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VANADIUM OXIDE

Material Safety Data Sheet
acc. to OSHA and ANSI

1 Identification of substance:
Product details:
Product name: Vanadium (IV,V) oxide
2 Composition/Data on components:
Chemical characterization:
Description: (CAS#)
Vanadium (IV,V) oxide (CAS# 12037-42-2), 100%

3 Hazards identification
Hazard description:

Xn Harmful

Information pertaining to particular dangers for man and
environment
R 20/22 Harmful by inhalation and if swallowed.
R 36/37 Irritating to eyes and respiratory system.
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH 3 Health (acute effects) = 3
Flammability = 0
FIRE 0
Reactivity = 0
REACTIVITY 0

4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep
patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Vanadium (IV,V) oxide

After eye contact
Rinse opened eye for several minutes under running water. Then
consult a doctor.
After swallowing Seek immediate medical advice.

5 Fire fighting measures
Suitable extinguishing agents
CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents
Water
Halogenated extinguisher
Special hazards caused by the material, its products of combustion
or resulting gases:
In case of fire, the following can be released:
Toxic metal oxide fume
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.

6 Accidental release measures
Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Measures for environmental protection:
Do not allow material to be released to the environment without
proper governmental permits.
Measures for cleaning/collecting:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Additional information:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage
Handling
Information for safe handling:
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
No special measures required.
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from halogens.
Further information about storage conditions:
Keep container tightly sealed.

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Vanadium (IV,V) oxide

Store in cool, dry conditions in well sealed containers.

8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous
chemicals and having an average face velocity of at least 100 feet
per minute.
Components with limit values that require monitoring at the
workplace:
Not required.
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be
followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands: Impervious gloves
Eye protection: Safety glasses
Body protection: Protective work clothing.

9 Physical and chemical properties:
General Information
Form: Powder
Color: Black
Odor: Not determined
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature /
start: Not determined
Flash point: Not applicable
Ignition temperature: Not determined
Decomposition temperature: Not determined
Danger of explosion: Product does not present an
explosion hazard.
Explosion limits:
Lower: Not determined
Upper: Not determined

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Vanadium (IV,V) oxide

Vapor pressure: Not determined
Density: Not determined
Solubility in / Miscibility with
Water: Insoluble

10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to
specifications.
Materials to be avoided:
Alkali metals
Halogens
Dangerous reactions No dangerous reactions known
Dangerous products of decomposition: Toxic metal oxide fume

11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Subacute to chronic toxicity:
Vanadium compounds act chiefly as an irritant to the eyes and
respiratory tract. Exposure may cause conjunctivitis, rhinitis and
reversible irritation of the respiratory tract. More severe cases
may cause bronchitis, bronchospasms and asthma like disease. May
cause polycythemia, red blood cell destruction and anemia,
albuminuria and hematuria, gastrointestinal disorders, nervous
complaints and severe cough.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
No classification data on carcinogenic properties of this material
is available from the EPA, IARC, NTP, OSHA or ACGIH.

12 Ecological information:
General notes:
Do not allow material to be released to the environment without
proper governmental permits.

13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations to ensure proper
disposal.

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Vanadium (IV,V) oxide

Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.

14 Transport information
DOT regulations:

Hazard class: 6.1
Identification number: UN3285
Packing group: II
Proper shipping name (technical
name): Vanadium compound, n.o.s.,
vanadium (IV,V) oxide
Land transport ADR/RID (cross-border)

ADR/RID class: 6.1 Toxic substances
Item: 58b
Danger code (Kemler): 60
UN-Number: 3285
Description of goods: Vanadium compound, n.o.s.,
vanadium (IV,V) oxide
Maritime transport IMDG:

IMDG Class: 6.1
UN Number: 3285
Packaging group: II
Proper shipping name: Vanadium compound, n.o.s.,
vanadium (IV,V) oxide
Air transport ICAO-TI and IATA-DGR:

ICAO/IATA Class: 6.1
UN/ID Number: 3285
Packaging group: II

D Material Safety Data Sheet
acc. to OSHA and ANSI

Product name: Vanadium (IV,V) oxide

Proper shipping name: Vanadium compound, n.o.s.,
vanadium (IV,V) oxide

15 Regulations
Product related hazard informations:
Hazard symbols:
Xn Harmful
Risk phrases:
20/22 Harmful by inhalation and if swallowed.
36/37 Irritating to eyes and respiratory system.
Safety phrases:
9 Keep container in a well-ventilated place.
26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
36 Wear suitable protective clothing.
National regulations
This product is not listed in the U.S. Environmental Protection
Agency Toxic Substances Control Act Chemical Substance Inventory.
Use of this product is restricted to research and development only.
Information about limitation of use:
For use only by technically qualified individuals.

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