: Not applicable Surface Tension: Not applicable
Specific Gravity (H2O=1): Not applicable % Volatile: Not applicable
Evaporation Rate: Not applicable
pH: Not applicable

Section 10 - Stability and Reactivity
Stability: Stable
Conditions to Avoid: Heat
Polymerization: Will not occur
Chemical Incompatibilities: None
Conditions to Avoid: Not applicable
Hazardous Decomposition Products: Not known

Section 11- Toxicological Information
Toxicity Data:
Eye Effects: Not known
Skin Effects: Not known
Acute Inhalation Effects: Not known
Acute Oral Effects: Not known

Section 12 - Ecological Information
Ecotoxicity: Not known
Environmental Fate: Not known
Environmental Transport: Not known
Environmental Degradation: Not known
Soil Absorption/Mobility: Not known

Section 13 - Disposal Considerations
Disposal: Return accumulated residues, wipes, mops, sand and vermiculite to precious metal refinery for metal recovery.
Disposal Regulatory Requirements: Follow federal, state, and local regulations for packaging, labeling, manifesting,
transportation and disposal.

revision: 7/19/04 [1,1??-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUMDICHLORIDE MSDS No. C4085
Section 14 - Transport Information
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Non Hazardous Non
Hazard Class:
Regulated
UN No.:
Packing Group:
Label:

Section 15 - Regulatory Information
EPA Regulations:
RCRA Hazardous Waste Number: Not listed (40 CFR 261.33)
RCRA Hazardous Waste Classification (40 CFR 261): Not classified
CERCLA Hazardous Substance (40 CFR 302.4), Sec. 3001; CWA, Sec. 311 (b)(4); CWA, Sec. 307(a), CAA, Sec. 112: Not listed
CERCLA Reportable Quantity (RQ): None known
SARA 311/312 Codes: Not listed
SARA Toxic Chemical (40 CFR 372.65): Not listed
SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Not listed, Threshold Planning Quantity (TPQ)
TSCA: Not listed in TSCA Inventory. For research and development use only.
OSHA Regulations:
Not listed

State Regulations: None known

Section 16 - Other Information
Prepared By: Paul Vincent
Revision Notes: Revised: 9/19/03 : 7/19/04 : 12/5/05
Disclaimer: Employers should use this information only as a supplement to other information gathered by them. and should make
independent judgment of suitability of this information to ensure proper use and protect the health and safety of employees. This
information. is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or
in combination with any other product or process, is the responsibility of the user.

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