information Related products Suppliers

2-Pyrrolidinemethanol,1-[[(2S)-1-methyl-2-pyrrolidinyl]methyl]-, (2S)-

Material Safety Data Sheet
Section 1. Product and Company Identification
Product Name (2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)
8.18259
Product Code
- methyl]-pyrrolidine for synthesis
EMD Chemicals Inc.
Manufacturer Effective Date 7/25/2003
P.O. Box 70
2/13/2004
Print Date
480 Democrat Road
Gibbstown, NJ 08027
Prior to January 1, 2003 EMD Chemicals Inc. was EM
Industries, Inc. or EM Science, Division of EM Industries,
Inc.
For More Information Call In Case of Emergency Call
(914) 592-4660 800-424-9300 CHEMTREC (USA)
M-F, 9AM-4:30 PM EST 613-996-6666 (Canada)
24 Hours/Day: 7 Days/Week
None.
Synonym
Analytical reagent.
Material Uses

Organic
Chemical Family
Section 2. Composition and Information on Ingredients
Component CAS # % by
Weight
(2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)-methyl]-pyrrolidine for 66283-23-6 100
synthesis

Section 3. Hazards Identification
Liquid. (Oily liquid.)
Physical State and
Appearance
CAUTION !
Emergency Overview
MAY BE HARMFUL IF INHALED OR SWALLOWED.
MAY CAUSE EYE AND SKIN IRRITATION.

Dermal contact. Eye contact. Inhalation. Ingestion.
Routes of Entry

Potential Acute Health Effects
Eyes May be hazardous in case of eye contact (irritant).
Skin May be hazardous in case of skin contact (irritant). Skin inflammation is characterized by
itching, scaling, reddening, or, occasionally, blistering.
Inhalation May be hazardous in case of inhalation.
Ingestion May be hazardous in case of ingestion.
Potential Chronic Health Effects
Carcinogenic Effects This material is not known to cause cancer in animals or humans.
Additional information See Toxicological Information (section 11)

Continued on Next (2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)
8.18259
- methyl]-pyrrolidine for synthesis
Repeated or prolonged exposure is not known to aggravate medical condition.
Medical Conditions
Aggravated by
Overexposure:

Section 4. First Aid Measures
Check for and remove any contact lenses. In case of contact, immediately flush eyes with
Eye Contact
plenty of water for at least 15 minutes. Get medical attention.
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an
Skin Contact
emollient. Remove contaminated clothing and shoes. Wash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything
by mouth to an unconscious person. If large quantities of this material are swallowed, call a
physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 5. Fire Fighting Measures
May be combustible at high temperature.
Flammability of the
Product
Not available.
Auto-ignition
Temperature
Not available.
Flash Points

Not available.
Flammable Limits

Not applicable.
Products of Combustion

Not available.
Fire Hazards in Presence
of Various Substances
Risks of explosion of the product in presence of static discharge: No.
Explosion Hazards in
Presence of Various
Risks of explosion of the product in presence of mechanical impact: No.
Substances
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
Protective Clothing (Fire) Be sure to use an approved/certified respirator or equivalent.

Not available.
Special Remarks on Fire
Hazards
Development of hazardous combustion gases or vapors possible in the event of fire.
Special Remarks on
Explosion Hazards

Section 6. Accidental Release Measures
Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Small Spill and Leak

Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill and Leak
Finish cleaning by spreading water on the contaminated surface and allow to evacuate through
the sanitary system.
No specific spill kit required for this product.
Spill Kit Information

Continued on Next (2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)
8.18259
- methyl]-pyrrolidine for synthesis
Section 7. Handling and Storage
Avoid contact with eyes, skin and clothing. Do not ingest. Avoid breathing vapors or spray
Handling
mists. Keep container closed. Use only with adequate ventilation. Wash thoroughly after
handling.
Keep container tightly closed. Keep container in a cool, well-ventilated area. Store between
Storage
15 to 25??C (59 to 77??F).

Section 8. Exposure Controls/Personal Protection
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
Engineering Controls
vapors below their respective occupational exposure limits. Ensure that eyewash stations and
safety showers are proximal to the work-station location.
Personal Protection
Eyes Splash goggles.
Body Lab coat.
Respiratory Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Hands Gloves.
Feet Not applicable.
Protective Clothing
(Pictograms)

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self-contained breathing
Personal Protection in
apparatus should be used to avoid inhalation of the product. Suggested protective clothing
Case of a Large Spill
might not be sufficient; consult a specialist BEFORE handling this product.
Exposure Limits
Product Name
(2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)-methyl]-pyrrolidine
Not available.
for synthesis

Section 9. Physical and Chemical Properties
Not available.
Odor

Colorless.
Color

Liquid. (Oily liquid.)
Physical State and
Appearance
198.31 g/mole
Molecular Weight

C11H22N2O
Molecular Formula

Not available.
pH

112??C (233.6??F)
Boiling/Condensation
Point
Not available.
Melting/Freezing Point

Not available.
Specific Gravity

Vapor Pressure Not available.

Not available.
Vapor Density

Not available.
Odor Threshold

Continued on Next (2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)
8.18259
- methyl]-pyrrolidine for synthesis
Not available.
Evaporation Rate

Not available.
LogKow

Not available.
Solubility

Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Not available.
Conditions of Instability

Not available.
Incompatibility with
Various Substances
Not available.
Rem/Incompatibility

Hazardous Decomposition NOx
Products
Hazardous Polymerization Will not occur.

Section 11. Toxicological Information
(2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)-methyl]-pyrrolidine
RTECS Number: Not available.
for synthesis
LD50: Not available.
Toxicity
LC50: Not available.
Not available.
Chronic Effects on
Humans
May be hazardous in case of eye contact (irritant). May be hazardous in case of skin contact
Acute Effects on Humans
(irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally,
blistering. May be hazardous in case of inhalation. May be hazardous in case of ingestion.

Synergetic Products Not available.
(Toxicologically)
Irritancy Draize Test: Not available.

Sensitization Not available.

Carcinogenic Effects This material is not known to cause cancer in animals or humans.

Toxicity to Reproductive Not available.
System
Teratogenic Effects Not available.
Mutagenic Effects Not available.

Section 12. Ecological Information
Not available.
Ecotoxicity

Not available.
BOD5 and CO
Toxicity of the Products of The products of degradation are less toxic than the product itself.
Biodegradation

Continued on Next (2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)
8.18259
- methyl]-pyrrolidine for synthesis
Section 13. Disposal Considerations
Not available.
EPA Waste Number

Material does not have an EPA Waste number and is not a listed waste, however consultation
Treatment
with a permitted waste disposal site (TSD) should be accomplished.
ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE
WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
Section 14. Transport Information
Not available.
DOT Classification

Not available.
TDG Classification
Not available.
IMO/IMDG
Classification
Not available.
ICAO/IATA
Classification

Section 15. Regulatory Information
TSCA: Not Listed On the TSCA Inventory. For Research & Development Use Only. Not for
U.S. Federal Regulations
Manufacturing or Commercial Purposes.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were
found.
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
Not controlled under WHMIS (Canada).
WHMIS (Canada)

No products were found.
This product has been classifed in accordance with the hazard criteria of the Controlled Product
Regulations and the MSDS contains all required information.
International Regulations
Not available.
EINECS

R36/38- Irritating to eyes and skin.
DSCL (EEC)

International Lists Australia (NICNAS):
(2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)-methyl]-pyrrolidine for synthesis

Philippines (RA6969):
(2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)-methyl]-pyrrolidine for synthesis
China: No products were found.
State Regulations New Jersey: (2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)-methyl]-pyrrolidine for
synthesis
California prop. 65: No products were found.

Continued on Next (2-S,2'S)-(-)-2-Hydroxylmethyl-1-[(1-methylpyrrolidine-2-yl)
8.18259
- methyl]-pyrrolidine for synthesis
Section 16. Other Information
National Fire Fire Hazard
1
Protection 2 0
Health Reactivity
Association
(U.S.A.) Specific Hazard

Changed Since Last +
Revision

Notice to Reader
The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable, are offered for
information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly
trained person having the necessary technical skills. Users should consider these data only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to
assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the
protection of the environment. EMD CHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND,
EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO
THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.

;