information Related products Suppliers

1-Propanol, 2-ethoxy-

MSDS for Ethoxy Propanol

MATERIAL SAFETY DATA SHEET
Ethoxy Propanol
------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 1: IDENTIFICATION OF SUBSTANCE/MIXTURE & SUPPLIE -----------------------------------------------------------------------------------------------------------------------------------------------

Ethoxy Propanol
Product Name:
Propylene Glycol Monoethyl Ether, Glycol Ether, Propanol Ethoxy
Other Names:
Recommended Use: Solvent for resins, inks and adhesives.
Supplier: CSR Distilleries Operations Pty Limited
ABN: ABN 85 009 660 191
Address: 265 Whitehall Street
Yarraville VIC 3013
Australia
Telephone: +61 3 9283 4500 (Or 1800 819 618 (available in Australia only))
Facsimile: 1800 647 260
000 Fire Brigade and Police (available in Australia only).
Emergency Phone :
Important Notice : This Material Safety Data Sheet (MSDS) is issued by the Supplier in accordance with
National Occupational Health & Safety Commission (NOHSC) guidelines. As such, the
information in it must not be altered, deleted or added to. The Supplier will issue a new
MSDS when there is a change in product specifications and/or NOHSC
guidelines/regulations. The Supplier will not accept any responsibility for any changes
made to its MSDS by any other person or organisation.

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 2: HAZARDS INFORMATION
------------------------------------------------------------------------------------------------------------------------------------------------

HAZARDOUS SUBSTANCE - DANGEROUS GOODS

DG Class 3
Subsidiary Risk 1: None Allocated
Packaging Group III
Poison Schedule None Scheduled

Risk Phrase(s)
R11 - Highly flammable.
R65 - Harmful: May cause lung damage if swallowed.
R66 - Repeated exposure may cause skin dryness and cracking.
R20/22 - Harmful by inhalation and if swallowed.
R36/38 - Irritating to eyes and skin.

Safety Phrase(s)
S16 - Keep away from sources of ignition - No smoking.
S23 - Do not breathe vapour.
S26 - In case of contact with eyes rinse immediately with plenty of water and seek medical advice.
S28 - After contact with skin wash immediately with plenty of soap-suds.
S29 - Do not empty into drains.
S33 - Take precautionary measures against static discharges.
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label whenever possible.)
S62 - If swallowed do not induce vomiting; seek medical advice immediately and show this container or label

RED TEXT ?? CONTROLLED COPY
GREY TEXT ?? UNCONTROLLED COPY
MSDS for Ethoxy Propanol

S7/9 - Keep container tightly closed and in a well ventilated place
S24/25 - Avoid contact with skin and eyes
S36/37/39 - Wear suitable protective clothing/ gloves and eye/face protection

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS
------------------------------------------------------------------------------------------------------------------------------------------------

Chemical Name: CAS Number: Proportion:
1-Ethoxy-2- Propanol 1569-02-4 >90%
2-Ethoxy-1-Propanol 19089-47-5 <10%

This material is listed on the Australian Inventory of Chemical Substances (AICS).

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 4: FIRST AID MEASURES
------------------------------------------------------------------------------------------------------------------------------------------------

If poisoning occurs, contact a doctor or Poisons Information Centre.

Swallowed: If a minor amount has been accidentally swallowed, then if conscious, dilute stomach contents by
giving large amounts of water. Seek medical attention. Do not attempt to induce vomiting or give anything by
mouth to an unconscious person.

Eye: Flush eye with water for a minimum of 15 minutes,. Seek medical attention promptly if irritation persists or
any loss of vision occurs.

Skin: Contamination of skin may cause minor irritation. With heavier contamination, remove contaminated
clothing. Wash skin with flowing water. Launder contaminated clothing before re-use.

Inhaled: Remove promptly to fresh air. If there are signs of drunkenness (intoxication or inebriation) or respiratory
irritation, dizziness, nausea or headache occurs, seek immediate medical attention. Treat unconsciousness by
placing the person in the coma position. Apply artificial respiration if breathing stops.

Notes to doctor: Treat symptomatically and as for a narcotic substance.

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 5: FIRE FIGHTING MEASURES
------------------------------------------------------------------------------------------------------------------------------------------------

Specific Hazards: Highly flammable liquid. May form flammable mixtures with air. Burns with a colourless flame. The
vapour is heavier than air and may travel along the ground; distant ignition and flash back are possible. Run off to
sewers and drains may cause explosions. Isolate for at least 800 metres in all directions if tanks or tankers are
involved. The use of compressed air for filling, discharging, mixing or handling is prohibited due to the vapour hazard.
All vessels must be earthed to avoid generation of static charges when agitating or transferring solvents. Avoid all
ignition sources. Intrinsically safe equipment is necessary in areas where this chemical is being used.

Extinguishing Media: Use water fog (or if unavailable fine water spray), dry chemical, carbon dioxide for small fires.
Alcohol stable foam or all purpose foam can be used on large fires.

Fire Fighting Procedures: Highly flammable liquid. Use water to cool exposed containers. Heating can cause
expansion or decomposition leading to violent rupture of containers. If safe to do so, remove containers from path of
fire. Spills and leaks may be washed away with copious volumes of water, fog or spray. For major fires or where the
atmosphere is either oxygen deficient or contains unacceptable levels of combustion products, firefighters must wear
self-contained breathing apparatus with full face-mask and protective clothing.

Hazardous Decomposition products: Burning can produce carbon monoxide and/or carbon dioxide.

RED TEXT ?? CONTROLLED COPY
GREY TEXT ?? UNCONTROLLED COPY
MSDS for Ethoxy Propanol

Hazchem code: 2[Y]

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 6 : ACCIDENTAL SPILL AND RELEASE MEASURES
------------------------------------------------------------------------------------------------------------------------------------------------

Containment Procedures: In the event of a spillage eliminate all sources of ignition and take measures to prevent
static discharge ?? no smoking. Stop and contain the spill for salvage or absorb in inert absorbent material (e.g. soil,
sand, vermiculite) for disposal by an approved method. Prevent run-off into drains and waterways. Clear area of all
personnel not directly involved in the clean up. All personnel involved in the containment and disposal procedures to
wear protective equipment as described in Section 8 to prevent skin and eye contamination and inhalation of
vapours. Use water spray to disperse vapour. Wash the cleaned up area with copious volumes of water to remove
any traces amounts of product. n-Propanol mixes completely with water. Spills can be converted to non-flammable
mixtures by dilution with water. Ventilate area well and ensure adequate personal protection as above. If
contamination of sewers or waterways has occurred, advise the local emergency services.

Disposal: Stop and contain the spill for salvage or absorb in inert absorbent material (e.g. soil, sand, vermiculite) for
disposal by an approved method. Dispose of all waste containers and used drums in accordance with local authority
guidelines. Non-returnable containers should be de-gassed prior to disposal.

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 7: HANDLING AND STORAGE
------------------------------------------------------------------------------------------------------------------------------------------------

Handling and Storage:
Handling: Use in well ventilated areas away from all ignition sources. Intrinsically safe equipment only must be
used in area where this chemical is being used. The use of compressed air for filling, discharging, mixing or
handling is prohibited due to the vapour hazard. Containers must be earthed to avoid generation of static
charges when agitating or transferring product.

Storage: Store in tightly closed containers in cool, dry, isolated and well ventilated areas away from heat,
sources of ignition and incompatibles. Store away from oxidizing agents. Keep containers closed at all times ??
check regularly for leaks. Do not eat, drink or smoke in areas of use or storage. Observe State Regulations
concerning the storage and handling of Dangerous Goods. Store with all precautions required for handling
flammable liquids. The requirement of Australian Standard AS 1940 should be observed in addition to AS 1020,
AS 1076, AS 2380 and AS 3000.

Empty containers retain residue (liquid and/or vapour and can be dangerous. Do not pressure cut, weld, braze,
solder, drill, grind or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition.

Incompatibilities: Incompatible with strong oxidising agents, air or oxygen and phosphorous compounds.

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 8: EXPOSURE CONTROL AND PERSONAL PROTECTION
------------------------------------------------------------------------------------------------------------------------------------------------

Exposure Standards:
National occupational exposure standards:

No Exposure standard has been established by Worksafe Australia for Ethoxy Propanol (Propylene Glycol
monoethyl Ether), however, they do have an exposure standard for Propylene Glycol monomethyl Ether. It is
recommended that the same level be applied for Ethoxy Propanol

Propylene Glycol Monomethyl Ether TWA - 100ppm (369 mg/m3)
STEL - 150ppm (553 mg/m3)
Carcinogen Category - None Allocated
Notices - None Allocated

RED TEXT ?? CONTROLLED COPY
GREY TEXT ?? UNCONTROLLED COPY
MSDS for Ethoxy Propanol

As published by National Occupational Health and Safety Commission.

Exposure Standard (TWA) is the time-weighted average airborne concentration over an eight-hour working day,
for a five-day working week over an entire working life. According to current knowledge this concentration should
neither impair the health or, not cause undue discomfort to, nearly all workers.

STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should
not be exceeded at any time during a normal eight-hour work day.

Sk Notice ?? absorption through the skin may be a significant source of exposure. The exposure standard is
invalidated if such contact should occur.

These Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric
contamination should be kept to as low a level as is workable. These Exposure Standards should not be used as
fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative
toxicity.

Engineering Controls:

Ventilation: Local exhaust ventilation and/or mechanical (general) exhaust is recommended where vapours are likely
to be generated. All such equipment must be intrinsically safe.

Special Considerations for Repair And/Or Maintenance of Contaminated Equipment: Empty containers retain
residue (liquid and/or vapour) and can be dangerous. Do not pressure cut, weld, braze, solder, drill, grind or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. Vapour is heavier than air ??
prevent concentration in hollows or sumps. Do not enter confined spaces where vapour may have collected. Keep
containers closed when not in use.

Personal Hygiene: Protective clothing (gloves, coveralls, boots, etc.) should be worn to prevent skin contact. Always
wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective
equipment before storing or re-using.

Eye Protection: Avoid eye contact by wearing chemical goggles with side shields or face shield (AS/NZS 1336)
whenever exposed to vapour or mist or if there is a risk of splashing liquid in the eyes. Safety showers with eye-wash
should be provided in all areas where product is handled.

Skin Protection: Avoid repeated skin contact by the use of approved chemical resistant gloves, aprons and boots ??
Butyl Rubber or Neoprene (AS 2161).

Respiratory Protection: None should be needed under normal circumstances. In high vapour concentrations, or in
suspected oxygen deficient atmospheres, such as empty vessels or confined spaces, use air supplied hood. In other
instances where vapour concentrations are likely to exceed 100ppm, an approved organic vapour respirator (AS/NZS
1715 and 1716) must be worn.

Smoking and Other Dusts: Smoking must be prohibited in all areas where this product is used - see safety
information on flammability

------------------------------------------------------------------------------------------------------------------------------------------------

RED TEXT ?? CONTROLLED COPY
GREY TEXT ?? UNCONTROLLED COPY
MSDS for Ethoxy Propanol

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
------------------------------------------------------------------------------------------------------------------------------------------------

Appearance: Clear colourless liquid
Odour Mild odour. Objectionable odour at > 100ppm
pH, at stated concentration Not Available
Boiling Point: (??C) 132 - 183??C
Melting Point: (??C) ~ -90??C
Vapour pressure: 10 mm Hg at 25??C
Specific gravity (H2O = 1) 0.89 - 0.91 at 20??C/20??C
Solubility in water: 100% - may take some time to completely mix.
Evaporation Rate: 0.44 (n-Butyl acetate = 100)
Vapour Density: 3.6 (1-Ethoxy-2-Propanol) (air = 1)
Per cent volatiles: 100%
Flash Point: 40 - 42??C
Closed Cup
FP Test Method:
Lower Explosive Limit (LEL): 1.3%
Upper Explosive Limit (UEL): 12%

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 10: STABILITY AND REACTIVITY
------------------------------------------------------------------------------------------------------------------------------------------------

Chemical Stability Stable
Is not expected to occur
Hazardous Polymerisation:

Incompatible Materials: Will react with strong oxidizing agents., air or oxygen and
phosphorous compounds
Conditions to avoid: Heat, sparks, flame and build-up of static electricity. Extended
contact with air or oxygen may form peroxides
Hazardous Decomposition products: Combustion or burning can produce carbon monoxide and/or carbon
dioxide and acrid smoke

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 11: TOXICOLOGICAL AND EPIDEMIOLOGICAL DATA
------------------------------------------------------------------------------------------------------------------------------------------------

Acute Effects:

Swallowed: Unlikely under normal occupational exposures, but swallowing the product may cause nausea, vomiting,
diarrhoea, abdominal discomfort, pain and stomach cramps.

Eye: Liquid and mists may severely irritate or damage the eyes. The vapour is mildly irritating at high
concentrations.

Skin: contact with skin may result in slight irritation. Prolonged or repeated contact and heavy skin contamination
may cause skin drying and cracking and/or dermatitis with redness, itching, and swelling. This may lead to possible
secondary infection.

Inhaled: Vapours in high concentrations may cause minor irritation of the upper respiratory tract. Higher
concentrations can cause drowsiness, headaches and vomiting. May also produce central nervous system
depression, which can lead to loss of co-ordination, impaired judgement and, if exposure is prolonged,
unconsciousness.
Acute Effects:

RED TEXT ?? CONTROLLED COPY
GREY TEXT ?? UNCONTROLLED COPY
MSDS for Ethoxy Propanol

Acute toxicity (ethoxy propanol):
LD50/oral/rat: 11752 mg/kg
LD50/dermal/rat: 2500 mg/kg

Long Term Effects: Not listed as mutagenic or carcinogenic. No information about long-term human exposures is
reported. However by analogy with other similar substances, repeated and excessive over-exposure may damage
organs such as the liver and kidneys.

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 12: ECOLOGICAL INFORMATION
------------------------------------------------------------------------------------------------------------------------------------------------

Ecotoxicity: No data available

Persistemce and degradability: Biodegradable

Mobility in soil: No data available

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 13: DISPOSAL CONSIDERATIONS
------------------------------------------------------------------------------------------------------------------------------------------------

Suitable for incineration by approved agent under controlled conditions if permitted by local authorities, otherwise
disposal must be in accordance with local waste authority requirements. Product must be contained and not disposed
to sewerage systems, drains or waterways. Advise flammable nature. Empty containers must be decontaminated by
rinsing with water.

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 14: TRANSPORTATION INFORMATION
------------------------------------------------------------------------------------------------------------------------------------------------

Transport Requirements:
UN number: 3271
Class 3
Subsidiary Risk 1: None Allocated
Packaging Group III
Hazchem code: 2[Y]
EPG
Incompatible with strong oxidising agents, air or oxygen and phosphorous
Incompatibilities:
compounds.

Road and Rail Transport (Australian Dangerous Goods Code):

UN Number: 3271
Proper Shipping Name: ETHERS NOS
Class: 3 Flammable Liquid
Hazchem Code: 2[Y]E
Packing Group: III

Marine Transport (International Maritime Dangerous Goods Code):
UN Number: 3271
Proper Shipping Name: ETHERS NOS
Class: 3 Flammable Liquid
Packing Group: III
Marine Pollutant: No

Air Transport (International Air Transport Association Dangerous Goods Regulations):

UN Number: 3271

RED TEXT ?? CONTROLLED COPY
GREY TEXT ?? UNCONTROLLED COPY
MSDS for Ethoxy Propanol

Proper Shipping Name: ETHERS NOS
Class: 3 Flammable Liquid
Packing Group: III

------------------------------------------------------------------------------------------------------------------------------------------------

SECTION 15: REGULATORY INFORMATION
------------------------------------------------------------------------------------------------------------------------------------------------

Regulatory Information:
Classification: Hazardous according to criteria of NOHSC.
Dangerous Good according to criteria of the Australian Dangerous
Goods Code.
Poisons Schedule: Not Scheduled

------------------------------------------------------------------------------------------------------------------------------------------------
SECTION 16: OTHER INFORMATION AND CONTACT POINT
------------------------------------------------------------------------------------------------------------------------------------------------

Further Information can be obtained from:

CSR Distilleries Operations Pty Limited (ABN 85 009 660 191), 265 Whitehall Street, Yarraville VIC 3013,
Australia. Phone +61 3 9283 4500 or 1800 819 618 (available in Australia only). Fax 1800 647 260

Additional Information

Australian Standards References:
AS 1020 The Control of undesirable static electricity.

AS 1076 Code of Practice for selection, installation and maintenance of electrical apparatus and
associated equipment for use in explosive atmospheres (other than mining applications) ??
Parts 1 to 13.

AS/NZS 1336 Recommended Practices for Occupational Eye Protection.

AS/NZS 1715 Selection, Use and Maintenance of Respiratory Protective Devices.

AS/NZS 1716 Respiratory Protective Devices.

AS 1940 The Storage and Handling of Flammable and Combustible Liquids.

AS 2161 Industrial Safety Gloves and Mittens (excluding electrical and medical gloves).

AS 2380 Electrical equipment for explosive atmospheres ?? Explosion Protection Techniques (Parts
1 to 9).

AS 3000 Electrical installations (known as the Australian/New Zealand Wiring Rules).

This MSDS was correct at the time it was prepared (see below for the date). The Supplier, as part of its Health and
Safety Programme, updates MSDS??s when its ongoing review process indicates a need for a change to be made.
You should make sure that the MSDS you are reading and relying on is current. You can do this by contacting the
Supplier at the above address.

Issue Date: 08/2008

MSDS Revision Summary
Supersedes Issue Date: 10/2003
Reasons for Issue: Updated emergency phone number only. Full review required by 10/2008.
CSR MSDS No.: MSDS-024
Expiry Date: 10/2008

RED TEXT ?? CONTROLLED COPY
GREY TEXT ?? UNCONTROLLED COPY

;