Borate(1-),tetrahydro-d4-, sodium (8CI,9CI)

1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand CAS-No. : : : : Sodium borodeuteride 205591 Anonymous 15681-89-7 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 2. 2.1 2.2 HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Substances, which in contact with water, emit flammable gases (Category 1) Acute toxicity, Oral (Category 3) Acute toxicity, Dermal (Category 3) Skin corrosion (Category 1B) Classification according to EU Directives 67/548/EEC or 1999/45/EC Highly flammable. Contact with water liberates extremely flammable gases. Toxic in contact with skin and if swallowed. Causes burns. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H260 H301 H311 H314 Precautionary statement(s) P223 Danger In contact with water releases flammable gases which may ignite spontaneously. Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231 + P232 P280 P301 + P310 P370 + P378 P422 Supplemental Hazard Handle under inert gas. Protect from moisture. Wear protective gloves/ protective clothing/ eye protection/ face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Store contents under inert gas. none Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R11 R15 R24/25 R34 S-phrase(s) S 7/8 S16 S36/37/39 S43 S45 Highly flammable. Contact with water liberates extremely flammable gases. Toxic in contact with skin and if swallowed. Causes burns. Keep container tightly closed and dry. Keep away from sources of ignition - No smoking. Wear suitable protective clothing, gloves and eye/face protection. In case of fire, use fire-fighting equipment on basis class D. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 2.3 3. 3.1 Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Substances Formula Molecular Weight Component : : D4BNa 41,86 g/mol Concentration Sodium [2H4]tetrahydroborate(1-) CAS-No. EC-No. 15681-89-7 239-764-7 - 4. 4.1 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 4.3 5. 5.1 5.2 5.3 5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 7.3 8. 8.1 8.2 Most important symptoms and effects, both acute and delayed Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Dry powder Special hazards arising from the substance or mixture Borane/boron oxides, Sodium oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Do not flush with water. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition - No smoking. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Never allow product to get in contact with water during storage. Moisture sensitive. Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Immersion protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 480 min Material tested:Dermatril? (Anonymous Z677272, Size M) Splash protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 30 min Material tested:Dermatril? (Anonymous Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 873000, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection Complete suit protecting against chemicals, Flame retardant protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). 9. 9.1 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: powder Colour: white no data available no data available no data available Melting point/range: > 300 °C no data available not applicable no data available i) Flammability (solid, gas) no data available j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density no data available no data available no data available m) Relative density 1,187 g/mL n) o) p) q) r) s) t) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties no data available no data available no data available no data available no data available no data available no data available 9.2 10. 10.1 10.2 10.3 10.4 10.5 10.6 11. 11.1 Other safety information no data available STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions Reacts violently with water. Conditions to avoid Exposure to moisture. Incompatible materials Strong oxidizing agents, acids, Alcohols, Violent chemical reaction; water reactive Hazardous decomposition products Other decomposition products - no data available TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Toxic if swallowed. Causes burns. Toxic if absorbed through skin. Causes skin burns. Causes eye burns. Signs and Symptoms of Exposure Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea Additional Information RTECS: Not available 12. 12.1 12.2 12.3 12.4 12.5 12.6 13. 13.1 14. 14.1 ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects no data available DISPOSAL CONSIDERATIONS Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. TRANSPORT INFORMATION UN number 14.2 ADR/RID: 1426 UN proper shipping name IMDG: 1426 IATA: 1426 ADR/RID: IMDG: IATA: SODIUM BOROHYDRIDE SODIUM BOROHYDRIDE Sodium borohydride Passenger Aircraft: Not permitted for transport 14.3 Transport hazard class(es) 14.4 14.5 14.6 15. ADR/RID: 4.3 Packaging group ADR/RID: I Environmental hazards ADR/RID: no Special precautions for user no data available REGULATORY INFORMATION IMDG: 4.3 IMDG: I IMDG Marine pollutant: no IATA: 4.3 IATA: I IATA: no This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 15.2 16. Safety, health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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