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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501 02/06/2005

Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501
MANUFACTURER: 3M
DIVISION: Marine & Specialty Vehicle

ADDRESS: 3M Center
St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 02/06/2005
Supercedes Date: Initial Issue

Document Group: 19-4642-5

Product Use:
Specific Use: Marine Adhesive Sealant

SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
URETHANE PREPOLYMER 68611-34-7 40.0 - 70.0
TALC 14807-96-6 15.0 - 40.0
TITANIUM DIOXIDE 13463-67-7 4.0 - 7.0
DIETHYLENE GLYCOL MONOETHYL ETHER ACETATE 112-15-2 1.0 - 2.5
FUMED SILICA, CRYSTALLINE FREE 112945-52-5 1.0 - 2.5
IRON MAGNESIUM OXIDE 12068-86-9 1.0 - 2.5
INORGANIC OXIDES Mixture 1.0 - 2.5
ZINC OXIDE 1314-13-2 1.0 - 2.5
ALKYL ISOCYANATE SILANE 85702-90-5 < 1.5
TOLUENE DIISOCYANATE 26471-62-5 <1
HEPTANE 142-82-5 < 0.25
TOLUENE 108-88-3 < 0.03
HEXAMETHYLENE DIISOCYANATE 822-06-0 < 0.02

SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
Odor, Color, Grade: High viscosity tan paste

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501 02/06/2005

General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause allergic
respiratory reaction. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a
chemical or chemicals which can cause birth defects or other reproductive harm.

3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.

Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.

May be absorbed following inhalation and cause target organ effects.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.

May be absorbed following ingestion and cause target organ effects.

Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.

Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.

Prolonged or repeated exposure may cause:
Kidney Effects: Signs/symptoms may include reduced or absent urine production, increased serum creatinine, lower back
pain, increased protein in urine, and increased blood urea nitrogen (BUN).

Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.

Ingredient C.A.S. No. Class Description Regulation
TOLUENE DIISOCYANATE 26471-62-5 Group 2B International Agency for Research on Cancer
TOLUENE DIISOCYANATE 26471-62-5 Anticipated human carcinogen National Toxicology Program Carcinogens

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501 02/06/2005

SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.

Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.

Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.

If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get immediate medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL

5.2 EXTINGUISHING MEDIA
Non-combustible. Choose material suitable for surrounding fire.

5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).

Unusual Fire and Explosion Hazards: Not applicable.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.

SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Ventilate the area with fresh air. Pour isocyanate decontaminant solution (90% water, 8% concentrated
ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30
minutes. Cover with absorbent material. Place in a container approved for transportation by appropriate authorities, but do not seal
the container for 48 hours to avoid pressure build-up. Collect as much of the spilled material as possible. Clean up residue with an
appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501 02/06/2005

on the solvent label and MSDS. Dispose of collected material as soon as possible.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid eye contact with
vapors, mists, or spray. Keep out of the reach of children. Do not breathe vapors. Avoid eye contact with dust or airborne particles.
Do not use heat to aid in the removal of product. The application of heat may generate levels of P,P'-METHYLENEBIS(PHENYL
ISOCYANTE) in excess of the TLV.

7.2 STORAGE
Store in a cool place. Store away from heat. Keep container in well-ventilated area.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Do not use in a confined area or areas with little or no air movement.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields.

8.2.2 Skin Protection
Avoid skin contact.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Butyl Rubber, Nitrile Rubber.

8.2.3 Respiratory Protection
Do not breathe vapors.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M
Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. Do not use heat to aid in
the removal of product. The application of heat may generate levels of P,P'-METHYLENEBIS(PHENYL ISOCYANTE) in excess of
the TLV.

8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
CADMIUM DUST OSHA TWA, as dust 0.2 mg/m3 Table Z-2
CADMIUM DUST OSHA CEIL, as dust 0.6 mg/m3 Table Z-2
CHROMIUM (VI), CERTAIN WATER ACGIH TWA, as Cr 0.01 mg/m3 Table A1
INSOLUBLE COMPOUNDS

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501 02/06/2005

FREE ISOCYANATES 3M TWA 0.005 ppm
FREE ISOCYANATES 3M STEL 0.02 ppm
HEPTANE ACGIH TWA 400 ppm
HEPTANE ACGIH STEL 500 ppm
HEPTANE OSHA TWA, Vacated 400 ppm
HEPTANE OSHA TWA 500 ppm Table Z-1
HEPTANE OSHA STEL, Vacated 500 ppm
HEXAMETHYLENE DIISOCYANATE ACGIH TWA 0.005 ppm
MERCURY NON-ALKYL, VAPOR ACGIH TWA, as Hg 0.05 mg/m3 Skin Notation*
MERCURY NON-ALKYL, VAPOR OSHA TWA, as Hg 0.05 mg/m3 Skin Notation*; Table Z-1A
MERCURY, ARYL & INORGANIC OSHA CEIL, as Hg 0.1 mg/m3 Skin Notation*; Table Z-1A
COMPOUNDS
MERCURY, INORGANIC COMPOUNDS ACGIH TWA, as Hg 0.025 mg/m3 Skin Notation*; Table A4
SELENIUM COMPOUNDS ACGIH TWA, as Se 0.2 mg/m3
SELENIUM COMPOUNDS OSHA TWA, as Se 0.2 mg/m3 Table Z-1
SILICATES (LESS THAN 1% OSHA TWA, as total dust 0.1 fiber/cc Standard Appendix
CRYSTALLINE SILICA) TALC
CONTAINING ASBESTOS
SILICATES (LESS THAN 1% OSHA STEL, as total dust 1 fiber/cc Standard Appendix
CRYSTALLINE SILICA) TALC
CONTAINING ASBESTOS
TALC ACGIH TWA, respirable 2 mg/m3 Table A4
TALC CMRG TWA, as respirable 0.5 mg/m3
dust
TALC OSHA TWA, respirable 2 mg/m3 Table Z-1A
TIN, ORGANIC COMPOUNDS ACGIH TWA, as Sn 0.1 mg/m3 Skin Notation*; Table A4
TIN, ORGANIC COMPOUNDS ACGIH STEL, as Sn 0.2 mg/m3 Skin Notation*
TIN, ORGANIC COMPOUNDS OSHA TWA, as Sn 0.1 mg/m3 Skin Notation*; Table Z-1A
TITANIUM DIOXIDE ACGIH TWA 10 mg/m3 Table A4
TITANIUM DIOXIDE CMRG TWA, as respirable 5 mg/m3
dust
TITANIUM DIOXIDE OSHA TWA, Vacated, as 10 mg/m3
dust
TITANIUM DIOXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1
TOLUENE ACGIH TWA 50 ppm Skin Notation*; Table A4
TOLUENE CMRG STEL 75 ppm Skin Notation*
TOLUENE OSHA TWA, Vacated 100 ppm
TOLUENE OSHA STEL, Vacated 150 ppm
TOLUENE OSHA TWA 200 ppm Table Z-2
TOLUENE OSHA CEIL 300 ppm Table Z-2
ZINC OXIDE ACGIH TWA, respirable 2 mg/m3
ZINC OXIDE ACGIH STEL 10 mg/m3
ZINC OXIDE OSHA TWA, as fume 5 mg/m3 Table Z-1
ZINC OXIDE OSHA TWA, respirable 5 mg/m3 Table Z-1
ZINC OXIDE OSHA STEL, Vacated, as 10 mg/m3
fume
ZINC OXIDE OSHA TWA, Vacated, as 10 mg/m3
dust
ZINC OXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1

* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.

VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.

SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501 02/06/2005

AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Paste
Specific Physical Form:
High viscosity tan paste
Odor, Color, Grade:
Solid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
Not Applicable
Boiling point
11.03 lb/gal
Density
No Data Available
Vapor Density

No Data Available
Vapor Pressure

1.3 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
No Data Available
Melting point

Nil
Solubility in Water
100,000 - 500,000 centipoise
Viscosity

SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.

Materials and Conditions to Avoid: Reaction with water, alcohols, and amines is not hazardous if container can vent to the
atmosphere to prevent pressure buildup.; Amines; Alcohols; Water

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products
Substance Condition
Isocyanates Not Specified
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Hydrogen Cyanide Not Specified
Irritant Vapors or Gases Not Specified
Oxides of Nitrogen Not Specified

SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501 02/06/2005

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION
Not determined.

CHEMICAL FATE INFORMATION
Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal
alternative, dispose of waste product in a facility permitted to accept chemical waste.

EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-9801-0690-4

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.

SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.

311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
ZINC OXIDE (ZINC COMPOUNDS) 1314-13-2 1.0 - 2.5
DIETHYLENE GLYCOL MONOETHYL 112-15-2 1.0 - 2.5
ETHER ACETATE (GLYCOL ETHERS)
TOLUENE DIISOCYANATE 26471-62-5 <1

This material contains a chemical which requires export notification under TSCA Section 12[b]:

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501 02/06/2005

Ingredient (Category if applicable) C.A.S. No Regulation Status
HEPTANE 142-82-5 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals

STATE REGULATIONS
Contact 3M for more information.

CALIFORNIA PROPOSITION 65

Ingredient C.A.S. No. Classification
TOLUENE 108-88-3 *Developmental Toxin
TOLUENE DIISOCYANATE 26471-62-5 **Carcinogen

* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.
** WARNING: contains a chemical which can cause cancer.

CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

INTERNATIONAL REGULATIONS
Contact 3M for more information.

US LABEL INFORMATION

PRECAUTIONS: Keep away from sources of ignition - No Smoking. Avoid breathing vapors, eye contact and prolonged skin
contact. Use only in well ventilated areas. When using do not eat, drink or smoke. Wash thoroughly after handling. Launder
contaminated clothing before re-use. Do not take internally. Keep container tightly closed and in a well ventilated place.

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 3 Flammability: 0 Reactivity: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.

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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant 5200 Tan PN 06501 02/06/2005

No revision information is available.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

3M MSDSs are available at www.3M.com

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