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1-Propene,1-chloro-2-methyl- (9CI)

1.1

IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifiers

Product name

Product Number

Brand

CAS-No.

1-Chloro-2-methylpropene

123358

513-37-1

1.2

Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Laboratory chemicals, Manufacture of substances

2.1

2.2

HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]

Flammable liquids (Category 2)

Acute toxicity, Inhalation (Category 1)

Acute toxicity, Dermal (Category 3)

Skin irritation (Category 2)

Eye irritation (Category 2)

Carcinogenicity (Category 1B)

Specific target organ toxicity - single exposure (Category 3)

Classification according to EU Directives 67/548/EEC or 1999/45/EC

May cause cancer. Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Irritating to

eyes, respiratory system and skin.

Label elements

Labelling according Regulation (EC) No 1272/2008 [CLP]

Pictogram

Signal word

Hazard statement(s)

H225

H311

H315

H319

H330

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Danger

Highly flammable liquid and vapour.

Toxic in contact with skin.

Causes skin irritation.

Causes serious eye irritation.

Fatal if inhaled.

H335

H350

Precautionary statement(s)

P201

P210

P260

P280

P284

P305 + P351 + P338

Supplemental Hazard

May cause respiratory irritation.

May cause cancer.

Obtain special instructions before use.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.

Wear protective gloves/ protective clothing.

Wear respiratory protection.

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

none

Statements

Restricted to professional users.

According to European Directive 67/548/EEC as amended.

Hazard symbol(s)

R-phrase(s)

R45

R23/24/25

R11

R36/37/38

S-phrase(s)

S53

S16

S27

S36/37/39

S45

May cause cancer.

Also toxic by inhalation, in contact with skin and if swallowed.

Highly flammable.

Irritating to eyes, respiratory system and skin.

Avoid exposure - obtain special instructions before use.

Keep away from sources of ignition - No smoking.

Take off immediately all contaminated clothing.

Wear suitable protective clothing, gloves and eye/face protection.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

Restricted to professional users.

2.3

3.1

Other hazards

Lachrymator.

COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Synonyms

Formula

Molecular Weight

Component

1-Chloro-2-methylpropene

Isocrotyl chloride

C4H7Cl

90,55 g/mol

Concentration

CAS-No.

EC-No.

513-37-1

208-158-4

4.1

FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

- 123358

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with

water. Consult a physician.

4.2

4.3

5.1

5.2

5.3

5.4

6.1

6.2

6.3

6.4

7.1

7.2

7.3

Most important symptoms and effects, both acute and delayed

burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting

Indication of any immediate medical attention and special treatment needed

no data available

FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large

fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or

spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of

water.

Special hazards arising from the substance or mixture

Carbon oxides, Hydrogen chloride gas

Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

Use water spray to cool unopened containers.

ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove

all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form

explosive concentrations. Vapours can accumulate in low areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up

Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and

place in container for disposal according to local regulations (see section 13).

Reference to other sections

For disposal see section 13.

HANDLING AND STORAGE

Precautions for safe handling

Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation

of vapour or mist.

Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic

charge.

Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are

opened must be carefully resealed and kept upright to prevent leakage.

Specific end uses

no data available

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8.1

8.2

9.1

EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components with workplace control parameters

Exposure controls

Appropriate engineering controls

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling

the product.

Personal protective equipment

Eye/face protection

Face shield and safety glasses Use equipment for eye protection tested and approved under

appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and

the standard EN 374 derived from it.

Body Protection

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type

of protective equipment must be selected according to the concentration and amount of the

dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator

with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup

to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Odour

Odour Threshold

Melting point/freezing

point

Initial boiling point and

boiling range

Flash point

Evaporation rate

Form: clear, liquid

Colour: light brown

no data available

68 °C - lit.

-1 °C - closed cup

no data available

Flammability (solid, gas) no data available

Upper/lower

flammability or

explosive limits

Vapour pressure

Vapour density

no data available

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m) Relative density

0,92 g/cm3 at 25 °C

Water solubility

Partition coefficient: n-

octanol/water

Autoignition

temperature

Decomposition

temperature

Viscosity

Explosive properties

Oxidizing properties

no data available

9.2

10.

10.1

10.2

10.3

10.4

10.5

10.6

11.

11.1

Other safety information

no data available

STABILITY AND REACTIVITY

Reactivity

no data available

Chemical stability

no data available

Possibility of hazardous reactions

no data available

Conditions to avoid

Heat, flames and sparks. Extremes of temperature and direct sunlight.

Incompatible materials

Strong oxidizing agents, Strong bases

Hazardous decomposition products

Other decomposition products - no data available

TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

LD50 Oral - rat - 4.465 mg/kg

Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Eye:Other. Behavioral:Muscle

weakness. Lungs, Thorax, or Respiration:Dyspnea.

LC50 Inhalation - rat - 4 h - 400 mg/m3

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

Possible human carcinogen

IARC:

- 123358

2B - Group 2B: Possibly carcinogenic to humans (1-Chloro-2-methylpropene)

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

Inhalation - May cause respiratory irritation.

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be fatal if inhaled. Causes respiratory tract irritation.

May be harmful if swallowed.

Toxic if absorbed through skin. Causes skin irritation.

Causes serious eye irritation.

Signs and Symptoms of Exposure

burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting

Additional Information

RTECS: UC8045000

12.

12.1

12.2

12.3

12.4

12.5

12.6

13.

13.1

14.

14.1

ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

Results of PBT and vPvB assessment

no data available

Other adverse effects

no data available

DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting

as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal

company. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

TRANSPORT INFORMATION

UN number

14.2

ADR/RID: 1993

UN proper shipping name

IMDG: 1993

IATA: 1993

ADR/RID:

IMDG:

IATA:

FLAMMABLE LIQUID, N.O.S. (1-Chloro-2-methylpropene)

Flammable liquid, n.o.s. (1-Chloro-2-methylpropene)

14.3

Transport hazard class(es)

ADR/RID: 3

- 123358

IMDG: 3

IATA: 3

14.4

Packaging group

14.5

14.6

15.

ADR/RID: II

Environmental hazards

ADR/RID: no

Special precautions for user

no data available

REGULATORY INFORMATION

IMDG: II

IMDG Marine pollutant: no

IATA: II

IATA: no

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

15.1

15.2

16.

Safety, health and environmental regulations/legislation specific for the substance or mixture

no data available

Chemical Safety Assessment

no data available

OTHER INFORMATION

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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