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1,3-Butadiene

1.1

IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifiers

Product name

Product Number

Brand

Index-No.

CAS-No.

1,3-Butadiene

17932

Fluka

601-013-00-X

106-99-0

1.2

Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Laboratory chemicals, Manufacture of substances

2.1

2.2

HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]

Flammable gases (Category 1)

Gases under pressure (Liquefied gas)

Carcinogenicity (Category 1A)

Germ cell mutagenicity (Category 1B)

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Extremely flammable. May cause cancer. May cause heritable genetic damage.

Label elements

Labelling according Regulation (EC) No 1272/2008 [CLP]

Pictogram

Signal word

Hazard statement(s)

H220

H280

H340

H350

Precautionary statement(s)

P201

P210

Danger

Extremely flammable gas.

Contains gas under pressure; may explode if heated.

May cause genetic defects.

May cause cancer.

Obtain special instructions before use.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P308 + P313

P410 + P403

Supplemental Hazard

IF exposed or concerned: Get medical advice/ attention.

Protect from sunlight. Store in a well-ventilated place.

none

Statements

Restricted to professional users.

According to European Directive 67/548/EEC as amended.

Hazard symbol(s)

R-phrase(s)

R45

R46

R12

S-phrase(s)

S53

S45

May cause cancer.

May cause heritable genetic damage.

Extremely flammable.

Avoid exposure - obtain special instructions before use.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

Restricted to professional users.

2.3

3.1

Other hazards - none

COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Molecular Weight

Component

1,3-Butadiene

54,09 g/mol

Concentration

CAS-No.

EC-No.

Index-No.

106-99-0

203-450-8

601-013-00-X

4.1

4.2

4.3

FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with

water. Consult a physician.

Most important symptoms and effects, both acute and delayed

Cholinesterase inhibitors can cause heavy salivation and secretion in the lungs, lachrymation, blurred

vision, involuntary defecation, diarrhea, tremor, ataxia, sweating, hypothermia, lowered heart rate, and/or a

fall in blood pressure as a result of their action at cholinergic nerve sites., narcosis, Headache, Nausea,

Vomiting, Dizziness, Drowsiness, Confusion., Weakness, Muscle cramps/spasms., Change in pupil size.,

Tremors, Seizures., Incoordination., Convulsions, Coma

Indication of any immediate medical attention and special treatment needed

no data available

5.1

5.2

5.3

5.4

6.1

6.2

6.3

6.4

7.1

7.2

7.3

8.1

8.2

FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Carbon oxides

Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

Use water spray to cool unopened containers.

ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.

Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to

form explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up

Clean up promptly by sweeping or vacuum.

Reference to other sections

For disposal see section 13.

HANDLING AND STORAGE

Precautions for safe handling

Avoid exposure - obtain special instructions before use.Avoid inhalation of vapour or mist.

Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic

charge.

Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Specific end uses

no data available

EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components with workplace control parameters

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and

at the end of workday.

Personal protective equipment

Eye/face protection

Face shield and safety glasses Use equipment for eye protection tested and approved under

appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and

the standard EN 374 derived from it.

Body Protection

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type

of protective equipment must be selected according to the concentration and amount of the

dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator

with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup

to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

9.1

PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Odour

Odour Threshold

Melting point/freezing

point

Initial boiling point and

boiling range

Flash point

Evaporation rate

Form: Liquefied gas

no data available

Melting point/range: -109 °C

-4,9 °C at 1.013 hPa - Tested according to Annex V of Directive

67/548/EEC.

-76 °C - closed cup - Tested according to Annex V of Directive

67/548/EEC.

no data available

Flammability (solid, gas) no data available

Upper/lower

flammability or

explosive limits

Vapour pressure

Vapour density

Upper explosion limit: 16,3 %(V)

Lower explosion limit: 1,4 %(V)

ca.2.400 hPa at 20 °C

3.200 hPa at 30 °C

5.700 hPa at 50 °C

no data available

m) Relative density

no data available

Water solubility

Partition coefficient: n-

octanol/water

Autoignition

temperature

Decomposition

temperature

Viscosity

Explosive properties

Oxidizing properties

0,5 g/l at 20 °C - Tested according to Annex V of Directive 67/548/EEC.

log Pow: 1,85 at 23 °C

no data available

9.2

Other safety information

no data available

10.

10.1

10.2

10.3

10.4

10.5

10.6

11.

11.1

STABILITY AND REACTIVITY

Reactivity

no data available

Chemical stability

no data available

Possibility of hazardous reactions

no data available

Conditions to avoid

Heat. Polymerisation occurs when exposed to white light, ultraviolet light or heat. May form peroxides of

unknown stability.

Heat, flames and sparks. Extremes of temperature and direct sunlight.

Incompatible materials

Oxidizing agents, Oxygen, Copper, Copper alloys, Carbides, Halogens, Metal oxides, Metals

Hazardous decomposition products

Other decomposition products - no data available

TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

LD50 Oral - rat - 5.480 mg/kg

LC50 Inhalation - rat - 4 h - 285 mg/l

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

In vivo tests showed mutagenic effects

Carcinogenicity

Carcinogenicity - rat - Inhalation

Tumorigenic:Carcinogenic by RTECS criteria. Cardiac:Tumors. Lungs, Thorax, or Respiration:Tumors.

This is or contains a component that has been reported to be carcinogenic based on its IARC, OSHA,

ACGIH, NTP, or EPA classification.

Human carcinogen.

IARC:

1 - Group 1: Carcinogenic to humans (1,3-Butadiene)

Reproductive toxicity

Reproductive toxicity - mouse - Inhalation

Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of

implants). Effects on Embryo or Fetus: Extra embryonic structures (e.g., placenta, umbilical cord). Effects

on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus).

Developmental Toxicity - rat - Inhalation

Specific Developmental Abnormalities: Musculoskeletal system.

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. May cause respiratory tract irritation.

May be harmful if swallowed.

May be harmful if absorbed through skin. May cause skin irritation.

May cause eye irritation.

Signs and Symptoms of Exposure

Cholinesterase inhibitors can cause heavy salivation and secretion in the lungs, lachrymation, blurred

vision, involuntary defecation, diarrhea, tremor, ataxia, sweating, hypothermia, lowered heart rate, and/or a

fall in blood pressure as a result of their action at cholinergic nerve sites., narcosis, Headache, Nausea,

Vomiting, Dizziness, Drowsiness, Confusion., Weakness, Muscle cramps/spasms., Change in pupil size.,

Tremors, Seizures., Incoordination., Convulsions, Coma

Additional Information

RTECS: Not available

12.

12.1

ECOLOGICAL INFORMATION

Toxicity

Toxicity to fish

LC50 - other fish - 71,5 mg/l - 24 h

12.2

12.3

12.4

12.5

12.6

13.

13.1

14.

14.1

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

Results of PBT and vPvB assessment

no data available

Other adverse effects

no data available

DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting

as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal

company.

Contaminated packaging

Dispose of as unused product.

TRANSPORT INFORMATION

UN number

14.2

ADR/RID: 1010

UN proper shipping name

IMDG: 1010

IATA: 1010

ADR/RID:

IMDG:

IATA:

BUTADIENES, STABILIZED

Butadienes, stabilized

Passenger Aircraft: Not permitted for transport

14.3

Transport hazard class(es)

ADR/RID: 2.1

14.4

Packaging group

ADR/RID: -

IMDG: 2.1

IMDG: -

IATA: 2.1

IATA: -

14.5

Environmental hazards

14.6

15.

ADR/RID: no

Special precautions for user

no data available

REGULATORY INFORMATION

IMDG Marine pollutant: no

IATA: no

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.1

15.2

16.

Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

Chemical Safety Assessment

no data available

OTHER INFORMATION

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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