3-Chloroperoxybenzoic acid

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand CAS-No. : : : : 3-Chloroperbenzoic acid 273031 937-14-4 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Organic peroxides (Type D) Skin irritation (Category 2) Eye irritation (Category 2) Skin sensitization (Category 1) Specific target organ toxicity - single exposure (Category 3) Classification according to EU Directives 67/548/EEC or 1999/45/EC Contact with combustible material may cause fire. May cause sensitization by skin contact. Irritating to eyes, respiratory system and skin. Heating may cause an explosion. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H242 H315 H317 H319 H335 - 273031 Danger Heating may cause a fire. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Precautionary statement(s) P220 P261 P280 P305 + P351 + P338 P410 P412 Supplemental Hazard Keep/Store away from clothing/ combustible materials. Avoid breathing dust. Wear protective gloves/ protective clothing/ eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. none Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R5 R8 R36/37/38 R43 S-phrase(s) S26 S36/37 Heating may cause an explosion. Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. 2.3 3. 3.2 Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Mixtures Synonyms Formula Molecular Weight : : : MCPBA 3-Chloroperoxybenzoic acid C7H5ClO3 172,57 g/mol Component 3-Chloroperbenzoic acid Classification Concentration CAS-No. EC-No. 937-14-4 213-322-3 Org. Perox. A; Skin Irrit. 2; Eye 50 - 100 % Irrit. 2; Skin Sens. 1; STOT SE 3; H240, H315, H317, H319, H335 O, Xi, R 5 - R 8 - R36/37/38 - R43 3-Chlorobenzoic acid CAS-No. EC-No. 535-80-8 208-618-4 Skin Irrit. 2; Eye Irrit. 2; STOT SE 3; H315, H319, H335 10 - 20 % Xi, R36/37/38 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 4. 4.1 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. - 273031 In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 4.3 5. 5.1 5.2 5.3 5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 7.3 Most important symptoms and effects, both acute and delayed To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, Hydrogen chloride gas Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal. Contain spillage, pick up with an electrically protected vacuum cleaner or by wet-brushing and transfer to a container for disposal according to local regulations (see section 13). Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition - No smoking.Keep away from heat and sources of ignition. Conditions for safe storage, including any incompatibilities Store in original container. Keep container tightly closed in a dry and well-ventilated place. Store in cool place. Recommended storage temperature: 2 - 8 °C Specific end uses no data available - 273031 8. 8.1 8.2 9. 9.1 EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: solid Colour: white no data available no data available no data available Melting point/range: 69 - 71 °C - lit. no data available no data available no data available i) Flammability (solid, gas) no data available j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density no data available no data available no data available m) Relative density - 273031 no data available n) o) p) q) r) s) t) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties no data available no data available no data available no data available no data available no data available no data available 9.2 10. 10.1 10.2 10.3 10.4 10.5 10.6 11. 11.1 Other safety information no data available STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid Do not heat over: 40°C Heat, flames and sparks. Incompatible materials Strong oxidizing agents, Strong bases, Strong reducing agents, Organic materials, Manganese/manganese oxides, Acids, Metals, Combustible material, Flammable materials Hazardous decomposition products Other decomposition products - no data available TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available - 273031 Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. Causes respiratory tract irritation. May be harmful if swallowed. May be harmful if absorbed through skin. Causes skin irritation. Causes serious eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS: Not available 12. 12.1 12.2 12.3 12.4 12.5 12.6 13. 13.1 14. 14.1 ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects no data available DISPOSAL CONSIDERATIONS Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. TRANSPORT INFORMATION UN number 14.2 ADR/RID: 3106 UN proper shipping name IMDG: 3106 IATA: 3106 ADR/RID: IMDG: IATA: ORGANIC PEROXIDE TYPE D, SOLID (3-CHLOROPEROXYBENZOIC ACID) (3- Chlorobenzoic acid) ORGANIC PEROXIDE TYPE D, SOLID (3-CHLOROPEROXYBENZOIC ACID) (3- Chlorobenzoic acid) Organic peroxide type D, solid (3-Chloroperoxybenzoic acid) (3-Chlorobenzoic acid) Special Provisions : “Keep away from heat” label required. 14.3 Transport hazard class(es) ADR/RID: 5.2 - 273031 IMDG: 5.2 IATA: 5.2 (HEAT) 14.4 Packaging group 14.5 14.6 15. ADR/RID: - Environmental hazards ADR/RID: no Special precautions for user no data available REGULATORY INFORMATION IMDG: - IMDG Marine pollutant: no IATA: - IATA: no This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 15.2 16. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Eye Irrit. H240 H315 H317 H319 H335 Org. Perox. Skin Irrit. Skin Sens. STOT SE O Xi R5 R8 R36/37/38 R43 Eye irritation Heating may cause an explosion. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Organic peroxides Skin irritation Skin sensitization Specific target organ toxicity - single exposure Oxidising Irritant Heating may cause an explosion. Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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