information Related products Suppliers

C.I. Pigment Black 12

Material Safety Data Sheet
Date Prepared: May 2003
Product Number:6131 Revision Date: April 2004

SECTION 1: Manufacturer Identification

Mason Color Works, Inc. Phone: (330) 385-4400
250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488
East Liverpool, OH 43920-5076

HMIS Classification: Health 2*
Flammability 0
Reactivity 0
Personal Protection See Section 6
*Indicates possible chronic health effects.

SECTION 2: Identification of Product
Chemical Family: Inorganic
Product Names: Titanium Iron Brown6131
Chemical Abstract Number(CAS): 68187-02-0
Chemical Name: Iron Titanium Brown - Spinel
Chemical Formula: Fe 2TiO4

SECTION 3 & 4: Hazardous ingredients Identity/Information and Overexposure Symptoms
ACGIH-TLVs OSHA PELs NOISHA RELs
5 mg/m 3 10 mg/m 3 5 mg/m 3
Iron Oxide (Fe2O3)
Cas # 1309-37-1

ACGIH: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms
of its carcinogencity in humans/animals. The value is for a particulate matter containing no asbestos and
1% crystalline silica.

SYMPTOMS OF OVEREXPOSURE:
Inhalation: Repeated and prolonged exposure may cause beginnings Pneumoconiosis called
Sideordsis.
Eye Contact: May cause irritation.
Skin Contact: May cause mechanical skin irritation.
Ingestion: Expected to be non-toxic.
ACGIH-TLVs OSHA PELs NOISHA RELs
10 mg/m 3 10 mg/m 3 (total) 0.2 mg/m 3
Titanium Dioxide (TiO2)
5 mg/m 3 (respirable)
Cas # 1309-37-1

SYMPTOMS OF OVEREXPOSURE:
Inhalation: Inhalation of dust can cause irritation of the nose, throat, and lungs.
Eye Contact: Like any foreign body, particles can cause mechanical irritation.
Skin Contact: This material can cause irritation if not promptly washed from skin.
Ingestion: This material is not expected to produce adverse effects.

SECTION 5: Emergency and First Aid Procedures
Eye: flush thoroughly with water for 15 minutes.
Skin: remove contaminated clothing, wash thoroughly with soap and water.
Inhalation: remove to fresh air, may give oxygen if needed.
Ingestion: give large amounts of water to induce vomiting, only in conscious persons.

IF THESE FIRST AID MEASURES FAIL, CONSULT A PHYSICIAN

Principal Routes of Entry:
Inhalation: Dust from this product may cause irritation of the respiratory system.
Overexposure may cause lung damage.
Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea,
vomiting and diarrhea.
Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation.

SECTION 6: Special Protection Information
Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with
adequate ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limit.
Wash thoroughly after handling. No food or beverage should be consumed in work area.
Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye
contact. Safety showers and eye statioins must be present in work stations.
Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust
levels below Occupational Exposure Limits.

SECTION 7: Physical and Chemical Characteristics

Boiling Point: N/A Odor: Odorless
Solubility in water: trace Specific Gravity (water=1): N/A
Vapor Pressure (mmHg): N/A Evaporation rate: None
Vapor Density (air=1): N/A % Volatile by volume: None
Appearance:

SECTION 8: Reactivity Data
Stability: Stable
Hazardous Polymerization: will not occur
Incompatibility: None
Hazard Decomposition of product: N/A

SECTION 9: Fire and Explosive Data
Flash point: N/A Flammable Limits:
Unusual Fire and Explosion Hazard : None expected.
Extinguishing Media: Carbon Dioside, dry chemical or water
Special Fire Fighting Procedures : Wear self contained breathing apparatus when
large quantities involved.

SECTION 10: Spill or Leak Procedures

Contain spillage and scoop or vacuum. Avoid making dust, put in appropriate container
for disposal. Waste disposal method in accordance with Federal, State and Local Laws.

This product is a blend of various metal oxides, salts and some compounds which are
interfused by high calcinations to form the finished product. Section 3, Hazardous
ingredients Identity/Information, and Section 4, Symptoms of Overexposure, pertain to
individual components. Section 5 through Section 10 are in reference to the finished
product.

******* Attention all Retailers of Mason Stains *******

ALL retailers of this product are REQUIRED by law to supply their customers with a copy of
material safety data sheet with initial purchase.

***SARA 313

This product contains certain oxides and compounds which are subject to reporting requirements of
Superfund Amendment and Reauthorization Act ( SARA) of 1986, Section 313 of the Emergency Planning
and Community Right to Know Act and of 40 CRF, Part 372.

The information contained in this MSDS must be provided to every employee who is exposed to this
product in any way. We recommend the user reads and understands the contents herein before
using this material.

PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY! MSDS'S ARE REQUIRED FO FIRST SHIPMENT, AND WILL BE SENT AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT
OR BY REQUEST.

Disclamer

;