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PHENOL:CHLOROFORM:ISOAMYL ALC. 25:24:1

1.1

IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifiers

Product name

Product Number

Brand

CAS-No.

Phenol ?C chloroform ?C isoamyl alcohol mixture

77617

136112-00-0

1.2

Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Laboratory chemicals, Manufacture of substances

2.1

2.2

HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]

Acute toxicity, Oral (Category 3)

Acute toxicity, Inhalation (Category 2)

Acute toxicity, Dermal (Category 4)

Skin corrosion (Category 1B)

Germ cell mutagenicity (Category 2)

Carcinogenicity (Category 2)

Specific target organ toxicity - repeated exposure (Category 2)

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Toxic by inhalation, in contact with skin and if swallowed. Causes burns. Harmful: danger of serious

damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Limited

evidence of a carcinogenic effect. Possible risk of irreversible effects.

Label elements

Labelling according Regulation (EC) No 1272/2008 [CLP]

Pictogram

Signal word

Hazard statement(s)

H301

H312

H314

H330

Danger

Toxic if swallowed.

Harmful in contact with skin.

Causes severe skin burns and eye damage.

Fatal if inhaled.

H341

H351

H373

Precautionary statement(s)

P260

P280

P284

P301 + P310

P305 + P351 + P338

P310

Supplemental Hazard

Suspected of causing genetic defects.

Suspected of causing cancer.

May cause damage to organs through prolonged or repeated exposure.

Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.

Wear protective gloves/ protective clothing/ eye protection/ face

protection.

Wear respiratory protection.

IF SWALLOWED: Immediately call a POISON CENTER or doctor/

physician.

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER or doctor/ physician.

none

Statements

According to European Directive 67/548/EEC as amended.

Hazard symbol(s)

R-phrase(s)

R23/24/25

R34

R40

R68

R48/20/21/22

Toxic by inhalation, in contact with skin and if swallowed.

Causes burns.

Limited evidence of a carcinogenic effect.

Possible risk of irreversible effects.

Harmful: danger of serious damage to health by prolonged exposure

through inhalation, in contact with skin and if swallowed.

S-phrase(s)

S26

S36/37/39

S45

In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

Wear suitable protective clothing, gloves and eye/face protection.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

2.3

3.2

Other hazards

Rapidly absorbed through skin., Vesicant.

COMPOSITION/INFORMATION ON INGREDIENTS

Mixtures

Component

Phenol

Classification

Concentration

CAS-No.

EC-No.

Index-No.

108-95-2

203-632-7

604-001-00-2

Muta. 2; Acute Tox. 3; STOT

RE 2; Skin Corr. 1B; H301,

H311, H314, H331, H341,

50 - 100 %

H373

T, Mut.Cat.3, R23/24/25 - R34

- R48/20/21/22 - R68

Chloroform

CAS-No.

EC-No.

Index-No.

67-66-3

200-663-8

602-006-00-4

Carc. 2; Acute Tox. 4; STOT

RE 2; Skin Irrit. 2; H302,

H315, H351, H373

25 - 50 %

Xn, Carc.Cat.3, R22 - R38 -

R40 - R48/20/22

3-Methylbutan-1-ol

CAS-No.

EC-No.

Index-No.

123-51-3

204-633-5

603-006-00-7

Flam. Liq. 3; Acute Tox. 4;

STOT SE 3; H226, H332,

H335, EUH066

< 10 %

Xn, R10 - R20 - R37 - R66

For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

4.1

4.2

4.3

5.1

5.2

5.3

5.4

6.1

6.2

6.3

6.4

FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take

victim immediately to hospital. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with

water. Consult a physician.

Most important symptoms and effects, both acute and delayed

Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and

skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,

pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,

Headache, Nausea

Indication of any immediate medical attention and special treatment needed

no data available

FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Carbon oxides, Hydrogen chloride gas

Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

Use water spray to cool unopened containers.

ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove

all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form

explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

environment must be avoided.

Methods and materials for containment and cleaning up

Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and

place in container for disposal according to local regulations (see section 13). Keep in suitable, closed

containers for disposal.

Reference to other sections

For disposal see section 13.

7.1

7.2

7.3

8.1

8.2

9.1

HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.

Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic

charge.

Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are

opened must be carefully resealed and kept upright to prevent leakage.

Recommended storage temperature: 2 - 8 ??C

Air and light sensitive. Store under inert gas.

Specific end uses

no data available

EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components with workplace control parameters

Exposure controls

Appropriate engineering controls

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling

the product.

Personal protective equipment

Eye/face protection

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection

tested and approved under appropriate government standards such as NIOSH (US) or EN

166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and

the standard EN 374 derived from it.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must be selected

according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator

with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup

to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Odour

Odour Threshold

Form: clear, liquid

Colour: yellow

no data available

7,7 - 8,3

Melting point/freezing

point

Initial boiling point and

boiling range

Flash point

Evaporation rate

no data available

79 ??C

no data available

Flammability (solid, gas) no data available

Upper/lower

flammability or

explosive limits

Vapour pressure

Vapour density

no data available

m) Relative density

1,28 g/cm3 at 20 ??C

Water solubility

Partition coefficient: n-

octanol/water

Autoignition

temperature

Decomposition

temperature

Viscosity

Explosive properties

Oxidizing properties

no data available

9.2

10.

10.1

10.2

10.3

10.4

10.5

10.6

11.

11.1

Other safety information

no data available

STABILITY AND REACTIVITY

Reactivity

no data available

Chemical stability

no data available

Possibility of hazardous reactions

no data available

Conditions to avoid

Heat, flames and sparks.

Incompatible materials

Strong bases, Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides, Reducing agents,

Lithium, Sodium/sodium oxides, Magnesium

Hazardous decomposition products

TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC:

2B - Group 2B: Possibly carcinogenic to humans (Chloroform)

3 - Group 3: Not classifiable as to its carcinogenicity to humans (Phenol)

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be fatal if inhaled. Material is extremely destructive to the tissue of the

mucous membranes and upper respiratory tract.

Harmful if swallowed. Causes burns.

Harmful if absorbed through skin. Causes skin burns.

Causes eye burns.

Signs and Symptoms of Exposure

Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and

skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,

pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,

Headache, Nausea

Additional Information

RTECS: Not available

12.

12.1

12.2

12.3

12.4

12.5

12.6

13.

13.1

ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

Results of PBT and vPvB assessment

no data available

Other adverse effects

Harmful to aquatic life.

DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

This combustible material may be burned in a chemical incinerator equipped with an afterburner and

scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging

Dispose of as unused product.

14.

14.1

TRANSPORT INFORMATION

UN number

14.2

ADR/RID: 2810

UN proper shipping name

IMDG: 2810

IATA: 2810

ADR/RID:

IMDG:

IATA:

TOXIC LIQUID, ORGANIC, N.O.S. (Phenol, Chloroform, 3-Methylbutan-1-ol)

TOXIC LIQUID, ORGANIC, N.O.S. (3-Methylbutan-1-ol, Phenol, Chloroform)

Toxic liquid, organic, n.o.s. (3-Methylbutan-1-ol, Phenol, Chloroform)

14.3

Transport hazard class(es)

14.4

14.5

14.6

15.

ADR/RID: 6.1

Packaging group

ADR/RID: II

Environmental hazards

ADR/RID: no

Special precautions for user

no data available

REGULATORY INFORMATION

IMDG: 6.1

IMDG: II

IMDG Marine pollutant: no

IATA: 6.1

IATA: II

IATA: no

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.1

15.2

16.

Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

Chemical Safety Assessment

no data available

OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Carc.

EUH066

Flam. Liq.

H226

H301

H302

H311

H314

H315

H331

H332

H335

H341

H351

H373

Muta.

Skin Corr.

Skin Irrit.

STOT RE

STOT SE

R10

R20

R22

R23/24/25

R34

Acute toxicity

Carcinogenicity

Repeated exposure may cause skin dryness or cracking.

Flammable liquids

Flammable liquid and vapour.

Toxic if swallowed.

Harmful if swallowed.

Toxic in contact with skin.

Causes severe skin burns and eye damage.

Causes skin irritation.

Toxic if inhaled.

Harmful if inhaled.

May cause respiratory irritation.

Suspected of causing genetic defects.

Suspected of causing cancer.

May cause damage to organs through prolonged or repeated exposure.

Germ cell mutagenicity

Skin corrosion

Skin irritation

Specific target organ toxicity - repeated exposure

Specific target organ toxicity - single exposure

Toxic

Flammable.

Harmful by inhalation.

Harmful if swallowed.

Toxic by inhalation, in contact with skin and if swallowed.

Causes burns.

R37

R38

R40

R48/20/21/22

R48/20/22

R66

R68

Irritating to respiratory system.

Irritating to skin.

Limited evidence of a carcinogenic effect.

Harmful: danger of serious damage to health by prolonged exposure through

inhalation, in contact with skin and if swallowed.

Harmful

Harmful: danger of serious damage to health by prolonged exposure through

inhalation and if swallowed.

Repeated exposure may cause skin dryness or cracking.

Possible risk of irreversible effects.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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