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Poly[oxy(methyl-1,2-ethanediyl)],a-hydro-w-hydroxy-, ether with2,2-bis(hydroxymethyl)-1,3-propanediol (4:1)

Huntsman Advanced Materials Americas Inc.

DISTRIBUTED BY FREEMAN MFG & SUPPLY CO. 800-321-8511

24-Hour Emergency Phone: 1-888-354-3323

MSDS No: 6119
Effective Date: 1/20/04 Material Safety Data Sheet

Health: 2
1. PRODUCT IDENTIFICATION 1
Flammability: 1
2 0
Reactivity: 0
Trade Name: Ren 6419
Personal Protection:
Chemical Family: Polyol
HMIS RATING
NFPA RATING
Synonyms:
RP 6419 Hardener

Intended Use or Product Type: Polyurethane

2. COMPOSITION / INFORMATION ON INGREDIENTS

O CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS CARCINOGEN
S STATUS
H ACGIH OSHA MFR. IARC NTP OSHA
A TWA STEL PEL STEL
* 102-60-3 2-Propanol, NE NE NE NE NE NR NR N 1,1',1'',1'''-(1,2-ethanediyldinitrilo)t
etrakis-
Common Amine based tetrol
Name:
* 9051-49-4 Poly(Oxy(Methyl-1,2-Ethanediyl)), NE NE NE NE NE NR NR N .alpha.-Hydro-.omega.-Hydroxy,
Ether with
2,2-Bis(Hydroxymethyl)-1,3-Propa
nediol (4:1)
Common Polyether polyol
Name:
* 115-96-8 Ethanol, 2-Chloro-, Phosphate (3:1) NE NE NE NE NE NR NR N Common Chlorinated phosphate ester
Name:

* = OSHA Hazardous Ingredient

3. HAZARDS IDENTIFICATION

Emergency Overview: Causes irritation if inhaled and can cause skin irritation, eye irritation, and allergic skin reaction. Can be
harmful if swallowed.

Primary Route(s) of Entry: Dermal; heated product may produce inhalable vapors.

Printed: 18/08/2004 Ren 6419 Huntsman Advanced Materials
Effective Date: 1/20/04 Americas Inc.

4. FIRST AID MEASURES

Ingestion: If conscious, give 2 - 4 glasses of water to drink. Do not induce vomiting. Call a physician.

Skin: Immediately wash with soap and water. Remove contaminated clothing and launder before reuse. Destroy contaminated
shoes.

Inhalation: Remove to fresh air. Call a physician.

Eyes: Immediately flush eyes with water for at least 15 minutes. Call a physician.

Overexposure Effects: Causes irritaion if inhaled and can cause skin irritation, eye irritation, and allergic skin reaction. Can be
harmful if swallowed.

Medical Conditions Aggravated by Exposure: Skin, eye and pulmonary conditions.

Additional Information: Referral to a physician is recommended if there is any question about the seriousness of any injury.

5. FIRE FIGHTING MEASURES

> 230??F (> 110 ??C)
Flash Point:
Estimated
Flash Point Method Used:
Not established
Flammable Limits in Air (Lower - % by volume):
Not established
Flammable Limits in Air (Upper - % by volume):

Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.

Fire Fighting Equipment: Use self-contained breathing apparatus.

Fire and Explosion Hazards: Decomposition and combustion products may be toxic.

6. ACCIDENTAL RELEASE MEASURES

Accidental Release Measures: Remove spillage by absorbing in absorbent material.

7. HANDLING AND STORAGE

Signal Word: Warning!

Precautions: Causes irritation if inhaled and can cause skin irritation, eye irritation, and allergic skin reaction. Can be harmful if
swallowed. Avoid breathing vapor or mist. Avoid contact with eyes, skin, and clothing. Avoid tasting or swallowing. Keep
container closed when not in use. Use with adequate ventilation. Wash thoroughly after handling.

Other Handling Information: Nuisance dust may be generated when sanding or sawing cured material.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Printed: 18/08/2004 Ren 6419 Huntsman Advanced Materials
Effective Date: 1/20/04 Americas Inc.

Skin Protection: Wear impermeable gloves.

Respiratory Protection: Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.

Eye Protection: Wear splash-proof chemical goggles.

Engineering Controls: General mechanical and local exhaust in accordance with ACGIH recommendations.

9. PHYSICAL AND CHEMICAL PROPERTIES

Cloudy
Appearance:
Off White
Color:
Liquid
Physical State:
Soluble
Solubility in Water:
Not Determined
Vapor Pressure:
1.19 (water = 1)
Specific Gravity:
Not Determined
Boiling Point:
Not Determined
Evaporation Rate:
Not Determined
Vapor Density:
Not Determined
pH:

Percent Volatile: Negligible.

10. STABILITY AND REACTIVITY

Conditions to Avoid: Excessive heat for prolonged periods of time.

Stability: Stable.

Incompatibility: Strong oxidizers, acids and bases.

Hazardous Decomposition Products: Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.

Hazardous Polymerization: Will not occur.

11. TOXICOLOGICAL INFORMATION

Acute Oral Effects (LD50): Component(s) are toxic, 50 - 500 mg/kg (rat).
Ethanol, 2-chloro-, phosphate (3:1)= 550 mg/kg (rat)

Acute Inhalation Exposure Effects: Respiratory irritant.

Sensitization: Possible in susceptible individuals.

Skin Irritation: Irritant.

Eye Irritation: Irritant.

12. ECOLOGICAL INFORMATION

Printed: 18/08/2004 Ren 6419 Huntsman Advanced Materials
Effective Date: 1/20/04 Americas Inc.

13. DISPOSAL CONSIDERATIONS

Waste Disposal Method: Consult qualified local or corporate personnel for method that will comply with local, state and federal
health and environmental regulations.

14. TRANSPORT INFORMATION

DOT: Non-Bulk
Resin compounds, N.O.I.
Proper Shipping Name:

Department of Transportation: Not regulated as a hazardous material by the U.S. Dept. of Transportation (DOT) 49 CFR 172.101
hazardous materials table.

15. REGULATORY INFORMATION

US Federal Regulations:
Occupational Safety and Health Act (OSHA): This Material Safety Data Sheet (MSDS) has been prepared in compliance with the
federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous chemical under
that standard.

Resource Conservation and Recovery Act (RCRA): Not a hazardous waste under RCRA (40 CFR 261).

SARA Title III: Section 313 Toxic Chemical List (TCL): This product contains a toxic chemical(s) for routine annual toxic
chemical release reporting under section 313 (40 CFR 372). This information must be included in all MSDS's copied or distributed for
this material.

Chemical Name: Aluminum Oxide (Al2O3)
Common Name: Alumina
Percent in Composition: 1.6571 % by wt
Comment:

TSCA Section 8(b) - Inventory Status: Chemical components listed on TSCA Inventory.

TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b) export
notification.

State Regulations:
Pennsylvania Right-to-Know: The following is required composition information:

Chemical Name: Poly(Oxy(Methyl-1,2-Ethanediyl)), .alpha.-Hydro-.omega.-Hydroxy, Ether with
2,2-Bis(Hydroxymethyl)-1,3-Propanediol (4:1)
Common Name: Polyether polyol
CAS Number: 9051-49-4
Comment: Not on Pennsylvania Hazardous Substance List

Chemical Name: Ethanol, 2-Chloro-, Phosphate (3:1)

Printed: 18/08/2004 Ren 6419 Huntsman Advanced Materials
Effective Date: 1/20/04 Americas Inc.

Common Name: Chlorinated phosphate ester
CAS Number: 115-96-8
Comment: Not on Pennsylvania Hazardous Substance List

Chemical Name: 2-Propanol, 1,1',1'',1'''-(1,2-ethanediyldinitrilo)tetrakis-
Common Name: Amine based tetrol
CAS Number: 102-60-3
Comment: Not on Pennsylvania Hazardous Substance List

Chemical Name: Polyphosphoric Acids, Ammonium Salts
Common Name: Ammonium polyphosphate
CAS Number: 68333-79-9
Comment: Not on Pennsylvania Hazardous Substance List

Chemical Name: Silica
Common Name: Fumed Silica
CAS Number: 7631-86-9
Comment: Hazardous Substance

Chemical Name: Aluminum Oxide (Al2O3)
Common Name: Alumina
CAS Number: 1344-28-1
Comment: Environmental Hazardous Substance

16. OTHER INFORMATION

6119
MSDS No:
Kenneth L. Payne
Approved By:
E,H&S Manager
Title:

Disclaimer: The following supercedes Buyer??s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,
EXPRESS OR IMPLIED, INCLUDING OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. No
statements herein are to be construed as inducements to infringe any relevant patent. Under no circumstances shall Seller be liable for
incidental, consequential or indirect damages for alleged negligence, breach of warranty, strict liability, tort or contract arising in
connection with the product(s). Buyer??s sole remedy and Seller??s sole liability for any claims shall be Buyer??s purchase price. Data
and results are based on controlled or lab work and must be confirmed by Buyer by testing for its intended conditions of use. The
product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged contact with mucous membranes,
abraded skin, or blood is intended; or for uses for which implantation within the human body is intended.

Printed: 18/08/2004
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