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Rosin, fumarated, polymer with ethylene glycol and pentaerythritol

#528
MATERIAL SAFETY DATA SHEET
NFPA RATING: Health = 1 Flammability = 0 Reactivity = 0
HMIS RATING: Health = 1 Flammability = 0 Reactivity = 0

SECTION I -- IDENTITY AND MANUFACTURER'S INFORMATION (#0747A)
Manufacturer's Name: HILLYARD INDUSTRIES Product Name: NORTH STA Address: 302 North Fourth Street Date Prepared: January 24, 2006
St. Joseph, MO 64502 Prepared by: Regulatory Affairs Department
Emergency Telephone No.: (800) 424-9300 (Only in the event of chemical emergency involving a spill, leak, fire, exposure or
accident involving chemicals.) Other information calls: (816) 233-1321 (Ext. 8285)
http://www.hillyard.com
SECTION II -- INGREDIENTS/IDENTITY INFORMATION
Components
(Specific Chemical Identity: OTHER LIMITS
Common Name(s) CAS# OSHA PEL ACGIH TLV RECOMMENDED %
Dipropylene Glycol Methyl Ether (1) 34590-94-8 100 ppm 100 ppm STEL = 150 2-4
5 mg/m3 5 mg/m3
Zinc Oxide 1314-13-2 N/A less than 0.9
Water 7732-18-5 none none none ---
Acrylic Copolymer Emulsion Unknown by not established not established N/A ---
Hillyard
Modified Rosin Ester 68152-57-8 not established not established N/A ---
Diethylene Glycol Monoethyl Ether** 111-90-0 not established not established N/A 1-3
Tributoxyethyl Phosphate** 78-51-3 not established not established N/A 1-3
(1) Regulated by OSHA, FL, IL, MA, NJ, PA, RI
**This product contains the following chemicals subject to reporting requirements of SARA Title III, Section 313: Diethylene
Glycol Monoethyl Ether and Tributoxyethyl Phosphate.

SECTION III -- PHYSICAL / CHEMICAL CHARACTERISTICS
Specific Gravity (H2O) = 1): 25??C = 1.04 & 39??C = 1.04
Boiling Point: 209??F
Vapor Pressure (mm Hg.): 19.3 77.6%
Percent Volatile by Volume (%):
Vapor Density (AIR = 1): 1.4 Evaporation Rate (ethyl ether = 1): Slower than 1
Solubility in Water: Complete Milky, white solution; non-objectionable polymer odor
Appearance and Odor:
8.0 - 9.0
pH (concentrate) =

SECTION IV -- FIRE AND EXPLOSION HAZARD DATA
None (Tag Closed Cup) Flammable Limits: LEL = N/A UEL = N/A
Flash point:
Not applicable
Extinguishing Media:
Special Fire Fighting Procedures: Wear self-contained breathing apparatus (pressure-demand, MSHA/NIOSH
approved or equivalent) and full protective gear.
Unusual Fire and Explosion Hazards: Material can spatter above 100??C/212??F. Polymer film can burn.

SECTION V -- PHYSICAL HAZARDS
Stability: Stable Conditions to Avoid: Onset of decomposition is 77??C/350??F
Incompatibility (Materials to Avoid): None known to Hillyard
Hazardous Decomposition Products or Byproducts: None known to Hillyard
Hazardous Polymerization: Will not occur. Conditions to Avoid: None known to Hillyard
SECTION VI -- HEALTH HAZARD DATA
Inhalation? Yes Skin? Yes Ingestion? Yes
Routes of entry:

HEALTH HAZARDS (1. Acute and 2. Chronic)
1. According to Primary Skin Irritation Test (FHSA), product is not an irritant; prolonged contact may cause moderate skin
irritation in sensitive individuals. Eye Irritation Test (FHSA), not an eye irritant; however, prolonged exposure may cause
conjunctivae irritation in sensitive individuals. Overexposure to high airborne levels or liquid splashes of Dipropylene
glycol methyl ether may cause eye, nose, throat, and skin irritation. Harmful if swallowed.
2. None known to Hillyard Industries.
page 2 of #528 - North Star
HEALTH HAZARD DATA (CONTINUED):
Chemical listed as Carcinogen or Potential Carcinogen:
National Toxicology Program = No I.A.R.C. Monographs = No OSHA = No
This product has no carcinogens listed by IARC, NTP, NIOSH, or ACGIH as of this date, greater than or equal to 0.1%.
Signs and Symptoms of Exposure: Prolonged eye contact with concentrate can cause slight irritation; test subjects showed eyes
cleared up in 48 hours. Prolonged skin contact with concentrate can cause moderate skin irritation but test subjects recovered by
day 8.
Medical Conditions Generally Aggravated by Exposure: Dipropylene glycol methyl ether may aggravate obstructive airway
diseases (persons with impaired pulmonary functions) and liver and kidney problems. Persons with pre-existing skin disorders may
be more susceptible to irritation.
Emergency and First Aid Procedures: If swallowed induce vomiting immediately. Immediately consult medical personnel. If
inhaled, remove to fresh air. If discomfort persists, get medical attention. In case of contact, immediately flush eyes or skin with
plenty of water for at least 15 minutes.
SECTION VII -- PRECAUTIONS FOR SAFE HANDLING AND USE
Steps To Be Taken In Case Material Is Released Or Spilled: Pick up with mop or wet vac and wash away with water. Absorb
large spills with oil-dri or similar inert absorbent. Collect material for proper disposal.
Waste Disposal Method: Wash small quantities down sewer with large amount of water. Contains ammonia which may be toxic to
aquatic life. Keep spills and cleaning runoffs out of municipal sewers and open bodies of water. Large spills should be picked up
with wet vac or absorbent material. Landfill or incinerate solids. Dispose of liquid per local, state or federal regulations.
Precautions To Be Taken In Handling And Storing: Freezing of product may rupture container. Product shelf life is best
retained by storage at 45 - 100??F temperature.
Other Precautions: Inhalation exposure to spray mist should be maintained at less than 10 mg/m3 per eight hours exposure (TWA
limit established for nuisance dust. USE WITH ADEQUATE VENTILATION. Avoid breathing vapors or spray mist. Open
windows and doors, use exhaust fans or other means to insure fresh air entry during application and drying. Refer to OSHA
Standard 29 CFR 1910.94 for technical guidelines on keeping air contamination below acceptable exposure limits. Keep container
closed when not in use.
SECTION VIII -- CONTROL MEASURES
Respiratory Protection (Specify Type): Wear appropriate, properly fitted respirator (NIOSH or MSHA approved) unless air
monitoring demonstrates vapor or mist levels are below applicable limits.
Ventilation: Good ventilation for public areas is 10 air changes per hour.
Recommended Recommended N/A Other = N/A
Local Exhaust = Mechanical (General) = Special =
Protective Gloves: Prolonged or repeated contact use solvent-resistant rubber or neoprene gloves
Eye Protection: None needed for normal use
Other Protective Clothing or Equipment: Protective clothing such as uniforms or coveralls.
Work / Hygienic Practices: Wash contaminated clothing before reuse (including shoes).
SECTION IX - TRANSPORTATION INFORMATION
DOT SHIPPING DESCRIPTION ON BILL OF LADING:
Applicable regulations: 49 CFR = no; IMCO = no; IATA = no.
Proper shipping name: Liquid Floor Wax & Polish
UN No.: not applicable; Limited Qty.: not applicable; Hazard Class: not applicable.
Labels required: not required DOT Exception: not applicable
EPA Hazardous waste number / code: not listed
Hazardous waste characteristics:
Ignitability = not applicable; Corrosivity = not applicable; Reactivity = not applicable.
DISCLAIMER OF WARRANTIES
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE, OR OF ANY NATURE ARE MADE WITH RESPECT TO THE PRODUCT(S) OR INFORMATION
CONTAINED IN THIS MATERIAL SAFETY DATA SHEET.
The information and recommendations contained in this Material Safety Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the
Occupational Safety and Health Standards Hazard Communication Rule. All information contained herein is presented in good faith and
is believed to be appropriate and accurate.
THE BUYER OR USER ASSUMES ALL RISKS ASSOCIATED WITH THE USE, MISUSE OR DISPOSAL OF THIS PRODUCT. THE
BUYER OR USER IS RESPONSIBLE TO COMPLY WITH ALL FEDERAL, STATE OR LOCAL REGULATIONS CONCERNING
THE USE, MISUSE OR DISPOSAL OF THESE PRODUCTS.

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