4-Chloro-2-methylphenylmagnesium bromid

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand : : : 4-Chloro-2-methylphenylmagnesium bromide solution 562262 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Flammable liquids (Category 2) Skin corrosion (Category 1B) Specific target organ toxicity - single exposure (Category 3) Classification according to EU Directives 67/548/EEC or 1999/45/EC Highly flammable. Causes burns. Irritating to respiratory system. May form explosive peroxides. Reacts violently with water. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H225 H314 H335 Precautionary statement(s) P210 P261 P280 Danger Highly flammable liquid and vapour. Causes severe skin burns and eye damage. May cause respiratory irritation. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing vapours. Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338 P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Supplemental Hazard information (EU) EUH014 EUH019 Reacts violently with water. May form explosive peroxides. According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R11 R14 R19 R34 R37 S-phrase(s) S16 S26 S36/37/39 S45 Highly flammable. Reacts violently with water. May form explosive peroxides. Causes burns. Irritating to respiratory system. Keep away from sources of ignition - No smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 2.3 3. 3.2 Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Mixtures Formula Molecular Weight : : C7H6BrClMg 229,78 g/mol Component Tetrahydrofuran Classification Concentration CAS-No. EC-No. Index-No. 109-99-9 203-726-8 603-025-00-0 Flam. Liq. 2; Eye Irrit. 2; STOT 50 - 100 % SE 3; H225, H319, H335, EUH019 F, Xi, R11 - R19 - R36/37 4-Chloro-2-methylphenylmagnesium bromide CAS-No. 480438-47-9 Skin Corr. 1B; H314, EUH014 10 - 20 % C, R14 - R34 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 4. 4.1 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 4.3 5. 5.1 5.2 5.3 5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 7.3 Most important symptoms and effects, both acute and delayed To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Dry powder Special hazards arising from the substance or mixture Carbon oxides, Hydrogen chloride gas, Hydrogen bromide gas, Magnesium oxide Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Do not flush with water. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Never allow product to get in contact with water during storage. Recommended storage temperature: 2 - 8 ??C Handle and store under inert gas. Dry residue is explosive. Specific end uses no data available 8. 8.1 8.2 9. 9.1 EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: liquid no data available no data available no data available no data available 65 - 67 ??C -17 ??C - closed cup no data available i) Flammability (solid, gas) no data available j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density no data available no data available no data available m) Relative density 0,959 g/mL at 25 ??C n) o) p) q) r) s) t) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties no data available no data available no data available no data available no data available no data available no data available 9.2 10. 10.1 10.2 10.3 10.4 10.5 10.6 11. 11.1 Other safety information no data available STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions Reacts violently with water. Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Exposure to moisture. Incompatible materials Oxidizing agents, Oxygen Hazardous decomposition products TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Causes respiratory tract irritation. Vapours may cause drowsiness and dizziness. Harmful if swallowed. Causes burns. May be harmful if absorbed through skin. Causes skin burns. Causes eye burns. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: Not available 12. 12.1 12.2 12.3 12.4 12.5 12.6 13. 13.1 14. 14.1 ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects no data available DISPOSAL CONSIDERATIONS Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. TRANSPORT INFORMATION UN number 14.2 ADR/RID: 2924 UN proper shipping name IMDG: 2924 IATA: 2924 ADR/RID: IMDG: IATA: FLAMMABLE LIQUID, CORROSIVE, N.O.S. (Tetrahydrofuran, 4-Chloro-2- methylphenylmagnesium bromide) FLAMMABLE LIQUID, CORROSIVE, N.O.S. (4-Chloro-2-methylphenylmagnesium bromide, Tetrahydrofuran) Flammable liquid, corrosive, n.o.s. (4-Chloro-2-methylphenylmagnesium bromide, Tetrahydrofuran) 14.3 Transport hazard class(es) ADR/RID: 3 (8) 14.4 Packaging group ADR/RID: II IMDG: 3 (8) IMDG: II IATA: 3 (8) IATA: II 14.5 Environmental hazards 14.6 15. ADR/RID: no Special precautions for user no data available REGULATORY INFORMATION IMDG Marine pollutant: no IATA: no This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 15.2 16. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 EUH014 EUH019 Eye Irrit. Flam. Liq. H225 H314 H319 H335 Skin Corr. STOT SE C F R11 R14 R19 R34 R36/37 Xi Reacts violently with water. May form explosive peroxides. Eye irritation Flammable liquids Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye irritation. May cause respiratory irritation. Skin corrosion Specific target organ toxicity - single exposure Corrosive Highly flammable Highly flammable. Reacts violently with water. May form explosive peroxides. Causes burns. Irritating to eyes and respiratory system. Irritant Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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