Benzenamine,2,4-dimethyl-N-(3-methyl-2(3H)-thiazolylidene)-

1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING Product Name Cymiazole 2.HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Acute toxicity, Oral (Category 4) Eye irritation (Category 2) According to European Directive 67/548/EEC as amended. Harmful if swallowed. Label elements Pictogram Signal word Hazard statement(s) H302 H319 Precautionary statement(s) P305 + P351 + P338 Warning Harmful if swallowed. Causes serious eye irritation. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Hazard symbol(s) Xn R-phrase(s) R22 S-phrase(s) Harmful Harmful if swallowed. none Other hazards - none 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms : 2-(2,4-Dimethylphenylimino)-3-methylthiazoline 2-(2,4-Xylylimino)-3-methylthiazoline N-[(2EZ)-3-Methyl-1,3-thiazol-2(3H)-ylidene]-2,4-xylidine Formula Molecular Weight : : C12H14N2S 218,32 g/mol CAS-No. EC-No. Index-No. Classification Concentration N-(3-methyl-3H-thiazol-2-ylidene)-2,5-xylidine 61676-87-7 262-890-9 - Acute Tox. 4; H302 - Xn, R22 For the full text of the H-Statements mentioned in this Section, see Section 16. 4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection. Conditions for safe storage Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves. Eye protection Safety glasses with side-shields conforming to EN166 Skin and body protection Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Safety data pH Melting point Boiling point Flash point Ignition temperature Lower explosion limit Upper explosion limit Density Water solubility Solubility crystalline no data available 42 - 46 ??C no data available no data available no data available no data available no data available 1,19 g/cm3 at 20 ??C 0,15 g/l at 20 ??C 800 g/l Benzene 800 g/l Methanol 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid no data available Materials to avoid no data available Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx), Sulphur oxides 11. TOXICOLOGICAL INFORMATION Acute toxicity LD50 Oral - rat - 725 mg/kg LC50 Inhalation - rat - 4 h - > 2.800 mg/m3 Skin corrosion/irritation Skin - rabbit - Mild skin irritation Serious eye damage/eye irritation Eyes - rabbit - Mild eye irritation Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. May cause respiratory tract irritation. Harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. May cause eye irritation. Signs and Symptoms of Exposure This product is a monoamine oxidase inhibitor (MAOI). Additional Information RTECS: Not available 12. ECOLOGICAL INFORMATION Toxicity Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 12 mg/l - 96 h LC50 - Cyprinus carpio (Carp) - 32 mg/l - 96 h Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil PBT and vPvB assessment no data available Other adverse effects no data available 13. DISPOSAL CONSIDERATIONS Product Observe all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION ADR/RID Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods 15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Acute Tox. H302 Xn R22 Acute toxicity Harmful if swallowed. Harmful Harmful if swallowed. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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