Benzene, ethyl-

1.
1.1
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifiers
Product name
Product Number
Brand
Index-No.
CAS-No.
:
:
:
:
:
Ethylbenzene
03079
Fluka
601-023-00-4
100-41-4
1.2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
:
Laboratory chemicals, Manufacture of substances
2.
2.1
2.2
HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Flammable liquids (Category 2)
Acute toxicity, Inhalation (Category 4)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Highly flammable. Harmful by inhalation.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word
Hazard statement(s)
H225
H332
Precautionary statement(s)
P210
Supplemental Hazard
Statements
Danger
Highly flammable liquid and vapour.
Harmful if inhaled.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
none
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R11
R20
S-phrase(s)
S16
S24/25
S29
Highly flammable.
Harmful by inhalation.
Keep away from sources of ignition - No smoking.
Avoid contact with skin and eyes.
Do not empty into drains.
2.3
3.
3.1
Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula
Molecular Weight
Component
Ethylbenzene
:
:
C8H10
106,17 g/mol
Concentration
CAS-No.
EC-No.
Index-No.
100-41-4
202-849-4
601-023-00-4
-
4.
4.1
4.2
4.3
5.
5.1
5.2
5.3
FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
Most important symptoms and effects, both acute and delayed
Central nervous system depression, Nausea, Headache, Vomiting, Ataxia., Tremors
Indication of any immediate medical attention and special treatment needed
no data available
FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
8.
8.1
8.2
Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to
form explosive concentrations. Vapours can accumulate in low areas.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13).
Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
hygroscopic
Specific end uses
no data available
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type
of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
9.
9.1
PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour Threshold
pH
Melting point/freezing
point
Initial boiling point and
boiling range
Flash point
Evaporation rate
Form: liquid
Colour: colourless
no data available
no data available
no data available
Melting point/range: -95 °C - lit.
136 °C - lit.
15,0 °C - closed cup
no data available
i)
Flammability (solid, gas) no data available
j)
k)
l)
Upper/lower
flammability or
explosive limits
Vapour pressure
Vapour density
Upper explosion limit: 6,7 %(V)
Lower explosion limit: 1 %(V)
25,3 hPa at 37,7 °C
13,3 hPa at 20,0 °C
no data available
m) Relative density
0,867 g/mL at 25 °C
n)
o)
p)
q)
r)
s)
t)
Water solubility
Partition coefficient: n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive properties
Oxidizing properties
no data available
log Pow: 2,92
432,0 °C
no data available
no data available
no data available
no data available
9.2
10.
10.1
10.2
10.3
Other safety information
no data available
STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
10.4
10.5
10.6
11.
11.1
Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available
TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
LD50 Dermal - rabbit - 15.433 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
Eyes - rabbit - Risk of serious damage to eyes.
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
This product is or contains a component that has been reported to be possibly carcinogenic based on its
IARC, ACGIH, NTP, or EPA classification.
IARC:
2B - Group 2B: Possibly carcinogenic to humans (Ethylbenzene)
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation
Ingestion
Skin
Eyes
Harmful if inhaled. May cause respiratory tract irritation.
May be harmful if swallowed.
May be harmful if absorbed through skin. May cause skin irritation.
Causes eye burns.
Signs and Symptoms of Exposure
Central nervous system depression, Nausea, Headache, Vomiting, Ataxia., Tremors
Additional Information
RTECS: DA0700000
12.
12.1
ECOLOGICAL INFORMATION
Toxicity
Toxicity to fish
LC50 - Cyprinodon variegatus (sheepshead minnow) - 88,00 mg/l - 96 h
LC50 - Lepomis macrochirus (Bluegill) - 80,00 mg/l - 96 h
NOEC - Cyprinodon variegatus (sheepshead minnow) - 88 mg/l - 96 h
LC50 - Oncorhynchus mykiss (rainbow trout) - 4,2 mg/l - 96 h
Toxicity to daphnia and
other aquatic
invertebrates
EC50 - Daphnia magna (Water flea) - 2,90 mg/l - 48 h
12.2
12.3
12.4
12.5
12.6
13.
13.1
14.
14.1
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
Toxic to aquatic life.
DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
company.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION
UN number
14.2
14.3
14.4
14.5
14.6
15.
ADR/RID: 1175
UN proper shipping name
ADR/RID:
ETHYLBENZENE
IMDG:
ETHYLBENZENE
IATA:
Ethylbenzene
Transport hazard class(es)
ADR/RID: 3
Packaging group
ADR/RID: II
Environmental hazards
ADR/RID: no
Special precautions for user
no data available
REGULATORY INFORMATION
IMDG: 1175
IMDG: 3
IMDG: II
IMDG Marine pollutant: no
IATA: 1175
IATA: 3
IATA: II
IATA: no
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1
15.2
16.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
no data available
OTHER INFORMATION
Further information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

guarantee of the properties of the product. Anonymous-Anonymous Co., shall not be held liable for any damage
resulting from handling or from contact with the above product. See reverse side of invoice or packing
slip for additional terms and conditions of sale.
;

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Dayang Chem (Hangzhou) Co.,Ltd.

China (Mainland) Assessed Supplier

Ethylbenzene

  • Assay:Industrial Grade ,
  • Appearance:Light transparent liquid
  • Package:according to the clients requirement
  • Storage:Store in dry, dark and ventilated place.
  • Transportation:by sea or by air
  • Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.
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  • Assay:99%
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Hebei yanxi chemical co.,LTD.

China (Mainland) Assessed Supplier

100-41-4 Ethylbenzene

  • Assay:1,
  • Appearance:White crystalline powder
  • Package:According to customer requirement packaging
  • Storage:
  • Transportation:Shipping
  • Application:N/A
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Ality Chemical Corporation

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Factory Supply Ethylbenzene

  • Assay:99.9%
  • Appearance:Refer to COA
  • Package:drum
  • Storage:keep in cool and dry place
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Chemwill Asia Co., Ltd.

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Ethylbenzene

  • Assay:1,d,
  • Appearance:As per Certificate of analysis and our TDS, MSDS
  • Package:Export standard and according to the clients requirement
  • Storage:Store in dry, dark and ventilated place;ISO / Kosher /GMP licence commercial bulk capacity factory in China
  • Transportation:By AIR or by SEA GMP licence / US-FDA,South Korea-KFDA
  • Application:It is an important raw material and intermediate for chemical industry.
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